Analysis of BTEX and other substituted benzenes in water using headspace SPME-GC-FID: method validation

The analysis of BTEX and other substituted benzenes in water samples using solid phase microextraction (SPME) and quantification by gas chromatography with flame ionization detection (GC-FID) was validated. The best analytical conditions were obtained using PDMS/DVB/CAR fibre using headspace extraction (HS-SPME) at 50 [degree]C for 20 min without stirring. The linear range for each compound by HS-SPME with GC/FID was defined. The detection limits for these compounds obtained with PDMS/DVB/CAR fibre and GC/FID were: benzene (15 ng L(-1)), toluene (160 ng L(-1)), monochlorobenzene (54 ng L(-1)), ethylbenzene (32 ng L(-1)), m-xylene (56 ng L(-1)), p-xylene (69 ng L(-1)), styrene (35 ng L(-1)), o-xylene (42 ng L(-1)), m-dichlorobenzene (180 ng L(-1)), p-dichlorobenzene (230 ng L(-1)), o-dichlorobenzene (250 ng L(-1)) and trichlorobenzene (260 ng L(-1)). This headspace SPME-GC-FID method was compared with a previously validated method of analysis using closed-loop-stripping analysis (CLSA). The headspace SPME-GC-FID method is suitable for monitoring the production and distribution of potable water and was used, in field trials, for the analysis of samples from main intakes of water (surface or underground) and from the water supply system of a large area (Lisbon and neighbouring municipalities).     

Predictors of willingness to relocate for managerial and professional employees

This study explored possible determinants, both inside and outside the job sphere, of willingness to relocate. Data were collected from a large sample of managerial and professional employees in one organization. Unlike previous research, this study investigated willingness to relocate for three different purposes: (1) for a better job or career development; (2) to help the organization; or (3) to remain employed. However, only two factors of willingness to relocate emerged: willingness to relocate for career enhancement or company needs, and willingness to relocate to remain employed. Results showed that the strongest predictors of willingness to relocate to remain employed were job sphere variables such as satisfaction with career development opportunities and propensity to remain, while family and community variables were much more important in predicting willingness to relocate for career enhancement or company needs. The implications of these results for both the organization and individuals are discussed.     

Protestant work ethic,work involvement and the psychological impact of unemployment

This study is an attempt to replicate and extend recent findings concerning the moderating effect of employment commitment on the psychological impact of unemployment. It was carried out in a highly educated population and employed Protestant work ethic endorsement (PWE) and work involvement (WINV) as indicators of commitment to work. Evidence was collected by questionnaires from 432 individuals who had been unemployed and again, six months later, from most of the same individuals. Cross-sectional and longitudinal analysis shows that individuals with high WINV were likely to suffer more from unemployment and to gain more from finding employment than low work-involved individuals. PWE, on the other hand, did not moderate the relationship between employment status and psychological state.     

A study of cross-cultural differences in work attitudes among three groups of Israeli prison employees

The study investigated differences in work attitudes among three cultural groups of Israeli prison officers: Druze (N = 83), Jews of North African origin (N = 127) and Jews of Georgian origin (N = 96). Several hypotheses were derived from previous knowledge of the three cultures and differences were explored in the relationships between perceptions and attitudes concerning specific aspects of the job on the one hand, and two measures of overall affective responses—general job satisfaction and tedium—on the other hand. Consistent cross-cultural differences that can be related to characteristics of the studied cultures were revealed only with regard to satisfaction with promotion and to role ambiguity. No other coherent and meaningful cross-cultural differences could be identified. The theoretical and practical significance of these results is discussed and a general direction for future studies in this area is recommended.     

E-participation for environmental sustainability in transitional urban China

Using information and communication technologies (ICTs), e-participation is a tool that promotes the inclusion of the public in participative and deliberative decision-making processes, thus contributing to a transformation of the interaction between government and citizens in environmental governance and sustainable development. In a number of Chinese cities, citizens increasingly draw on ICTs to promote environmental sustainability and to encourage community-based actions aimed to address various environmental concerns. The potential success of e-participation and the role of ICTs in China has, however, not been well explored. The objective of this study is to understand the role that ICTs can play in promoting public participation about environmental sustainability issues in urban China. Based on an online survey with 630 respondents, the study aims to: (1) analyze what public motivations, perception/attitudes and actions drive environmental e-participation; (2) identify barriers to e-participation, and (3) assess the different applications and functions of ICT for citizen participation in environmental sustainability. The analysis illustrates how ICTs have helped the public to obtain sensitive information about sustainability issues, to mobilize people and to gain media coverage for their actions. The central finding is that new technologies have taken citizen engagement to new heights online. More specifically, the age of ICTs has unleashed a stronger public voice on environmental governance and sustainability issues in urban China, which does not go unnoticed by the Chinese state authorities.     

The relationships between career concerns and political tactics in organizations

The study examined the relationships between four career concerns (Personal Success, Organizational Involvement, Skill Development and Autonomy) and two categories of political tactics in organizations (Hierarchical Tactics and Networking Tactics) in a sample of management school alumni. Career concerns were not related to the employment of hierarchical tactics but were strongly related to the use of networking tactics. ‘External’ career concerns of personal success and organizational involvement were more strongly related to political behavior than ‘internal’ career concerns of skill development and autonomy. Organization size was significantly related to the use of hierarchical tactics but not to the use of networking tactics. Type of organization structure (mechanistic versus organic) did not have a direct effect on political behavior but moderated the relationships between career concerns and political tactics. These relationships were stronger in organic than in mechanistic organizations.     

Transparency in global sustainability governance: to what effect?

ABSTRACT

Transparency in environmental governance is no longer an uncontroversial answer to problems of accountability and effectiveness. How to design effective transparency systems and in what policy contexts they are effective remain contested issues. This special section, consisting of this introduction and four research articles, interrogates complex and potentially conflicting links between transparency, accountability, empowerment and effectiveness in environmental governance. Building on existing literature and the four contributions, we discuss persisting diversity in varieties of transparency, the evolving dynamics of commodity chain transparency, and the consequences of emerging novel forms of digitalized transparency. As we show, the contributions to this special section interrogate in novel ways the transformative potential of transparency, through shedding light on the performative effects of transparency in ever more complex environmental governance contexts. These contexts may include, inter alia, the growing ubiquity of traceability in transnational commodity chains, the need for ever more anticipatory (ex-ante) forms of environmental governance, and an ever-broadening quest for digitally monitored environments. In particular, the impacts of the real-time ‘radical’ transparency engendered by use of novel digital technologies remain under-analyzed in the sustainability domain. We conclude by raising several critical concerns that deserve further scientific research and policy debate.     

Trace elements in sediments in a city with agricultural development

The objective of this study was to determine the concentrations of trace elements in sediment samples taken from impermeable urban areas of a city with predominantly agroindustrial development characteristics. For this, samples were taken every month from paved streets in the city of Toledo, Paraná State (PR), Brazil. Thus, trace element levels were obtained through analysis performed by optical emission spectrometry with inductively coupled plasma. Levels of total organic carbon were also obtained through the dry combustion method. When compared to local background levels, the trace element levels were shown to be enriched in the following percentage proportions: barium (Ba) (45.4%), copper (Cu) (48.6%), chromium (Cr) (37.2%), manganese (Mn) (81.6%), nickel (Ni) (0%), lead (Pb) (40%), zinc (Zn) (283.7%), magnesium (Mg) (34.3%), and sodium (Na) (250.2%), whereas the carbon (C) percentages were around 1%. The most significant enrichment factors occurred for Ba, Cr, Pb, Zn, Mg, and Na. The highest rates occurred in geoaccumulation where the sediments were enriched by zinc. According to the principal guidelines, the concentrations obtained for cadmium (Cd), Cr, Cu, Ni, and Zn can cause adverse environmental impacts.