Isovaleraldehyde elimination by UV/TiO2 photocatalysis: comparative study of the process at different reactors configurations and scales

A proposal for scaling-up the photocatalytic reactors is described and applied to the coated catalytic walls with a thin layer of titanium dioxide under the near ultraviolet (UV) irradiation. In this context, the photocatalytic degradation of isovaleraldehyde in gas phase is studied. In fact, the removal capacity is compared at different continuous reactors: a photocatalytic cylindrical reactor, planar reactor, and pilot unit. Results show that laboratory results can be useful for reactor design and scale-up. The flowrate increases lead to the removal capacity increases also. For example, with pilot unit, when flowrate extends four times, the degradation rate varies from 0.14 to 0.38 g h^?1 m_cat ^?2. The influence of UV intensity is also studied. When this parameter increases, zboth degradation rate and overall mineralization are enhanced. Moreover, the effects of inlet concentration, flowrate, geometries, and size of reactors on the removal capacity are also studied.     

The impact of material design on the photocatalytic removal efficiency and toxicity of two textile dyes

Environmental Science and Pollution Research - This study deals with the toxicity of the treated solutions of two types of dyes, namely, the anthraquinonic Reactive Bleu 19 dye (RB19) and the...     

Irrigation pricing policies and its impact on agricultural inputs demand in Tunisia: a DEA-based methodology

This paper estimates farmers' individual irrigation water demand functions employing the information hidden in individual farmers' technical efficiency. This information is extracted through the development of a new deductive methodology based on inverse Data Envelopment Analysis (DEA) models. The empirical results for Tunisia show that farmers who are more technically efficient have less elastic irrigation water demand functions; these farmers would adjust demand only to a limited extent and they can afford the water price. In contrast, water pricing significantly affects those that are less efficient. These farmers shift towards a different cropping pattern using significantly less water and more land when the price of water increases. Thus, higher water prices would threaten this category's livelihood if their efficiency is not improved. However, if the technical efficiency of these farmers were to improve, then it would be more difficult to reach water saving objectives since their demand will also become highly inelastic. The findings have important implications in view of the objectives of Tunisia water policy which include:full cost recovery, continuity of the irrigation activity, and water saving at the national level.     

Valuing Improvements in The Water Rights System in South Africa: A Contingent Ranking Approach1

Speelman, Stijn, Stefano Farolfi, Aymen Frija, and Guido Van Huylenbroeck, 2010. Valuing Improvements in the Water Rights System in South Africa: A Contingent Ranking Approach. Journal of the American Water Resources Association (JAWRA) 46(6):1133–1144. DOI: 10.1111/j.1752-1688.2010.00480.x Abstract: In the context of increasing water scarcity, understanding is growing that irrigation water rights are important and that a lack of an effective water rights system constitutes a major reason for inefficient water management. This study carried out a contingent ranking experiment to study how smallholder irrigators in South Africa would value potential changes in water rights. Three specific dimensions of water rights, relevant for the South African case, are considered: duration, quality of title, and transferability. Results indicate that smallholder irrigators are prepared to pay considerably higher water prices if improvements are made in the water rights system. This implies that the proposed interventions in the water rights system would improve the efficiency and productivity of the small-scale irrigation sector. The increased willingness to pay could furthermore also assist the South African government to reach the objective of increased cost recovery.     

Gaseous ethylbenzene removal by photocatalytic TiO2 nanoparticles immobilized on glass fiber tissue under real conditions: evaluation of reactive oxygen species contribution to the photocatalytic process

Environmental Science and Pollution Research - Photocatalytic oxidation (PCO) using a TiO2 catalyst is an effective technique to remove gaseous volatile organic compounds (VOCs). Herein, a...     

Mapping Social Networks for Performance Evaluation of Irrigation Water Management in Dry Areas

Collaboration between actors is an important determinant of water governance, particularly in developing countries suffering from lack of institutional and organizational performances for water management. The objective of this paper is to use the social network (SN) concept in bringing depth to the understanding of local irrigation governance in three irrigated schemes located in dry regions of southern Tunisia. Local stakeholders in the considered schemes interact around different water-related issues. These include authorizations for access to water, extension services for irrigated crops, training on the use of irrigation technologies, and finance and subsidies of irrigation water saving equipment. We considered each of these types of interactions as different tie and we mapped social networks around each of them. For each network, actors’ densities, frequencies, and weight were reported. The results were revealing that better performances of water management are observed in areas with high SN density and high centrality of water users’ associations. The relative “weights” of actors in the three considered areas were significantly different, indicating that the application of a standard decentralization process of irrigation water may result in different local organizational arrangements, depending on patterns of social interactions.     

Are Investments in Groundwater Irrigation Profitable? A Case of Rice Farms from South India1

Varghese, Shalet Korattukudy, Jeroen Buysse, Aymen Frija, Stijn Speelman, and Guido Van Huylenbroeck, 2012. Are Investments in Groundwater Irrigation Profitable? A Case of Rice Farms from South India. Journal of the American Water Resources Association (JAWRA) 1‐15. DOI: 10.1111/j.1752‐1688.2012.00690.x Abstract: This article examines the profitability of cultivating double rice under bore well irrigation, given the cumulative interference of and reduced life span of wells, and thus increases the cost of groundwater extraction and use. The overexploitation of groundwater is a common stock problem and the cultivation of water intensive crops, such as rice, further exacerbates the overdraft of groundwater. Under these circumstances, we quantify the marginal benefit of irrigation investments in rice farming by estimating the probability of having a double rice crop as a function of the investment made in wells. Using this information, we explore profit maximization behavior of farms with a mathematical programming model to derive individual economic optima of irrigation costs. The results demonstrate that the ongoing overexploitation of groundwater, and its use to cultivate an economically inefficient crop, such as rice, has resulted in low profitability at farm level. A sensitivity analysis found that even when the investment in irrigation wells is reduced by 70%, small farms are still not economically efficient, thereby confirming the Tragedy of the Commons. Raising awareness amongst farmers with regard to the economics of irrigation would facilitate the participatory implementation of control mechanisms to regulate groundwater extraction.     

Review on inactivation of airborne viruses using non-thermal plasma technologies: from MS2 to coronavirus

Environmental Science and Pollution Research - Although several non-thermal plasmas (NTPs) technologies have been widely investigated in air treatment, very few studies have focused on the...