The sources of submicrometer particulate matter (PM1) remain poorly characterized in the industrialized city of Houston, TX. A mobile sampling approach was used to characterize PM1 composition and concentration across Houston based on high-time-resolution measurements of nonrefractory PM1 and trace gases during the DISCOVER-AQ Texas 2013 campaign. Two pollution zones with marked differences in PM1 levels, character, and dynamics were established based on cluster analysis of organic aerosol mass loadings sampled at 16 sites. The highest PM1 mass concentrations (average 11.6 ± 5.7 µg/m3) were observed to the northwest of Houston (zone 1), dominated by secondary organic aerosol (SOA) mass likely driven by nighttime biogenic organonitrate formation. Zone 2, an industrial/urban area south/east of Houston, exhibited lower concentrations of PM1 (average 4.4 ± 3.3 µg/m3), significant organic aerosol (OA) aging, and evidence of primary sulfate emissions. Diurnal patterns and backward-trajectory analyses enable the classification of airmass clusters characterized by distinct PM sources: biogenic SOA, photochemical aged SOA, and primary sulfate emissions from the Houston Ship Channel. Principal component analysis (PCA) indicates that secondary biogenic organonitrates primarily related with monoterpenes are predominant in zone 1 (accounting for 34% of the variability in the data set). The relevance of photochemical processes and industrial and traffic emission sources in zone 2 also is highlighted by PCA, which identifies three factors related with these processes/sources (~50% of the aerosol/trace gas concentration variability). PCA reveals a relatively minor contribution of isoprene to SOA formation in zone 1 and the absence of isoprene-derived aerosol in zone 2. The relevance of industrial amine emissions and the likely contribution of chloride-displaced sea salt aerosol to the observed variability in pollution levels in zone 2 also are captured by PCA.
Implications: This article describes an urban-scale mobile study to characterize spatial variations in submicrometer particulate matter (PM1) in greater Houston. The data set indicates substantial spatial variations in PM1 sources/chemistry and elucidates the importance of photochemistry and nighttime oxidant chemistry in producing secondary PM1. These results emphasize the potential benefits of effective control strategies throughout the region, not only to reduce primary emissions of PM1 from automobiles and industry but also to reduce the emissions of important secondary PM1 precursors, including sulfur oxides, nitrogen oxides, ammonia, and volatile organic compounds. Such efforts also could aid in efforts to reduce mixing ratios of ozone. 相似文献
This paper presents results of source size distribution measurements over the size range from 0.1 μm to 5 μm for six classes of particulate sources and fractional efficiency measurements on five full scale electrostatic precipitators and one pilot scale precipitator. The precipitators all showed moderately high to high particulate collection efficiencies for particles having diameters larger than a few micrometers or smaller than a few hundredths of a micrometer and a minimum in collection efficiency for particles having diameters of a few tenths of a micrometer. 相似文献
Three natural nonaggregated soil samples, with similar grain-size distributions, have been used to determine the dispersive behavior of porous media under steady, saturated and unsaturated flow conditions. Tritium was used as a tracer and was found to have no sorption on the solid matrix. Generated breakthrough curves (BTCs) for the unsaturated experiments were symmetrical with no evidence of tailing. The unsaturated experiments for two of the soils were adequately described by considering all the water in the pore volume as mobile. However, about 10% of the pore water, independent of the degree of saturation, was found to be immobile in the case of the third soil during unsaturated flow. For this soil, there was no mass transfer between the two water regions, indicating that the immobile water is essentially isolated from the flowing water fraction. For all three soils, dispersivity under unsaturated conditions was found to be higher, independent of the degree of water saturation, than the value determined for the saturated experiments. This is inconsistent with what would be expected from the simple bundle-of-capillary-tubes model and does not agree well with a more sophisticated conceptualization of the porous medium. The data, however, clearly indicate a wider range in pore-water velocities when these soils are desaturated. 相似文献
Black carbon (BC) was measured every 5 min for two years (May 1998-May 2000) inside and immediately outside a northern Virginia house (suburban Washington, DC) occupied by two nonsmokers. Two aethalometers, which measure BC by optical transmission through a quartz fiber tape, were employed indoors and outdoors. Meteorological parameters were obtained on an hourly basis from nearby Dulles airport. Indoor activities were recorded to identify indoor sources such as combustion activities, which occurred 9% of the time during the first year and 4% of the time during the second year. At times without indoor sources, indoor/outdoor BC ratios averaged 0.53 in the first year and 0.35 in the second year. The main outdoor source of BC was the general regional background, contributing 83-84% of the total during each of the two years. Morning rush hour traffic contributed 8-9% of the total BC. An evening peak in the fall and winter, thought to include contributions from wood burning, was responsible for approximately 8% of the annual average BC concentration. The main indoor sources of BC were cooking and candle burning, contributing 16 and 31%, respectively, of the annual average indoor concentrations in the two years. Relative humidity (RH) affected the outdoor aethalometer in both years. An artifact associated with the tape advance was noted for the aethalometer, but a correction factor was developed that reduced the associated error by a factor of 2. 相似文献
Theories of particle charging based on boundary value solutions to the diffysional equation may not be applicable to electrostatic precipitators where the ion density is rarely more than an order of magnitude greafer than the particle concentration. A new charging equation, based on kinetic theory, is presented which evaluates the charging rate in terms of the probability of collisions between the flust particles and ions. In the presence of an external electric field, the surface of the particle is divided into three charging regions, and separate charging rates are calculated for each region. The total charging rate is the sum of these three individual rates. For large particles and high electric fields, this theory predicts essentially the same charging rate as the classical field charging equation of Rohmann and Pauthenier. For low electric fields, the theory reduces to White’s diffusional charging equation. Agreement is within 25% of Hewitt’s experimental results over the entire range of variables where data are available. For practical charging times, agreement is within 15%. 相似文献
Ecosystem disturbances produce changes in macrobenthic community structure (abundances, biomass, and production) that persist
for a few weeks to many decades. Examples of disturbances with extremely long-term effects on benthic communities include
contamination by persistent toxic agents, physical changes in habitats, and altered energy inputs. Stream size, retention,
and local geomorphology may ameliorate the influence of disturbances on invertebrates. Disturbances can alter food webs and
may select for favorable genotypes (e.g., insecticidal resistance). Introductions of pesticides into lotic ecosystems, which
do not result in major physical changes within habitats, illustrate several factors that influence invertebrate recovery time
from disturbance. These include: (1) magnitude of original contamination, toxicity, and extent of continued use; (2) spatial
scale of the disturbance; (3) persistence of the pesticide; (4) timing of the contamination in relation to the life history
stages of the organisms; (5) vagility of populations influenced by pesticides; and (6) position within the drainage network.
The ability of macroinvertebrates to recolonize denuded stream habitats may vary greatly depending on regional life histories,
dispersal abilities, and position within the stream network (e.g., headwaters vs larger rivers). Although downstream drift
is the most frequently cited mechanism of invertebrate recolonization following disturbance in middle- and larger-order streams,
evidence is presented that shows aerial recolonization to be potentially important in headwater streams. There is an apparent
stochastic element operating for aerial recolonization, depending on the timing of disturbance and flight periods of various
taxa. Available evidence indicates that recolonization of invertebrate taxa without an aerial adult stage requires longer
periods of time than for those that possess winged, terrestrial adult stages (i.e., most insects). Innovative, manipulative
experiments are needed in order to address recolonization mechanisms of animals inhabiting streams that differ in size, latitude,
disturbance frequency and magnitude, as well as the potential influence of early colonists on successional sequences of species
following disturbance. 相似文献
In recent years, an increasing number of regulations and methodologies have begun to utilize total organic carbon (TOC) analysis for monitoring microbial contamination and/or disinfectant byproduct (DBP) precursors. This paper highlights some analytical differences and similarities between the two widely used TOC oxidation techniques: UV persulfate and high temperature combustion (HTC). Previous papers have come to different and sometimes contradictory conclusions on this subject. However, these studies either compared instruments with significantly different flow paths or TOC systems from different eras. Unlike previous studies, this paper compares two modern TOC analyzers with nearly identical flow paths for sample recovery, detection limits, and analysis of real world samples. On average, both persulfate and HTC oxidation yielded good recoveries for 10 hard to oxidize compounds and potable water samples from 5 different locations across the USA. In general, persulfate yielded more precise results because of its lower background response relative to sample response while HTC gave slightly higher results (roughly 2% to 3%) for surface water samples. 相似文献
ABSTRACT: Critical design characteristics of ephermal runoff such as hydrograph rise time, duration, mean peak discharge, volume, peak-volume ratio, and maximum flood were related to physical basin parameters such as area, shape, slope, drainage density, basin relief, stream length, and combinations of these in intermontane watersheds representative of the Mexican Highland section of the Basin and Range Province. Parameters used were restricted to those easily obtainable from maps or aerial photographs. A parameter expressing basin shape and size was developed which proved to be as accurate a predictor as others used in existing prediction equations tested and was simpler and faster to derive. Simple prediction equations derived for hydrograph characteristics were all significant except for volume at the 5% level; three were significant at the 1% level. Relationships determined are applicable in semi-arid basins of the Southwest up to 60 square miles (155 km2) in area. 相似文献