紫木凼金矿开采过程中的环境效应:2.污染趋势分析

主要对紫木凼金矿区CN- 、As、Hg、Pb、Zn五个污染项目进行了趋势分析和污染预测。氰化物虽然是剧毒污染物 ,但它具有很强的自净降解作用 ,对矿区的污染影响不大 ,只是对于废液池的清洗外排必须先治理后排放。建立了As、Hg、Pb、Zn在各个污染途径中的定量分配模式。该模式表明 ,开采过程中As、Hg、Pb的大部分 ( 64 %以上 )进入废液池外排 ,其余的进入矿渣。在此基础上 ,对这些元素从 1 989年到 2 0 0 0年的开采总量、进入废液、土壤、积水坑的分量进行了计算 ,并给出了在堆场下伏粘土中各元素的饱和吸附量和开始外排的时间。     

黑色岩系中贵金属富集层的成因:来自固定铵的佐证

对湘黔地区（遵义、大庸）下寒武统牛蹄塘组黑色岩系的部分样品进行了Au、Ag、PGE、固定铵的分析，综合前人的资料进行了数据的对比和讨论，首次应用其中的固定铵来讨论了贵金属富集层的成因。     

Effects of cadmium on forearm bone density after reduction of exposure for 10 years in a Chinese population

The main focus of this study was to evaluate long term effects of cadmium on forearm bone mineral density after stopping ingestion of cadmium-polluted rice for 10 years in a Chinese population. A total of 532 persons (338 women and 194 men), living in control, moderately and heavily polluted areas, were included in this study. The residents living in the polluted area ceased ingesting cadmium-polluted rice in 1996. All participants were require to answer a questionnaire and the bone mineral density (BMD) was measured by dual energy X-ray absorptiometry (DXA) at the proximal radius and ulna. Samples of urine and blood were collected for determination of cadmium in urine (UCd) and blood (BCd).The BMD of subjects living in the heavily polluted area was significantly lower than that of those living in control area in both men and women (p < 0.01). For the people living in the moderately polluted area, only the women's BMD was greatly lower compared to that in the control area (p < 0.05). The BMD declined with the increasing BCd and UCd in both sexes, especially in the highest level (BCd > 5 µg/L, UCd > 10 µg/g crea) groups (p < 0.01). It was found that there were significant differences in the prevalence of osteoporosis among the different areas (χ² = 13.046, p = 0.0003) and different UCd groups (χ² = 4.511, p = 0.0337) in women, but not in men (χ² = 0.962, p = 0.3268; χ² = 1.906, p = 0.1675). But a significant difference exists in the prevalence of osteoporosis among different BCd groups in both genders (χ² = 9.304, p = 0.00229, in women; χ² = 4603, p = 0.0319, in men). This study suggested that cadmium could play a long-term role on bone and more attention should be paid to cadmium effects on bone metabolism after reduction of exposure.     

中国红色粘土型金矿成矿特征

中国的红色粘土型金矿是 90年代初发现并开始研究的 ,基本上产于南方特别是西南地区。由于特殊的地质构造条件和气候、地貌条件 ,该类型金矿与国外的红土型金矿存在明显的差异 :红色粘土型金矿剖面发育差 ,红土化程度低 ;对源岩依存度高 ;铁铝含量低、硅含量高 ;矿石处在富粘土矿物阶段 ,少见三水铝石 ,一般为伊利石和高岭石共存。金在红色粘土中以微细粒分散形式存在 ,且在红色粘土剖面中由于表生淋滤作用而发生活化、迁移和再沉淀。     

贵州典型电厂粉煤灰的放射性安全评估

贵州是华南最重要的煤电和粉煤灰生产省份,粉煤灰的放射性安全评估是综合利用的基础。对贵州不同产煤区域典型电厂粉煤灰进行了放射性核素比活度测定并根据国标GB6566-2001进行了安全性评估,结果表明:西部纳雍电厂粉煤灰内照射指数IRa和外照射指数Iγ均较低,使用范围不受限制;中部大方、金沙电厂和东部黔东电厂粉煤灰I_(Ra)较低而I_γ接近限值,可以作为建筑主体材料(其中大方一级灰仅限于空心率大于25%的主体材料)和A类装修材料;北部桐梓和二郎电厂粉煤灰I_(Ra)和I_γ均超出限值,分别可作为B类和C类装修材料,作为建筑主体材料应严格控制掺量比例。综合本次研究和前人数据,确证了粉煤灰中U、Th含量和相关放射性核素比活度具有良好相关性,推导了利用粉煤灰U、Th含量(C_U,C_(Th),×10~(-6))进行快速评估的经验公式:I_(Ra)=0. 0616×C_U+0. 0049;I_γ=0. 0341×C_U+0. 0159×C_(Th)+0. 0517。     

Study on ecological environment quality evaluation of the energy consumption pollution treatment in industrial parks

Environmental Science and Pollution Research - In order to explore the effective method of ecological environment quality evaluation the of environmental pollution treatment of energy consumption...     

紫木凼金矿开采过程中的环境效应:1.污染状况对比

金矿开采具有其独特的环境效应 ,特别是贵州等地的卡林型金矿 ,因为这种金矿富含As、Tl、Hg、Sb、Pb等有毒元素 ,而且矿区发育喀斯特地形 ,使这类金矿的开采具有“毒上加毒”的污染特征和“明暗相间”的污染扩散迁移特征。本文通过对紫木凼金矿从1 989年到 1 995年开采六年间土壤、地表水、地下水的监测项目的变化对比 ,证明了黄金生产造成了矿区土壤、地表水、地下水中CN- 、As、Hg、Pb、Zn等的增高 ,其中以对地表水的影响最大 ;确定了主要的污染源有采矿废石、矿渣及废液 ,主要污染物有CN- 、As、Hg、Pb和Zn ,由于矿区Tl的区域背景值较低 ,未造成Tl的二次污染。     

Low bone density and renal dysfunction following environmental cadmium exposure in China

This paper presents the main findings of a study on health effects of environmental cadmium pollution in China, performed in 1998, i.e. approximately 25 years after the first warnings of such effects were published in Ambio. Forearm bone mineral density (BMD) and renal dysfunction were assessed in population groups exposed to cadmium via rice. Decreased BMD was found in postmenopausal women with elevated urinary cadmium (CdU) or cadmium in blood (CdB) and among men with elevated CdB. Also, clear and statistically significant dose-effect and dose-response relationships were found between CdB or CdU and renal dysfunction (increased excretion of retinol-binding protein). This is the first report of bone effects among Cd-exposed population groups in Asia outside Japan. The report is also of interest since it demonstrates that bone effects, a comparatively severe adverse health effect of Cd, in combination with renal dysfunction, still occurs in environmentally exposed population groups in Asia. Recent reports on bone effects in Cd-exposed population groups in Europe are discussed.     

云南潞西上芒岗红色粘土型金矿地质特征

潞西上芒岗红色粘土型金矿赋存于下二叠统岩溶面之上的第三、第四系红色粘土层中 ,矿体形态受地形控制明显 ,呈似层状。品位较高 ,规模中等 ,适合于露天开采。矿体的红土化作用不彻底 ,去硅富铁铝能力低 ,常见高岭石与伊利石共生。矿石中石英、褐铁矿、粘土矿物为主要载金矿物。成矿物质来自燕山中晚期形成的中侏罗勐嘎组中段与二叠系的沙子坡组的断层接触破碎带内的卡林型金矿。在湿热条件下 ,金发生活化、迁移、富集 ,在潜水面附近成矿。     

Green finance,technological progress,and ecological performance—evidence from 30 Provinces in China

The interaction between green finance and other factors, such as ecological environment, has been a research hotspot nowadays. Especially, the reasonable guiding of capital into energy conservation and environmental protection industries would greatly affect those factors, so as to the relation between them. This paper aimed to analyze the relationships between green finance, technological progress, and ecological performance quantitatively. The entropy method was used to respectively construct the system of index for green finance and technological progress, and index for ecological performance was measured by the super-SBM model. The panel vector autoregressive (PVAR) model was selected to empirically analyze dynamic relationships based on datasets from 30 provinces in China during 2008–2019 period. The results told that (1) from 2008 to 2019, China’s overall level of green finance, technological progress and ecological performance increased to varying degrees. Spatially, the areas with high-developed green finance greatly coincided with those such as large cities or the eastern coast that had good financial development. The distribution of technological progress index were similar, except some underdeveloped areas with relatively advanced scientific research institutes. The ecological performance, however, was high in the South and low in the north. (2) In the lag for 3 years, the influence of green finance on ecological performance in different regions was all positive for that all the coefficient symbols that passed the significance test were above 0, while that on technological progress was negative first and then positive. And the effects of technological progress on ecological performance were positive in ecological regions and negative in low ecological regions (0.0893 and -0.1211 in the case of three-stage lag respectively). (3) The contribution of green finance to ecological performance was high according to the results of variance decomposition, maintained at about 30%, and that of technological progress increased year by year (from 0.000 to 0.039). Therefore, we proposed to strengthen the development of green finance in underdeveloped regions. The emphasis should be laid on the researches and applications of green technology, the formulation of financing policies in innovation compensation and the establishment of a dynamic monitoring system for the ecological environment.