It is known that globalization has led first- and second-tier cities’ urban restructuring trajectories, excreted pressures, and caused tremendous socioeconomic volatility. This resulted in marginalized communities in dire of social empowerment, employment structure variance, and industry sectoral adjustment. Moreover, recent successive climate and health crisis unfolded and affirmed the state of our urban incompetence to sustain socioeconomic resilience or otherwise; lacking swift responses in providing critical management and services, cites are facing multifaceted challenges. Urban well-being and resilience are at stake. Although the environmental and health dimensional effects are apparent, this study ascertains that the transept multi-scalar analysis within the urban socioeconomic structure is crucial in sustaining core resilience to foster health and well-being of the community. As an integral part of the investigation, the revised DPSIR assessment framework is applied to evaluate the sectoral shift; spatial structure disarray and urban codependence degree are examined within the Taipei metropolitan area (TMA), a medium size but densely populated metropolitan area in Taiwan. The place-based DPSIR analysis ascertained the states and impacts in TMA: (1) A population decline speeded the restructuring of the urban core, while the impact of demographic aging and shrinkage rate mandates proper management and planning responses to the decline process; (2) the socioeconomic state effect is determined but does not critically affect the periphery zone, while an uneven demographic shift within the urban core necessitates dynamic adjustment responses to appropriately provide intergenerational services; (3) the uneven sector redistribution stimulated the core’s spatial and structural inter-dependency with peripheral zones, requiring governance with tighter cross-administration cooperation among respective public sectors; and (4) facing the sector/temporal and demographic pressure, urban cohesiveness in the TMA is greatly affected, which in turn disrupts the resilience pathway toward a cohesion. The study ascertained that the revised DPSIR framework could provide cities facing pressing socioeconomic drivers with effective analysis to allocate pressures, states, and impacts and formulate the necessary responses. To assure the socioeconomic resilience and urban cohesiveness, planning policy should carefully monitor and evaluate socio-demographic and sector redistribution factors to promote the urban resilience.
The quantitative relationship between the median effective concentration (EC50) of organic chemicals to Daphnia magna and the number of molecular fragments was investigated based on experimental EC50 values for 217 chemicals derived from the literature. A fragment constant model was developed based on a multivariate linear regression between the number of fragments and the logarithmically transformed reciprocal values of EC50. Functional correction factors were introduced into the model. The model was verified using an independent set of randomly selected data. The mean residual of the final model was 0.4 log-units. The robustness of the model was discussed based on the results of three jackknife tests. 相似文献
F-V_2 O_5-WO3/Ti02 catalysts were prepared by the impregnation method.As the content of F ions increased from 0.00 to 0.35 wt.%,the NO conversion of F-V_2 O_5-WO_3/TiO_2 catalysts initially increased and then decreased.The 0.2 F-V_2 O_5-WO_3/TiO_2 catalyst(0.2 wt.% F ion)exhibited the best denitration(De-NOx) performance,with more than 95% NO conversion in the temperature range 160-360℃,and 99.0% N2 selectivity between 110 and 280℃.The addition of an appropriate amount of F ions eroded the surface morphology of the catalyst and reduced its grain size,thus enhancing the NO conversion at low temperature as well as the sulfur and water resistance of the V_2 O_5-WO3/Ti02 catalyst.After selective catalytic reduction(SCR) reaction in a gas flow containing SO_2 and H_2 O,the number of NH3 adsorption sites,active component content,specific surface area and pore volume decreased to different degrees.Ammonium sulfate species deposited on the catalyst surface,which blocked part of the active sites and reduced the NO conversion performance of the catalyst.On-line thermal regeneration could not completely recover the catalyst activity,although it prolonged the cumulative life of the catalyst.In addition,a mechanism for the effects of S02 and H_2 O on catalyst NO conversion was proposed. 相似文献