Speciation of metals in bed sediments and water of Qaraaoun Reservoir, Lebanon

Determination of only total element in sediments does not give an accurate estimate of the likely environmental impacts. Speciation study of metals in sediment provides information on the potential availability of metals (toxic) to biota under various environmental conditions. In water, the toxic metal specie is the free hydrated metal ion. The toxicity of metals depends especially on their chemical forms rather than their total metal content. The present study focuses on Qaraaoun Reservoir, Lebanon. Earlier studies focused only on total metal concentrations in sediment and water. The objective of this study was to determine metal speciation (Fe, Cr, Ni, Zn, Cu, Pb, Cd) in the (operationally defined) sediment chemical fractions and metal speciation in reservoir water. This would reflect on metal bioavailability and toxicity. Water samples and bed sediments were collected from nine sites during the dry season and a sequential chemical fraction scheme was applied to the <75-??m sieve sediment fraction. Metal content in each fraction was determined by the FAAS technique. The data showed that the highest percentages of total metal content in sediment fractions were for: Fe in residual followed by reducible, Cr and Ni in residual and in reducible, Cu in organic followed by exchangeable, Zn in residual and in organic, Pb in organic and carbonate, Cd was mainly in carbonate. Total metal content in water was determined by ICP-MS technique and aqueous metal speciation was predicted using AQUACHEM software interfaced to PHREEQC geochemical computer model. The water speciation data predicted that a high percentage of Pb and Ni were present as carbonate complex species and low percentages as free hydrated ions, highest percentage of Zn as carbonate complex species followed by free hydrated ion, highest percentage of Cd as free hydrated ion followed by carbonate complex species. The sensitivity attempt of free hydrated ion of Ni, Zn, Pb, and Cd in reservoir water revealed dependence of Zn and Cd on pH and alkalinity, while Ni and Pb were only dependent on pH.     

Optimised product and water recovery from batch-production rinsing waters

Product concentrate can be recovered from rinsing waters [cleaning in place (CIP)] of surfactant and detergent batch production processes by using ultrafiltration and nanofiltration membranes. The problem in designing a separation process for the rinsing water is that the different compositions of the CIP-batches result in different treatment characteristics. The product formulations considered in this study are based on anionic and non-ionic surfactants. Detergents additionally contain salts, dyes, perfumes and solvents. Product solution enrichment by means of ultrafiltration membranes was investigated. Flux behaviour and selectivity are modelled on the basis of the experimental results as a basis for economic optimisation of the recovery process. The model is validated with the experimental data. The simulation model is used to calculate optimal design and operation parameters for a multi-stage UF concentration plant. An optimal number of feed-and-bleed-stages can be found under economic constraints. For water purification, a nanofiltration step has to be implemented for some of the surfactant CIP-batches. Depending on the separation characteristics, the batches are treated with a single (UF) or two-step membrane process (NF/ UF).     

Mitochondrial DNA sequence data of the Cape fur seal (Arctocephalus pusillus pusillus) suggest that population numbers may be affected by climatic shifts

The Cape fur seal, Arctocephalus pusillus pusillus is distributed along the southern African coastline from northern Namibia to the south-east coast of South Africa. The species has been impacted by sealing operations since the 1600s, and historical records suggest that the taxon experienced a bottleneck prior to the 20th century. Mitochondrial DNA control region sequences were generated for 106 individuals belonging to six breeding colonies. Haplotype diversity was found to be high (0.975±0.014) whereas levels of nucleotide diversity were much lower compared to other seal species (0.011±0.006). An analysis of molecular variance indicated that the largest percentage of haplotype diversity is distributed within colonies rather than among them. This could be attributed to either extensive gene flow among colonies, a lack of substantial female site philopatry, or incomplete lineage sorting of haplotypes. Mismatch distribution and Fu’s F _S test indicated that the population has experienced a historical population expansion probably between c. 37,000–18,000 YBP and this date coincides very well with the height of the last glacial maximum when food resources were abundant in the South Atlantic. These results also suggest that the recent sealing-induced bottleneck did not have a profound influence on the haplotype diversity and a historical bottleneck prior to a demographic expansion may have been severe enough to reduce nucleotide diversity substantially.     

Assessment of domestic water quality: case study, Beirut, Lebanon

In urban cities, the environmental services are the responsibility of the public sector, where piped water supply is the norm for urban household. Likewise, in Beirut City (capital of Lebanon) official water authorities are the main supplier of domestic water through a network of piping system that leaks in many areas. Beirut City and its suburbs are overpopulated since it is the residence of 1/3 of the Lebanese citizens. Thus, Beirut suffers deficiency in meeting its water demand. Water rationing, as a remedial action, is firmly established since four decades by the Lebanese Water Authorities. Consumers resorted then to private wells to supplement their domestic water needs. Consequently, household water quality is influenced by external factors relating to well water characteristics and internal factors depending on the types of the pipes of the distribution network and cross connections to sewer pipes. These factors could result in chemical and microbial contamination of drinking water. The objective of this study is to investigate domestic water quality variation in Beirut City emerging form the aforementioned factors. The presented work encircles a typical case study of Beirut City (Ras Beirut). Results showed deterioration pattern in domestic water quality. The predicted metal species and scales within the water pipes of distribution network depended on water pH, hardness, sulfate, chloride, and iron. The corrosion of iron pipes mainly depended on Mg hardness.     

Evaluation of water quality of the Qaraaoun Reservoir,Lebanon: suitability for multipurpose usage

The increased demand on water resources in Lebanon as a resultof: progressive urbanization, socio-economic growth, agriculturalactivities and development of industries is, according to the national authorities, a major critical factor by the year 2010.Political difficulties in earlier years imply a dearth of pertinent data. The objective of this study was to evaluate water quality of the Qaraaoun Reservoir of the Litani River andassess its feasibility for multi-purpose usage as one of the solutions to the aggravated water problems in Lebanon. Sampleswere collected from 18 sampling sites at several dates duringthe dry season. Parameters analysed were, pH, electrical conductivity, TDS, turbidity, alkalinity, Ca, Mg, TH, Cl^-, SO₄ ^2-, NH₃, NO₃ ^-,PO₄ ^3-, Fe, Al, Na, Zn, Cr, Cu and As. The reported data were in compliancewith WHO guidelines, USEPA regulation and EEC directives. Statistical analysis of the data defined three distinct environmental zones and water quality in the central, main zone satisfied most criteria. It is concluded that the reservoir water is fit for multipurpose uses, namely, drinking, domestic,recreational activities, irrigation, fisheries, livestock and industrial, and should be properly managed accordingly.     

Provision of safe domestic water for the promotion and protection of public health: a case study of the city of Beirut,Lebanon

Securing adequate safe drinking water and proper sanitation is a major challenge facing the developing world. The “Water for Life Decade” emphasizes the importance of upgrading national water quality and sanitation services. This study assessed the domestic water profile in the city of Beirut. Samples were collected from three types of household water sources (municipality, private wells, and vended water bottles) and assessed for their physiochemical and microbiological profile. At the same time, a cross-sectional survey assessing water consumption patterns and the prevalence of water-borne diseases was conducted. The results showed a deficient water quality profile in all three water sources. The measured physiochemical and bacteriological parameters reflected the high frequency of water-borne diseases. Action to secure a safe domestic water supply is essential. The plan should guarantee the protection of water sources, ensure sufficient treatment of domestic water and upgrade the national program for potable water quality control. Periodic quality monitoring and legislating the chaotic water-vending sector are indispensable. Additionally, the deterioration of private well sources by sea and wastewater infiltration necessitates the enforcement of legislation associated with the use and management of private wells. Consumer awareness and active contributions to promote and protect public health are important.     

Variation of Metals in Bed Sediments of Qaraaoun Reservoir, Lebanon

The Qaraaoun Reservoir (impoundment of the River Litani) is the only artificial surface water body in the country, Lebanon. Earlier study on the water quality of the Qaraaoun Reservoir identified three water quality zoning with a central distinct zone suitable for multipurpose water usage. The objective of this study was to extend the earlier work by considering the total metal content of reservoir bed sediments and hence to evaluate factors that control metal deposition or capture. Water samples were collected from 15 sampling sites and sediment samples were simultaneously collected from 9 sites. Water parameters analyzed were pH, Eh, DO and temperature. Sediment samples were dried and sieved and sediment < 75 μ m was retained for analysis. Sediments were subjected to a stepwise heating process with aqua regia to extract the metals, and their content in sediments determined by ICP-MS. The sediment data revealed higher metal contents where the river entered the reservoir which matched higher concentrations of water parameters at the influx site. Regression analysis of total metals in sediments with distance from the river Litani influx point to the dam revealed a log trend for Fe, Cr and Ni, whereas, the concentrations of Cu, Zn, Cd, Pb were better described by a polynomial regression. Three sediment zones were identified: entrance, oxidation (central) and reducing (near dam) zones. Sediment contents of Zn, Cu and Pb correlated with organic content, whereas sediment Cr and Ni were associated with iron. It was concluded that sediments act as a sink for metals and the deposition of metals is primarily related to sediment organic content and the level of dissolved oxygen in water.     

Effectiveness of wastewater management in rural areas of developing countries: a case of Al-Chouf Caza in Lebanon

Ghaggar, one of the major rivers of northern India originating in outer Himalayas and flowing through the state of Punjab, Haryana, and Rajasthan, is put to multiple uses. Along its course of 464 km, it receives discharge from various cities and runoff from agricultural lands. Punjab and Haryana are two predominantly agricultural states of India using substantial amounts of agrochemicals, yet there are no reports available in literature on the level of pesticides in the stretch of river Ghaggar through Punjab and Haryana. This is the first report on pesticide pollution of the river Ghaggar in Haryana. Water samples along the 230-km stretch of the river in Haryana were analyzed for the presence of organochlorine insecticide residues. While aldrin and dieldrin were below detection limits, both hexachlorocyclohexane (HCH) and dichlorodiphenyltrichloroethane (DDT) were traceable in all the water samples. High concentration of β-HCH among ΣHCH indicates old pollution source whereas predominance of p,p^′ -DDT among ΣDDT reflects its recent use in the catchment area of the river. The concentrations of HCH and DDT in all the samples were above the permissible limits prescribed by the European Commission Directive for drinking purposes.     

Feature selection approaches for predictive modelling of cadmium sources and pollution levels in water springs

The World Health Organization lists cadmium (Cd) as one of the top ten chemicals of public health concern. Cd is toxic at relatively low exposure levels and has acute and chronic effects on both health and the environment. In this study, we investigate a suite of data-driven methods that could assist decision-makers in estimating Cd levels in water springs, and in identifying polluting sources. Machine learning (ML) regression models were used to identify sources of contamination and predict Cd levels based on support vector machines and a variety of tree-based models, including Random Forests, M5Tree, CatBoost, and gradient boosting. Feature selection analysis revealed that heavy traffic and distance to a major power plant in the sampled area play a leading role in springs Cd contamination, together with precipitation levels and average of slopes of the closest waste dumps upstream to sampled springs. Our best performing ML model was the Adaboost regression tree using all the features (RMSE = 19.36, R^2 = 0.64). Our findings highlight the effectiveness of predictive data-driven modeling in addressing environmental challenges, particularly in high-risk areas with low resources.