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Luke M. Mosley Benjamin Zammit Ann-Marie Jolley Liz Barnett Rob Fitzpatrick 《Environmental monitoring and assessment》2014,186(1):1-18
Large-scale exposure of acid sulfate soils during a hydrological drought in the Lower Lakes of South Australia resulted in acidification of surface water in several locations. Our aim was to describe the techniques used to monitor, assess and manage these acidification events using a field and laboratory dataset (n?=?1,208) of acidic to circum-neutral pH water samples. The median pH of the acidified (pH?<?6.5) samples was 3.8. Significant (p?<?0.05) increases in soluble metals (Al, Co, Mn, Ni and Zn above guidelines for ecosystem protection), SO4 (from pyrite oxidation), Si (from aluminosilicate dissolution) and Ca (from carbonate dissolution and limestone addition), were observed under the acidic conditions. The log of the soluble metal concentrations, acidity and SO4/Cl ratio increased linearly with pH. The pH, alkalinity and acidity measurements were used to inform aerial limestone dosing events to neutralise acidic water. Field measurements correlated strongly with laboratory measurements for pH, alkalinity and conductivity (r 2?≥?0.97) but only moderately with acidity (r 2?=?0.54), which could be due to difficulties in determining the indicator-based field titration endpoint. Laboratory measured acidity correlated well with calculated acidity (r 2?=?0.87, acidity present as AlIII?>>?H+?≈?MnII?>?FeII/III) but was about 20 % higher on average. Geochemical speciation calculations and XRD measurements indicated that solid phase minerals (schwertmannite and jarosite for Fe and jurbanite for Al) were likely controlling dissolved metal concentrations and influencing measured acidity between pH 2 and 5. 相似文献
3.
D W Fitzpatrick L D Arbuckle A M Hassen 《Journal of environmental science and health. Part. B》1988,23(4):343-354
Young female rats were orally dosed with either 1 or 100 mg zearalenone kg-1 body weight; zearalenone and metabolites were measured in a 96-h collection of urine and feces by HPLC analysis. Dose had little effect on metabolites formed, or excretion route. In both treatment groups, about 55% of the oral dose was excreted in the feces, while the urine was also a major route of excretion accounting for 15-20% of the administered dose. Zearalenone and metabolites were excreted mainly in the free form, with the production of alpha-zearalenol, the most potent estrogenic metabolite, being greater than 10% of the zearalenone dose. 相似文献
4.
5.
Scott Michael Fitzpatrick 《Journal of Coastal Conservation》2012,16(2):173-186
In this paper I review a host of natural and cultural processes that have affected the preservation and integrity of archaeological
sites on islands in the West Indies, many of which are located in low-lying coastal areas. Given the position of the Caribbean
lithospheric plate—juxtaposed between four others—it is no surprise that by its very nature the region is volcanically active
and frequently associated with earthquake and tsunami events. This makes coastal zones, and related archaeological sites in
the region, highly susceptible to a wide range of destructive natural events. The high frequency of tropical systems (hurricanes
and storms) in the Caribbean and rising sea level, coupled with human activities such as sand mining, development, and looting,
makes the region’s archaeological record one of the most vulnerable and threatened in the world. Ongoing research is dedicated
to understanding how past populations may have been affected by these events in the past. 相似文献
6.
Dianne L. Watson Euan S. Harvey Ben M. Fitzpatrick Timothy J. Langlois George Shedrawi 《Marine Biology》2010,157(6):1237-1250
Measures of fish abundance, assemblage composition and length were compared when sampled by baited remote underwater stereo-video
(stereo BRUV) and diver-operated stereo-video transects (stereo DOV) at the Houtman Abrolhos Islands and Ningaloo Reef. Species
richness counts were 40% higher on stereo BRUV than stereo DOV. Stereo BRUVs also recorded a greater number of large-bodied
targeted species in higher abundance than stereo DOV (e.g. Lethrinus nebulosus, Plectropomus leopardus) at the Houtman Abrolhos and at Ningaloo Reef. Many non-targeted species were also recorded in greater abundances on stereo
BRUV than stereo DOV (e.g. Coris auricularis, Gymnothorax spp). Stereo DOV transects recorded a greater abundance of some small-bodied Pomacentridae, Labridae and Scaridae species
than did stereo BRUV, particularly at Ningaloo Reef. This study demonstrates that choice of sampling technique for surveys
of reef fish can lead to very different biological interpretations of fish assemblage structure. 相似文献
7.
Quantitative polymerase chain reaction (qPCR) for the identification and quantification of microbes has become a common tool
for the study of harmful algal blooms (HABs). We developed a qPCR method for the diatom genus Pseudo-nitzschia. Several species of this genus form toxic blooms through the production of the neurotoxin domoic acid (DA). Outbreaks of
toxicity attributed to DA along the US west coast have caused sickness and death of marine mammals and seabirds through food
web contamination. The method developed here quantifies Pseudo-nitzschia spp. at low abundances in natural samples, thereby, providing a method to improve our understanding of the environmental
conditions leading to blooms of these species. This has been accomplished previously by techniques for identification and
quantification that are slow and laborious compared to qPCR. The approach was successfully tested and validated using eight
species of Pseudo-nitzschia and 33 non-target organisms and employed to follow local bloom dynamics. 相似文献
8.
Kevin A. Judge Janice J. Ting Jonathan Schneider Mark J. Fitzpatrick 《Behavioral ecology and sociobiology》2010,64(12):1971-1979
Both resource-holding potential (RHP) and experience in aggressive contests are known to affect future aggressive behaviour. However, few studies have examined the effects of mating experience on agonistic behaviour, despite the fact that dominant males usually acquire more matings. We investigated the effect of mating experience on male aggressive behaviour including the relationship between RHP and fighting success in the fall field cricket, Gryllus pennsylvanicus. We formed pairs of size- and age-matched males that varied in RHP (relative weapon size) and conducted two experiments. In the first, we varied male mating experience by allowing one male in a pair to either be (a) ‘mated’: court, be mounted and copulate with a virgin female or (b) ‘experienced’: court, be mounted, but prevented from copulating. The second experiment varied postcopulatory experience where the male was allowed (‘contact’) or prevented from (‘no-contact’) continued contact with his recent mate. Following treatment, experimental males engaged in an aggressive contest with the naïve size- and age-matched male. In our first experiment, we found that mated and experienced males were equally likely to escalate contests to combat with a naïve opponent, but mated males were less likely than experienced males to win. There was no effect of mating on the relationship between RHP and fighting success. In our second experiment, we found no effect of maintaining contact with the female on the tendency to escalate or the probability of winning. As in the first experiment, males with relatively larger heads again won more fights and this relationship was unaffected by male experience. These results suggest that mating is itself detrimental to male success in aggressive contests, but that this effect is not sufficient to eliminate the effect of RHP on fighting success. 相似文献
9.
A sustainable national policy on waste electronic and electrical equipment reuse has to ensure an integrated environmental economic and social approach. In this paper, a quantitative model is developed that permits a comparative analysis of re-use and non-re-use scenarios from an environmental and economic perspective. The model demonstrates the importance of considering user consumption profiles and the changing national electricity generation portfolio in determining the best end-of-life strategy, whether it should be reuse or recycling. A case study of Ireland is used to demonstrate the model. From a social perspective, qualitative aspects of reuse, such as the job creation potential and the impact on prosperity for low income families, are also considered. Reuse of white goods, if conducted through social enterprises, will create more employment than an equivalent amount of recycling for those most vulnerable to unemployment. Any environmental and social dividends from re-use can be realized only in the context of an economically sustainable system. This would include such factors as a secure supply of suitable equipment, a competitive cost base and sufficient revenues from sales and other sources in order for the business to survive. In an attempt to examine whether a white goods re-use program could possibly operate in a competitive manner with new appliances, this study has examined examples of comparable businesses operating in the EU as well as interpreting data on consumer demand. 相似文献
10.
The results of four experiments on acidification effects upon the Enchytraeid worm populations of ombrotrophic peats are reported. in the first, populations were measured in peats from Calluna vulgaris-dominated microcosms collected from along a gradient in N deposition in the UK and subjected for 18 months to simulated precipitation with a solute composition appropriate for their site of collection. There was a significant decline in Enchytraeid population along the N deposition gradient for Calluna-dominant microcosms, but when grasses took over from the Calluna, Enchytraeid numbers increased significantly. in the second experiment, two sets of peat moorland microcosms from a single site, supporting Calluna and Calluna-grass mixed vegetation, were subjected for 12 months to ambient and 2- and 6-times the ambient N deposition. Additional N was added in two forms, as ammonium sulphate and as nitric acid. the high N treatments significantly reduced the Enchytraeid populations for both vegetation types. in a third experiment, the pH preference for the Enchytraeids was assessed using interconnected tubes of peat covering the pH range 2.2-8.7. the preferred pH range after 8 months was 2.7-3.7. in the final experiment, it was found that recolonization with Enchytraeids after initial removal was more rapid under grass dominant vegetation than under Calluna dominant vegetation. 相似文献