Environmental Science and Pollution Research - Phosphogypsum (PG) is a solid waste product of the wet-process phosphoric acid industry that accumulates in large amounts on the ground, forming PG... 相似文献
The deformation of microstructure of tailings caused by seepage is the main factor that leads the tailings dam to be damaged and lose stability. The effect of seepage on microstructure of tailings has been studied by a self-made observation testing apparatus of micro-mechanics and deformation of tailings, and its mechanism also has been explained in mechanics of particulate matter. The results show that the deformation response to microstructure of tailings is fast under load. The settlement of sample increases stepwise. Firstly, the fine particles crumble, then skeleton particles move, so as to noticeable settlement. Because the loose particles migrate taken by seepage water, the upper pores become bigger and lower pores become smaller. The relation of seepage water and settlement changing with time could be divided into two stages. In each stage, the rates of seepage and settlement reduce with time, and between the two stages, the rate of settlement increases significantly and the rate of seepage reduces with time. The seepage has significant effect on the particle size distribution of tailings in different depths, which has a little effect on the coarse tailings; the proportion of fine tailings increases significantly with the depth increasing; the minimum particle size decreases gradually and median diameter reduces stepwise with the depth increasing. 相似文献
The removal of thallium ions in flue gas desulfurization wastewater from ferrous metallurgic industry was studied by emulsion liquid membrane (ELM) method using 2-ethylhexyl phosphoric acid-2-ethylhexyl ester (P507) as carrier, aviation kerosene (AK) as organic solvent, polyisobutylene succinimide (T154) as surfactant, polyisobutylene (PIB) as additive, and sulfuric acid as internal reagent. Some important influence parameters such as concentrations of carrier, surfactant and stripping agent, agitation speed, extraction time, volume ratios of feed solution to emulsion phase and internal phase to membrane phase, and their effects on the removal efficiency of Tl in the ELM process were investigated and optimized. Under the optimum operating conditions of 2% of carrier, 5% of surfactant, 0.5 M of stripping agent, 350 rpm of agitation speed, 12.5:1 of volume ratio of feed solution to emulsion phase, and 3:1 volume ratio of membrane to internal phase, the maximum extraction efficiency of thallium reached 99.76% within 15-min reaction time. The ICP-MS analysis indicated that the thallium concentration in treated wastewater was below 5 μg/L and could meet the emission standard demand for industrial wastewater enacted by the local government of Hunan province of China. Meanwhile, the extraction of impurity ions calcium and magnesium in the ELM system was investigated. The result showed that an acidic environment would be in favor of the removal of Tl from calcium and magnesium contained in wastewater.