Factors affecting TCLP lead leachability from computer CPUs

The factors impacting lead leachability from computer central processing units (CPUs) during the toxicity characteristic leaching procedure (TCLP) were investigated. Several CPUs were disassembled and their component materials were decreased in size to meet the requirements of the TCLP. The impact of CPU composition was examined by leaching different combinations of the CPU components. The ferrous metal content of the mixture greatly impacted lead leaching. TCLP lead concentrations of CPUs predicted by leaching the lead-bearing printed wire boards alone were much greater than those measured when the ferrous metal of the CPU was included in the mixture. The leaching of iron and zinc from the galvanized steel components of the CPU created electrochemical conditions where lead was less soluble. Additional size reduction beyond that required by the TCLP did not result in additional lead leaching. As the volume of head space above the leaching solution increased, the concentration of lead measured increased as well.     

Effects of Sorbent Injection on Participate Properties: Part I. Low-Temperature Sorbent Injection

Abstract

This article is the first of a two-part series dealing with the effects of sorbent injection processes on particulate properties. Part I reviews the effects on particulate properties of low-temperature sorbent injection processes (those processes that treat flue gas at temperatures near 300 °F). Part II reviews the effects on particulate properties of high-temperature sorbent injection processes (those processes that involve sorbent injection into the combustion or economizer sections of a boiler). In this article, we review what is currently known about the effects of the low-temperature sorbent injection processes on electrical resistivity, particulate mass loading, particulate size distribution, particulate morphology and cohesivity.

Mixtures of ash and sorbent produced by low-temperature sorbent injection processes are typically less cohesive than most types of fly ash. At temperatures within 30 °F of the water dew point, the combination of low cohesivity and low electrical resistivity of the ash and sorbent mixtures can cause electrical reentrainment in electrostatic precipitators. Deliquescent additives such as calcium chloride cause the water to be retained on the particle surface, thereby increasing cohesivity.

Sorbent injection has been reported to increase the particulate mass loading by a factor of 1.8 to 10, depending upon the reagent ratio and the coal sulfur content. Conventional and in-duct spray drying processes tend to shift the particle size distribution toward larger particles, while dry injection processes tend to shift the particle size distribution toward smaller particles.     

Filtration Properties of Fly Ash from Fluidized Bed Combustion

Some of the features of the fluidized-bed combustion (FBC) process have a direct bearing on the particulate properties that most strongly influence filtering pressure drop. A laboratory program was conducted to experimentally determine the relative pressure drop characteristics of ashes from the TVA-EPRI 20-MW bubbling bed, atmospheric pressure FBC (AFBC) pilot plant and six pulverized-coal combustion (PC) units. The combined influences of measured particle and dust cake properties on filtering pressure drop were estimated with existing filtration theories. These theories predict a higher pressure drop for a dust cake produced with the AFBC ash than for one consisting of any of the PC ashes. Laboratory measurements were made of the flow resistance of idealized, simulated dust cakes to confirm these predictions. Field operating data from the fabric filters collecting some of the tested ashes were available to validate the laboratory results. The laboratory and field data show relatively good agreement. The AFBC ash must be treated as a special case for fabric filters, and careful selection of cleaning method and fabric must be made to minimize the inherently high pressure drop characteristics of this ash.     

Status and Future of Baghouses in the Utility Industry

Abstract

The cumulative years of service of baghouses in the electric utility industry have doubled since the last industrywide review of their operating performance. We have gathered information from all 102 operating baghouses to develop an updated record of how this technology continues to serve the electric utility industry. In general, baghouse performance has met or exceeded the expectations for controlling emissions. There are, however, wide ranges of pressure drop and bag life performance. Most operators report a long-term trend of increasing pressure drop. The life expectancy of filter bags averages 7.5 years, with more than 20% of the population achieving more than 10 years of bag life. Factors such as coal and ash properties certainly affect baghouse operation, but another reason for variations in bag life is the lack of an optimized protocol for controlling the long-term buildup of residual dustcake. We conclude that many baghouses could operate with lower pressure drop and longer bag life by optimizing the cleaning system. Dustcake weight or drag are better indicators of performance than pressure drop and should be used to develop an optimum baghouse operating protocol.     

Determination of Baghouse Performance from Coal and Ash Properties: Part II

Baghouse performance at utility coal-fired power plants is determined by baghouse design, operating procedures, and the characteristics of the ash that is collected as a dustcake on the fabric filter. The Electric Power Research Institute has conducted laboratory research to identify the fundamental variables that influence baghouse performance. A database was assembled including measured characteristics of coal and dustcake ash, and data describing operating parameters and performance of full-scale and pilotscale baghouses. Predictions of performance can be based on physical characteristics of the ash to be filtered (discussed in Part I of this article), as well as chemical characterizations of the ash, or empirical correlations with the alkali content of the source coal The effects of design and operational variables can be included in these predictions. Baghouse performance can be optimized by exercising proper operating practices and by selecting a filtering fabric and cleaning method matched to the cohesivity of the ash to be collected.     

Productivity responses of Acer rubrum and Taxodium distichum seedlings to elevated CO2 and flooding

Elevated levels of atmospheric CO2 are expected to increase photosynthetic rates of C3 tree species, but it is uncertain whether this will result in an increase in wetland seedling productivity. Separate short-term experiments (12 and 17 weeks) were performed on two wetland tree species, Taxodium distichum and Acer rubrum, to determine if elevated CO2 would influence the biomass responses of seedlings to flooding. T. distichum were grown in replicate glasshouses (n = 2) at CO2 concentrations of 350 or 700 ppm. and A. rubrum were grown in growth chambers at CO2 concentrations of 422 or 722 ppm. Both species were grown from seed. The elevated CO2 treatment was crossed with two water table treatments, flooded and non-flooded. Elevated CO2 increased leaf-level photosynthesis, whole-plant photosynthesis, and trunk diameter of T. distichum in both flooding treatments, but did not increase biomass of T. distichum or A. rubrum. Flooding severely reduced biomass, height, and leaf area of both T. distichum and A. rubrum. Our results suggest that the absence of a CO2-induced increase in growth may have been due to an O2 limitation on root production even though there was a relatively deep (approximately 10 cm) aerobic soil surface in the non-flooded treatment.     

Determination of Baghouse Performance from Coal and Ash Properties: Part I

Baghouse performance at utility coal-fired power plants is determined by baghouse design, operating procedures, and the characteristics of the ash that is collected as a dustcake on the fabric filter. The Electric Power Research Institute has conducted laboratory research to identify the fundamental properties of dustcake ash that influence baghouse performance. A database was assembled including measured characteristics of dustcake ash and data describing operating parameters and performance of full-scale and pilot-scale baghouses. Semi-empirical models were developed that describe the effects of particle morphology, particle size, ash cohesivity and ash chemistry on filtering pressure drop and particulate emissions. Cohesivity was identified as the primary ash characteristic affecting baghouse performance. Predictions of performance can be based on physical or chemical characterizations of the ash to be filtered. Part II of this article will discuss the effects of ash and coal chemistry, and baghouse design and operation on performance.     

EFFECTS OF SALINITY ON PREFERRED AND LETHAL TEMPERATURES OF THE BLACKCHIN TILAPIA,SARATHERODON MELANOTHERON1

Acclimation to varying salinities did not affect the preferred temperature of Saratherodon melanotheron, which had a final preferred temperature of 33.5 C. However, fish acclimated to 25 C and 0, 15, and 30 o/oo salinities had lower lethal temperatures of 15, 13, and 15 C, respectively, and an upper lethal temperature of 37 C. The thermal zone of tolerance for fish acclimated in freshwater was 17-35 C, and was not dependent upon acclimation temperatures. Data suggest this species could expand its range in North America.