Photocatalytic activity of TiO2 containing anatase nanoparticles and rutile nanoflower structure consisting of nanorods

A series of TiO2 with different crystal phases and morphologies was synthesized via a facile hydrothermal process using titanium nbutoxide and concentrated hydrochloric acid as raw materials. The photocatalytic activity of the samples was evaluated by degradation of Methyl Orange in aqueous solution under UV-Visible light irradiation. On the basis of detailed analysis of the characterizing results of high-resolution transmission electron microscopy, X-ray powder diffraction measurements, X-ray photoelectron spectroscopy and Brunauer-Emmett-Teller measurement, it was concluded that the photo-activity of the catalyst is related directly to the 3D morphology and the crystal phase composition. An excellent catalyst should have both a futile 3D flower-like structure and anatase granulous particles. The 3D flower-like structure could enhance light harvesting, as well as the transfer of reactant molecules from bulk solution to the reactive sites on TiO2. In addition, the optimum anatase/rutile phase ratio was found to be 80：20, which is beneficial to the effective separation of the photogenerated electron-hole pairs.     

Mechanism of decolorization and degradation of CI Direct Red 23 by ozonation combined with sonolysis

The decolorization and degradation of CI Direct Red 23, which is suspected to be carcinogenic, were investigated using ozonation combined with sonolysis. The results showed that the combination of ozonation and sonolysis was a highly effective way to remove color from waste water. The operational parameters, namely concentration of the dye, pH, ozone dose and ultrasonic density, were investigated during the process. The decolorization of the dye followed pseudo-first-order kinetics. Increasing the initial concentration of Direct Red 23 led to a decreasing rate constant. The optimum pH for the reaction was 8.0, and both lower and higher pH decreased the removal rate. The effect of the ozone dose on the dye decolorization was much greater than that of the sonolysis density. Intermediates such as naphthalene-2-sulfonic acid, 1-naphthol, urea and acetamide were detected by gas chromatography coupled with mass spectrometry in the absence of pH buffer, while nitrate and sulfate ions and formic, acetic and oxalic acids were detected by ion chromatography. A tentative degradation pathway was proposed without any further quantitative analyses. During the degradation, all nitrogen atoms and phenyl groups of Direct Red 23 were degraded into urea, nitrate ion, nitrogen and formic, acetic and oxalic acids, etc.     

生物法处理NOx废气的研究进展

氮氧化物 (NOx)是主要的大气污染物之一 ,是治理大气污染的一大难题。对当前国内外生物处理NOx 的研究现状进行了系统的论述 ,介绍了生物过滤法处理氮氧化物的基本原理 ,分析了生物过滤法处理氮氧化物存在的问题 ,并预测该技术的未来发展趋势     

Ag/Ag2SO3 plasmonic catalysts with high activity and stability for CO2 reduction with water vapor under visible light

Environmental Science and Pollution Research - The conversion of CO2 into useful raw materials for fuels and chemicals by solar energy is described using a plasmonic photocatalyst comprised of Ag...     

可见光响应的碘掺杂TiO2光催化剂的制备及其作用机理

以钛酸四丁酯为前驱物制备了碘掺杂TiO2催化剂(I-TiO2),考察了碘掺杂量、水解水量、水解温度和煅烧温度对催化剂物理化学性质与光催化活性的影响。X射线衍射(XRD)结果显示,I-TiO2由锐钛矿相和金红石相组成。在可见光照射下,通过降解水溶液中的苯酚评价了I-TiO2催化剂的光催化性能。结果表明,在水解温度为20℃,水解水量为300 mL,煅烧温度为400℃,碘钛比(摩尔比)为20%的制备条件下,催化剂显示了最优的光催化活性。通过向反应体系中引入自由基捕获剂及降低溶解氧,证实光催化降解苯酚主要由光生空穴或吸附的羟基自由基引发。     

Mineralization of C.I. Reactive Yellow 84 in aqueous solution by sonolytic ozonation

The operational parameters and mechanism of mineralization of C.I. Reactive Yellow 84 (RY84), one of the azo dyes, in aqueous solution were investigated using sonolytic ozonation (US/O(3) oxidation). Of the pseudo-first-order degradation rate constants of TOC reduction, 9.0 x 10(-4), 7.3 x 10(-3) and 1.8 x 10(-2)min(-1) were observed with US, O3, and a combination of US and O3, respectively. These results illustrate that ozonation combined with sonolysis for removal of TOC is more efficient than ozonation alone or ultrasonic irradiation alone without considering the operating costs. With the initial pH value at 10.0, the ozone dose at 4.5 g h(-1), the energy density of ultrasound at 176 W l(-1), and the initial concentration of RY84 at 100 mg l(-1), the extent of mineralization measured as TOC loss was maximized. The variation of the concentrations of related ions (oxalate, formate, acetate, NO3(-), NO2(-), NH4(+), Cl(-), and SO4(2-)) during the reaction process was monitored. Other organic intermediates detected by GC/MS were N-methyleneaniline, phthalic acid, 4-hydroxyphthalic acid, isocyanatobenzene, aniline, 4-iminocyclohexa-2,5-dien-1-one, butene diacid and urea. Based on these findings, a tentative degradation pathway was proposed.     

高校节能减排的潜力与效益实证研究

高校节能减排的潜力和效益非常可观。但是,要想达到预计的节能减排效益,高校必须建立和健全节能减排制度,加大节能技术和设施设备改造力度,引导师生采取有效的节能减排措施,加强对学生资源忧患意识和节约习惯的养成教育。     

TA对印染废水处理效果的影响

印染综合废水的酸析预处理效率主要受废水中对苯二甲酸（TA）含量的影响,且印染综合废水酸析规律与纯TA配制液相比较存在一定的差异,分别对纯TA配制液,印染综合废水,加TA后的废水,酸析预处理后的废水进行好氧生化处理试验,研究其降解规律与去除效率,结果表明TA属易好氧生化物质,它的存在可提高废水的可生化性。     

河西绿洲灌区玉米秸秆带膜还田腐解特征研究

为探讨河西绿洲灌区玉米秸秆带膜还田时的腐解规律,采用尼龙网袋法,对不同带膜还田模式下玉米秸秆的腐解特征进行研究,旨为当地玉米秸秆还田提供理论依据和技术指导。结果表明：土壤温度是影响当地玉米秸秆腐解的主要因素,经过180 d腐解后,各还田处理秸秆的腐解率均在50%以上,其中翻压处理的腐解率（67.5%～76.0%）高于覆盖处理（50.5%～59.0%）,而且腐解主要发生在还田后的30～120 d。秸秆在还田前期（前60 d）会与作物争夺土壤氮素,但是在还田后期会释放一定氮素,而且翻压和粉碎还田释放的氮素要高于覆盖和整株还田。从秸秆完全腐解的预测时间看,整株半量翻压、整株半量覆盖、粉碎半量翻压、粉碎全量翻压、粉碎半量覆盖和粉碎全量覆盖处理分别需要247、326、212、227、277和299 d才能完全腐解,可见,在河西绿洲灌区实行带膜还田前景广阔,而且翻压优于覆盖,粉碎优于整株,半量优于全量。     

危化品罐车自封堵式安全截断阀设计与分析

为解决危化品罐车的储罐阀门管线等关键部件易损坏造成危化品泄漏的问题,基于系统本质安全原理设计1种内置自封堵式安全截断阀并对其关键部件强度进行校核计算,建立实现阀芯阀座有效密封的三维实体模型并完成有限元分析。结果表明:在阀座密封面与球形阀芯接触处出现最大应力,阀座承受的最大应力小于材料的最大屈服应力,内置自封堵式安全截断阀具有较高的可靠性,可为危化品储运相关安全装置设计提供理论参考。