Speciation and leachability of copper in mine tailings from porphyry copper mining: influence of particle size

Mine tailing from the El Teniente-Codelco copper mine situated in VI Region of Chile was analysed in order to evaluate the mobility and speciation of copper in the solid material. Mine tailing was sampled after the rougher flotation circuits, and the copper content was measured to 1150 mg kg (-1) dry matter. This tailing was segmented into fractions of different size intervals: 0-38, 38-45, 45-53, 53-75, 75-106, 106-150, 150-212, and >212 microm, respectively. Copper content determination, sequential chemical extraction, and desorption experiments were carried out for each size interval in order to evaluate the speciation of copper. It was found that the particles of smallest size contained 50-60% weak acid leachable copper, whereas only 32% of the copper found in largest particles could be leached in weak acid. Copper oxides and carbonates were the dominating species in the smaller particles, and the larger particles contained considerable amounts of sulphides.     

Emission study of a diesel engine fueled with higher alcohol-biodiesel blended fuels

This work examines the effect of butanol (higher alcohol) on the emission pattern of neat neem oil biodiesel (NBD100) fueled diesel engine. Single-cylinder, 4-stroke, research diesel engine was employed to conduct the trial. Blends comprising the mixture of biodiesel and higher alcohol were prepared by employing an ultrasonic agitator. Four test fuels such as neat neem oil biodiesel, diesel, and two blends of higher alcohol/neem oil biodiesel: 10% and 20% (by volume). Experimental result showed that increasing alcohol content to biodiesel brought down the various emissions such as Smoke, NO_x, HC, and CO by 6.8%, 10.4%, 8.6%, and 5.9%, respectively, at all loads. It was also concluded from the trail that a 20% higher alcohol/neem oil biodiesel blends show the promising signs in reducing all the emissions associated with biodiesel fuelled diesel engine.