钢铁行业不同物料的二英生成分布及机理探讨

钢铁行业是我国二噁英的第一大排放源,但对不同钢铁生产过程二英的生成排放认识有所欠缺.本文系统探究了钢铁行业不同物料的二噁英生成能力和同系物分布特征.结果表明,烧结飞灰的二英生成能力最强,而烧结生料生成二噁英能力最弱.3种污泥(连铸、热轧、冷轧)和烧结生料的二英生成途径相似,4种飞灰(电炉、转炉、高炉一次、高炉二次)之间也有相似的二英生成途径,而烧结飞灰则与其他物料均不同.所有物料中,有毒2,3,7,8-PCDD同系物之间存在极强的相关性,且氯酚合成二噁英路径也被发现存在于钢铁生产过程中.     

Simultaneous removal of PCDD/Fs and mercury by activated carbon from a full-scale MSW incinerator in southeast China

This study emphasized on the removal performance of polychlorinated-ρ-dibenzodioxins and dibenzofurans (PCDD/Fs) and mercury by different activated carbon injection (ACI) rates from a full-scale (700 t/d) MSW incinerator. The result exhibited that the emission standard of PCDD/Fs and mercury could be met when the ACI rate reached 50 mg/Nm³ and 30 mg/Nm³, respectively. Lower chlorinated PCDD/Fs and PCDFs showed higher removal efficiencies compared with highly chlorinated PCDD/Fs and PCDDs, which could be attributed to the larger competitiveness of highly volatile congeners in AC adsorption than the lower volatile ones. AC turned out to have different adsorption selectivity for CP-routes PCDD/Fs congeners, among which 1379-TCDD was preferred to be absorbed while others exhibited little or poor selectivity for AC adsorption. The removal efficiency of PCDD/Fs was positively correlated with ACI rate at 99% confidence interval with a linear relationship (R²?=?0.98). Also, the outlet concentration of mercury decreased with the increase of ACI rate in a nearly linear function (R²?=?0.96). These results will be meaningful for the rational use of AC for pollutants control.