Bioremediation emphasizes the detoxification and destruction of toxic substances by microorganisms. Wastewater obtained from an industrial concern was solvent extracted with methyl alcohol and dichloromethane and analysed by GC/MS. Besides phenol, a large variety of organic compounds were detected. Under controlled laboratory conditions, the wastewater was innoculated with a mixed culture of microorganisms specially selected for their abilities to degrade phenol. Samples were collected at regular intervals from the stirred tank bioreactor and analysed for phenol by reverse phase HPLC with a C18 column. Results shows that from an initial phenol concentration of 987 ppm, slightly more than 50% was destroyed within 163 hours. The dry weight of the microorganisms and the plate count (CFU/ml) shows a steady increase from 0.5238 gms to 0.5355 gms and from 1.1E+9 to 1.94E+13 respectively over the same period. This suggested that the phenol was consumed by the microorganisms as the sole carbon source. 相似文献
Food surveys for levels of toxic chemicals frequently report the levels on an uncooked basis. It is known that cooking may in some conditions decrease the amount of dioxins and related chemicals in food. Surveys of polybrominated diphenyl ether (PBDE) levels in food to date show data from uncooked food only. In this article, it was shown that broiling, with fat dripped from the foods reported here, ground beef, ground lamb, catfish, trout, and salmon, reduces the amount of PBDEs in these foods. This suggests that calculations of food intake need to take into consideration levels in the cooked food rather than in the uncooked food. 相似文献
From simultaneous air and water polychlorinated biphenyl (PCB) measurements collected in September 2010, we re-evaluated the direction and magnitude of net air-water exchange of PCBs in southwest Lake Michigan and compared them with estimations made using similar approaches 15 years prior. Air and water samples were collected during a research expedition on Lake Michigan at 5 km off the coast of Chicago, with prevailing winds from the southwest of our location. Gas-phase ΣPCB concentrations ranged from 190 to 1100 pg m?3 with a median of 770 pg m?3, which is similar to the concentrations measured in the City of Chicago at the same time and similar to concentrations measured in this part of the lake over the last 20 years. Water dissolved-phase ΣPCB concentrations ranged from 150 to 170 pg L?1 with a median of 160 pg L?1, which is one-tenth of that measured in the 1990s. ?PCB net fluxes showed a slightly absorptive behavior, with a median of (?) 21 ng m?2 day?1 and an interquartile range of (?) 47 to (+) 5 ng m?2 day?1, where (?) and (+) fluxes indicate absorption and volatilization, respectively. Airborne PCB concentrations were higher when the winds were coming from Chicago and drive the deposition. Our fluxes are not significantly different from estimations from 1994 and 1995 and suggest that absorption of PCBs into the waters is slightly more prevalent than 15 years ago. It was confirmed that Chicago remains an important atmospheric source of PCBs to Lake Michigan.
Indiana Harbor and Ship Canal (IHSC) is an active navigational system that serves a heavily industrial area of southern Lake Michigan. We have determined the amount of polychlorinated biphenyls (PCBs), congener distributions, sorbent types and potential for dioxin-like PCB toxicity from two IHSC sediment cores. Vertical distributions of ΣPCBs (sum of 161 individual or coeluting congeners) ranged from 410 to 91000 and 1800 to 41000 ng g(-1) dry weight (d.w.) for cores 1 and 2, respectively. Core 1 showed its highest accumulation rate for the year ~1979 and exhibits a strong Aroclor 1248 signal in sediments accumulating over the last 60 years. It appears that from the late 1930s until the beginning of the 1980s there was a large and constant input of PCBs into this system. This pattern differs from lake cores from the Great Lakes region which commonly exhibit a rapid increase, a peak, followed by a sharp decrease in the PCB accumulation rates. Core 2 also has a strong Aroclor 1248 signal in the top layers, but deeper layers show evidence of mixtures of Aroclors and/or weathering processes. High levels of black carbon as a fraction of total organic carbon were found in both cores (median ~30%), which reflect the long history of local combustion sources. No strong relationship was found between ΣPCB concentration and sorbents. Both cores contain dioxin-like PCBs that are highest in concentration below the surface. The high levels of PCBs in the deep sediments are of concern because of plans to dredge this system. 相似文献
Integrated rice–fish culture is a competitive alternative to rice monoculture for environmental sustainability and food productivity. Compared to rice monoculture, rearing fish in rice field ecosystems could increase food (rice and fish) production from this coculture. Moreover, the water productivity of rice–fish coculture is considerably higher than that of rice monoculture, because of double cropping. Despite these benefits, rice–fish coculture has not yet been broadly practiced. One of the potential challenges for the wider adoption of rice–fish coculture is water management. There are two forms of water involved in rice–fish cultivation: (1) blue water–surface and groundwater, and (2) green water–soil water from rainfall. The aim of this article is to focus on key factors determining the adoption of rice–fish cultivation through the effective utilization of blue–green water. We suggest that the efficient application of blue and green water in rice–fish coculture could help confronting water scarcity, reducing water footprint, and increasing water productivity. 相似文献
The volatile organic pollutants from direct vehicular exhaust were trapped with activated charcoal, desorbed with carbon disulphide and analysed by GC/MS with tert-butyl benzene as an internal standard. A comparative study was made from the exhaust of 1000 cc, 1300 cc, 1600 cc cars, pickup, lorry(diesel), 125 cc and 70 cc motorbikes. The level of pollutants emitted were in the following order, motorbike(petrol) car(petrol) pickup(petrol) lorry(diesel). The range of highest emission (125 cc motorbike) to the lowest emission (lorry(diesel)) was of the order of 102 for benzene, 6×102 for ethyl benzene, 5×102 for toluene and 3×102 for xylenes. Among cars, those fitted with catalytic convertors emitted a lower level of benzene (2 to 3 times) when compared with those without catalytic convertors. Similar studies on the air in air-conditioned buses, non air-conditioned buses and three metres from the edge of the road shows that they have the same pollutant level. The level of these pollutant as compared to those from direct car exhaust are of the order of 102 times less for benzene, xylene and toluene and 103 times less for ethylbenzene. The levels of benzene, toluene, ethylbenzene and xylenes by the road side and in the buses were found to be lower than the exposure limits of ACGIH, OSHA and EH40. 相似文献
A kinetic model for the uptake ofpolycyclic aromatic hydrocarbons (PAHs) wasdeveloped from the anatomical structure of broadleaves. The model, which is supported by fielddata, includes the uptake from two pathways: outercuticle pathway and stomatal pathway, and withgrowth rate incorporated as a dilution term. Allthe parameters for the calculation of total masstransfer coefficient, kOL, were estimated fromthe conductance of water vapor diffusion throughleaves. The results indicate that the stomatalpathway is a dominant pathway for dry gaseousdeposition of POPs on leaves and the uptake fromouter cuticle pathway can be neglected for the PAHsof molar volumes larger than phenanthrene becauseof the rate limitation in outer layer cuticle. Model sensitivity analyses demonstrates that withinthe range of environmental conditions and normalleaf structure, the surface area in stomata has themost significant effect on the uptake rate. If thestomatal pathway is closed, the kinetics of uptakeare so slow that accumulation appears independentof compound lipophilicity or molecular size. Ineither case, the leaf growth rate has little effecton the predicted accumulation 相似文献