排序方式: 共有48条查询结果,搜索用时 15 毫秒
1.
Ester Heath Marjeta Česen Noelia Negreira Miren Lopez de Alda Laura Ferrando-Climent Lucie Blahova Tung Viet Nguyen Mohamed Adahchour Achim Ruebel Neville Llewellyn Janez Ščančar Srdjan Novaković Vesna Mislej Marjeta Stražar Damià Barceló Tina Kosjek 《Environmental science and pollution research international》2016,23(15):14692-14704
The results of an inter-laboratory comparison exercise to determine cytostatic anticancer drug residues in surface water, hospital wastewater and wastewater treatment plant effluent are reported. To obtain a critical number of participants, an invitation was sent out to potential laboratories identified to have the necessary knowledge and instrumentation. Nine laboratories worldwide confirmed their participation in the exercise. The compounds selected (based on the extent of use and laboratories capabilities) included cyclophosphamide, ifosfamide, 5-fluorouracil, gemcitabine, etoposide, methotrexate and cisplatinum. Samples of spiked waste (hospital and wastewater treatment plant effluent) and surface water, and additional non-spiked hospital wastewater, were prepared by the organising laboratory (Jo?ef Stefan Institute) and sent out to each participant partner for analysis. All analytical methods included solid phase extraction (SPE) and the use of surrogate/internal standards for quantification. Chemical analysis was performed using either liquid or gas chromatography mass (MS) or tandem mass (MS/MS) spectrometry. Cisplatinum was determined using inductively coupled plasma mass spectrometry (ICP-MS). A required minimum contribution of five laboratories meant that only cyclophosphamide, ifosfamide, methotrexate and etoposide could be included in the statistical evaluation. z-score and Q test revealed 3 and 4 outliers using classical and robust approach, respectively. The smallest absolute differences between the spiked values and the measured values were observed in the surface water matrix. The highest within-laboratory repeatability was observed for methotrexate in all three matrices (CV?≤?12 %). Overall, inter-laboratory reproducibility was poor for all compounds and matrices (CV 27–143 %) with the only exception being methotrexate measured in the spiked hospital wastewater (CV?=?8 %). Random and total errors were identified by means of Youden plots. 相似文献
2.
3.
Furtula V Derksen G Colodey A 《Journal of environmental science and health. Part. B》2006,41(8):1259-1271
A new approach to surface water analysis has been investigated in order to enhance the detection of different organic contaminants in Nathan Creek, British Columbia. Water samples from Nathan Creek were prepared by liquid/liquid extraction using dichloromethane (DCM) as an extraction solvent and analyzed by gas chromatography mass spectrometry method in scan mode (GC-MS scan). To increase sensitivity for pesticides detection, acquired scan data were further analyzed by Automated Mass Spectrometry Deconvolution and Identification Software (AMDIS) incorporated into the Agilent Deconvolution Reporting Software (DRS), which also includes mass spectral libraries for 567 pesticides. Extracts were reanalyzed by gas chromatography mass spectrometry single ion monitoring (GC-MS-SIM) to confirm and quantitate detected pesticides. Pesticides: atrazine, dimethoate, diazinone, metalaxyl, myclobutanil, napropamide, oxadiazon, propazine and simazine were detected at three sampling sites on the mainstream of the Nathan Creek. Results of the study are further discussed in terms of detectivity and identification level for each pesticide found. The proposed approach of monitoring pesticides in surface waters enables their detection and identification at trace levels. 相似文献
4.
Ivana Trbojević Jelena Jovanović Dušan Kostić Slađana Popović Dragana Predojević Vesna Karadžić Gordana Subakov Simić 《Russian Journal of Ecology》2018,49(2):135-142
The aim of this study was to assess the effect of substrate type and incubation depth on periphyton that had developed on artificial substrates. Uniform rectangular tiles made out of artificial substrates: glass, ceramic, willow tree and yew tree, were fixed on a floating buoy and deployed at three different depths in a photic zone of the Sava Lake (Belgrade, Serbia). Non-taxonomic attributes in the developed biofilm were estimated week-by-week from the start of the experiment in July, until its end in September 2014. Through assessment of substrate type and depth of incubation effect we concluded that these parameters for the fact influence periphyton development and composition. Glass was preferred by autotrophic component over ceramic and wooden substrates. In general, substrate type effect was diminished by increasing incubation depth. When non-taxonomic parameters are to be used in biomonitoring studies, our results suggest that glass substrate and shallow layer of water column (up to 50 cm) for incubation should be preferred. 相似文献
5.
Du?ica Ili? Ivan S. Risti? Ljubi?a Nikoli? Mihajlo Stankovi? Goran Nikoli? Ljiljana Stanojevi? Vesna Nikoli? 《Journal of Polymers and the Environment》2012,20(1):80-87
In this work was described poly(d,l-lactide) microwave synthesis using tin(II) 2-ethylhexanoate initiated ring-opening polymerization. Polymerization was performed
at 100 °C with monomer to initiator molar ratio ([M]/[I]) of 5,000 in 30 min. The achieved number average molar mass of obtained
polymers (determined by gel permeation chromatography) was 102,320 g/mol, with the polydispersion index, Q, 2.80. Structural characterization was performed by FT-IR spectroscopy followed characteristic bands. For applicative purposes
the obtained polymer was purified during the procedure of microsphere preparation. Biodegradable microspheres prepared from
poly(d,l-lactide) have been widely studied in recent years and have become well established controlled drug delivery systems. In this
work microspheres were loaded with allyl thiosulfinate (allicin) and its transforments products (ajoene and vinyldithiine),
as pharmacological active substances. The morphology of the microspheres was analyzed using a scanning electron microscope.
Allicin was synthesized by acid oxidation of allyl disufide and purification of obtained products by liquid–liquid extraction
with diethyl ether. Obtained allicin, purity 73%, was transformed using microwave in acetone solution, at solvent boiling
temperature, for 5 min. For the quality and quantity analysis of allicin and its transformation process was used LC/MS chromatography.
(E)- and (Z)-ajoene were detected at retention time 3.1 and 3.3 min, respectively, whence 3-vynil-4H-1,2-dithiine and 2-vynil-4H-1,3-dithiine
were detected at 4.3 and 4.8 min, respectively. Retention time of allicin was 2.93 min, according to liquid chromatography
results. HPLC method was used for assessment of pharmaceutical substances (alicine and alicine transforments) releasing from
microspheres at room temperature in solutions with different pH (pH = 3 and pH = 8) for 24 h. 相似文献
6.
Ljubica Župunski Vesna Spasić-Jokić Mirjana Trobok Vojin Gordanić 《Environmental science and pollution research international》2010,17(9):1574-1580
Purpose
The purpose of this paper is to assess fatal cancer risk after external and internal (inhalation and ingestion) exposure from natural radionuclides in soil like 238U, 232Th, 40K, and 226Ra on the territory of Bela Crkva, Serbia. Although receiving doses are low from sources like natural radionuclides in soil, because of stochastic effects of ionizing radiation, risk for developing cancer exists and can be quantified. 相似文献7.
8.
Inclusion of vegetable oils in Fenton's chemistry for remediation of PAH-contaminated soils 总被引:11,自引:0,他引:11
Pre-treatment with vegetable oils prior to treatment with Fenton's reagent led to increased oxidation by the latter of polycyclic aromatic hydrocarbons (PAHs) in a pair of model manufactured gas plant soils. This effect was frequently most pronounced in the cases of high-molecular-weight (HMW) PAH species, indicating a preferential "targeting" of oxidative equivalents toward these compounds. In both cases, addition of oils--either corn oil containing unsaturated lipids or palm kernal oil (PKO) comprised primarily of saturated fats--at the 5% dosage was required; supplementation with 1% oil apparently did not sufficiently facilitate PAH desorption and mass-transfer to have a notable effect on degradation efficiency. In PKO-supplemented reactions, replacement of H2O2 with calcium peroxide (CaO2) further increased the extent of PAH removal. Again, this was most pronounced in the cases of several HMW PAHs; among a suite of four 5- and 6-ring PAH (benzo[a]pyrene, dibenz[a, h]anthracene, benzo[g, h, i]perylene and indeno[c, d]pyrene), average removal efficiency increased from 5% in PKO-supplemented reactions in which H2O2 served as the oxidant, compared to 44% in CaO2-containing reactions. This last finding is consistent with other reports which have indicated that slower-release oxidants are better suited to degradation of contaminants which, despite vegetable oil treatment, remain soil-sorbed. 相似文献
9.
Vesna Zupanc Martina ŠturmSonja Lojen Nina Marši?-KacjanJoseph Adu-Gyamfi Branka Bra?i?-?eleznikJanko Urbanc Marina Pintar 《Agriculture, ecosystems & environment》2011,144(1):167-174
In the search for new technologies that would ensure optimum yield and environmental sustainability, various irrigation, nitrogen and cropping system management strategies for the production of vegetables with a shorter growing period were assessed at a benchmark site in Slovenia for the years 2006 and 2007. In the studied years four irrigation and fertilization treatments were applied: (1) 50% drip irrigation of plants water requirements ETcrop and the farmer's practice of fertilisation (broadcasting), (2) fertilisation and 100% drip irrigation (fertigation), (3) the farmer's practice of irrigation (sprinkler irrigation using water stored in plastic tanks) and fertilisation, and (4) control (the farmer's practice of irrigation but no fertilisation). An equivalent of 80, 80 and 200 kg ha−1 of nitrogen (N), 50, 50 and 80 kg ha−1 of phosphorous (P) and 120, 120 and 300 kg ha−1 of potassium (K) was added for iceberg lettuce, endive and cabbage, respectively. Nitrogen (N) labelled fertilizer (15N) was applied to trace the movement of the applied N fertiliser. The tested irrigation and fertilisation techniques for the production of vegetables with a shorter growing period in the Slovenian climate showed that environmentally sustainable practices (split application of nutrients compared to broadcast incorporating fertilisation) should be a practice of choice in water protection zones. The results confirm that fertigation and improved irrigation scheduling can be an effective way of minimizing nitrate leaching, and should be considered for vegetable production in or close to groundwater protection zones. 相似文献
10.
Lojpur Vesna Krstić Jelena Kačarević-Popović Zorica Filipović Nenad Validžić Ivana Lj. 《Environmental Chemistry Letters》2018,16(2):659-664
Environmental Chemistry Letters - Producing green and efficient energy sources is a major challenge. As a consequence, the use of photovoltaic devices for conversion of light into electricity is... 相似文献