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1.
Sorption of alpha and beta hydrophobic endosulfan in a Vertisol from southeast region of Turkey 总被引:1,自引:0,他引:1
Aye Dilek Atasoy Ahmet Ruhi Mermut Halil Kumbur Faruk nce Hüdaverdi Arslan Emel Deniz Avc 《Chemosphere》2009,74(11):1450-1456
Endosulfan has been applied to control numerous insects in a variety of food and non-food crops. Limited information is available on dynamics of this pesticide in the soil. The objective of this research was to determine the adsorption–desorption behavior of the alpha (α) and beta (β) endosulfan in a Vertisol from the southeast region of Turkey, where cotton is the main crop in the large irrigated lowlands. The α and β endosulfan were adsorbed considerably and Freundlich adsorption–desorption isotherms fitted the α and β endosulfan data (R2 > 0.98). Freundlich adsorption coefficients (Kf) for the α endosulfan ranged between 21.63 and 16.33 while for the β endosulfan they were between 14.01 and 17.98 for the Ap and Bw2 horizons. The difference of Kf values of α and β endosulfan for two horizons were explained with the slight difference in the amount of organic matter and clay, but considerable difference in Fe contents of the two horizons. Alpha and β endosulfan Kfd values were 118.03 and 45.81 for the Ap and 48.08 and 68.71 for the Bw2 horizons. Higher adsorption and desorption behavior of the endosulfan isomers for the same horizon was attributed to poor physical bonding between the endosulfan molecule and the surfaces of fundamental soil particles. This fact is thought to increase the effective use of endosulfan in agriculture with a possibility of its movement to the surface and groundwater in the Vertisol studied. 相似文献
2.
İsmail Hilali 《International Journal of Green Energy》2016,13(9):911-917
This study presents a comparative analysis of sizing of metal hydride tank filled with different alloys. Alloys include solid solutions and intermetallic compounds of the generic families AB5, AB2, AB, A2B. The effects of the different alloys on the sizing of metal hydride hydrogen storage tanks are complicated and depend on many factors. In this paper, a thermoeconomic optimization analysis with a simple algebraic formula was presented for the estimation of optimum metal hydride tank surface area for heat transfer enhancement. The optimum area of the metal hydride tank filled with commercially available different alloys (LaN5, Ti0,98Zr0,02V0,43Fe0,09Cr0,05Mn1,5, TiFe, Mg2NiH4) was evaluated and compared by the developed method. The optimum net savings and the value of payback were determined for four alloys. It is found that mathematical model can be employed for the determination of optimum metal hydride tank design and increasing net savings according to alloy types. The optimum areas of the tanks filled with four alloys (LaN5, Ti0,98Zr0,02V0,43Fe0,09Cr0,05Mn1,5, TiFe, Mg2NiH4) were calculated as 0.136, 0.130, 0.133, and 0.173 m2, respectively. The optimum net savings for tanks filled with four alloys (LaN5, Ti0,98Zr0,02V0,43Fe0,09Cr0,05Mn1,5, TiFe, Mg2NiH4) are about 461.0, 409.3, 419.6, and 979.6 $ and the values of payback are about 1.98, 2.1, 2.17, and 1.37 years, respectively. Excessive area of the metal hydride tank would not be as economical as the optimum tank area. Thermal management of metal hydride tank must be designed for optimum points calculated at which maximum savings occur. 相似文献
3.
Zafer Ziya Öztürk Cihat Tasaltin Güleda Önkal Engin Ayşe Gül Gürek Devrim Atilla Vefa Ahsen Mahir İnce 《Environmental monitoring and assessment》2009,151(1-4):369-375
Sewage treatment works are one of the major sources that cause atmospheric odour pollution. The increase in the number of complaints about odour nuisance is due to the increase in environmental concerns. Unfortunately, the legislation on odour nuisance from sewage treatment works is very limited. In order to determine suitable thresholds on which to base legal standards, reliable and efficient odour measurement methods need to be defined. A chemical sensor array was developed for the purpose of measuring wastewater odour. This paper describes the development of the chemical sensor system which is specifically tuned to odours of wastewater origin and which can give an electronic measure of the wastewater odours. Odour emissions from a wastewater treatment facility were detected by using a quartz crystal microbalance (QCM) sensor array. The array consists of nine sensor elements, which were coated with different materials. In this paper, the usage of these novel instruments in the water industry was shown. 相似文献
4.
Sangun MK Aydin E Timur M Karadeniz H Caliskan M Ozkan A 《Journal of environmental biology / Academy of Environmental Biology, India》2007,28(4):731-733
The essential oils of the leaves and fruits from bay (Laurus nobilis L.) grown in Antakya, Yayladagi and Samandagi were isolated by solvent extraction and analysed by capillary gas chromatography (GC), gas chromatography and mass spectrometry (GC/MS). In Antakya, Yayladagi and Samandagi the chemical compositions of the fruits and leaves were similar according to qualitative and quantitative analysis. Although in both fruits and leaves the major component was found to be 1.8-Cineole a concentration of about 50% compared with essential oils. The composition of the essential oil from the leaves has high content of 1.8-Cineole, Sabinene and alpha-Terpinyl acetate, but a low content of a-Pinene, alpha-Phellandrene and trans-/beta-osimen. 1.8-Cineole was found major component of the leaves essential oil collected from Samandagi (59.94%) which is sea coast of region. Interestingly alpha-Pinene, beta-Pinene, alpha-Phellandrene, 1.8-Cineole and trans-beta-osimen were found the major components of fruits of Laurus nobilis L. harvested from Antakya, Yayladagi and Samandagi Trans-beta-osimen was detected as the major component of fruits essential oil collected again from Samandagi (28.35%) 相似文献
5.
Hanedar Asude Çifçi Deniz İzlen Zafer Nur Görgün Erdem 《Journal of Material Cycles and Waste Management》2022,24(5):1760-1767
Journal of Material Cycles and Waste Management - In this study, the amount of medical waste generated in a high-populated city in Turkey between January 2018 and August 2021 was evaluated, and the... 相似文献
6.
Higher number of microplastics in tumoral colon tissues from patients with colorectal adenocarcinoma
Cetin Meltem Demirkaya Miloglu Fatma Kilic Baygutalp Nurcan Ceylan Onur Yildirim Serkan Eser Gizem Gul Halise İnci 《Environmental Chemistry Letters》2023,21(2):639-646
Environmental Chemistry Letters - Microplastics have been detected in marine and terrestrial ecosystems, yet the toxic effects of microplastics on living organisms are poorly known. In particular,... 相似文献
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8.
Adsorption kinetics of methyl violet onto perlite 总被引:11,自引:0,他引:11
This study examines adsorption kinetics and activation parameters of methyl violet on perlite. The effect of process parameters like contact time, concentration of dye, temperature and pH on the extent of methyl violet adsorption from solution has been investigated. Results of the kinetic studies show that the adsorption reaction is first order with respect to dye solution concentration with activation energy of 13.2 kJ mol(-1). This low activation energy value indicates that the adsorption reaction is diffusion controlled. The activation parameters using Arrhenius and Eyring equations have been calculated. Adsorption increases with increase of variables such as contact time, initial dye concentration, temperature and pH. 相似文献
9.
İlhan Nagehan Demir Yetiş Ayşegül Yeşilnacar Mehmet İrfan Atasoy Ayşe Dilek Sınanmış 《Environment, Development and Sustainability》2022,24(3):3258-3292
Environment, Development and Sustainability - The objective of this paper is twofold. First; we demonstrate the application of data mining techniques to predict quality indicators (TDS, Hardness,... 相似文献
10.
Kiymet Gözek Ülkü Yücel Murat İlim Perihan Aysal Aydin Ş. Tunçbilek 《Journal of environmental science and health. Part. B》2013,48(3):413-429
Abstract An olive tree was treated twice in the field with 14C‐dimethoate (237.7 (μCi, 2.4 g) and 14C residues were determined in the olive fruits at harvest. The fruits were crushed and pressed to extract the crude oil, then refined by neutralization, bleaching and deodorization. The crude oil contained 14.1% of the total 14C in the olive fruits. Neutralization resulted in a reduction of 14C by about 50% of the total 14C residues in oil. Bleaching and deodorization processes further reduced the 14C residues and the refined oil contained 31.6% (which corresponds to 4.4% of I4C residues of the total 14C in olive fruits) of the total 14C in the crude oil. Industrially extracted crude oil was fortified with 14C‐dimethoate at 1.8 mg kg‐1 (0.02 μCi) level and subjected to the same refining process. A sharp decrease in the amount of 14C was observed by neutralization and the amount of 14C remaining in the refined oil was about 7.3% of the total l4C in the crude fortified oil. The data suggest that the 14C residues in the aged and the fortified oil amples were not of the same nature. The terminal 14C residue in the refined oil obtained from the field experiment did not contain dimethoate and/or its oxon. 相似文献