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排序方式: 共有101条查询结果,搜索用时 15 毫秒
1.
Jan Kupec Kateřina Charvátová Milan Navrátil Vojtěch Křesálek Martina Křesálková 《Journal of Polymers and the Environment》2003,11(3):93-100
Most native polymers used in processing and application technologies are admittedly disposable from the environment in a biologic manner, but products possess low mechanical strength. One of the paths to increasing this attribute (if feasible) is their cross-linking, which may, however, affect their readiness to biodegradation. In the presented work this condition was observed on the example of waste protein (Hykol B) cross-linking by means of glutardialdehyde and glyoxal. Degree and course of cross-linking were determined through impedance spectroscopy. The objective of this work also was to obtain data for constructing a sensor capable of following the cross-linking course in real time, for potential industrial application of Hykol in continuous production. Impedance spectroscopy proved to be applicable even to this kind of material marked by considerable water content and exhibiting relatively high electric conductivity; so far it had been used only for materials of low conductivity. An aqueous environment inoculated with digested anaerobic sludge from a municipal wastewater treatment plant was selected for modeling anaerobic conditions. The relation was studied between cross-linking degree given by content of cross-linking agent (determined by impedance spectroscopy) and biodegradation degree under anaerobic conditions. It was confirmed that network density as given by quantity of added agent not only reduced breakdown degree but also slowed the course of the process. This fact is particularly obvious with cross-linking by means of glyoxal; network density is thus dependent on type of employed substance, which affect type and structure of created network. That not merely forms an obstacle during polymer swelling and dissolution but also prevents access of bacteria to source of metabolized organic carbon. 相似文献
2.
Bytnerowicz A Badea O Barbu I Fleischer P Fraczek W Gancz V Godzik B Grodzińska K Grodzki W Karnosky D Koren M Krywult M Krzan Z Longauer R Mankovska B Manning WJ McManus M Musselman RC Novotny J Popescu F Postelnicu D Prus-Głowacki W Skawiński P Skiba S Szaro R Tamas S Vasile C 《Environment international》2003,29(2-3):367-376
An international cooperative project on distribution of ozone in the Carpathian Mountains, Central Europe was conducted from 1997 to 1999. Results of that project indicated that in large parts of the Carpathian Mountains, concentrations of ozone were elevated and potentially phytotoxic to forest vegetation. That study led to the establishment of new long-term studies on ecological changes in forests and other ecosystems caused by air pollution in the Retezat Mountains, Southern Carpathians, Romania and in the Tatra Mountains, Western Carpathians on the Polish-Slovak border. Both of these important mountain ranges have the status of national parks and are Man & the Biosphere Reserves. In the Retezat Mountains, the primary research objective was to evaluate how air pollution may affect forest health and biodiversity. The main research objective in the Tatra Mountains was to evaluate responses of natural and managed Norway spruce forests to air pollution and other stresses. Ambient concentrations of ozone (O(3)), sulfur dioxide (SO(2)), nitrogen oxides (NO(x)) as well as forest health and biodiversity changes were monitored on densely distributed research sites. Initial monitoring of pollutants indicated low levels of O(3), SO(2), and NO(x) in the Retezat Mountains, while elevated levels of O(3) and high deposition of atmospheric sulfur (S) and nitrogen (N) have characterized the Tatra Mountains. In the Retezat Mountains, air pollution seems to have little effect on forest health; however, there was concern that over a long time, even low levels of pollution may affect biodiversity of this important ecosystem. In contrast, severe decline of Norway spruce has been observed in the Tatra Mountains. Although bark beetle seems to be the immediate cause of that decline, long-term elevated levels of atmospheric N and S depositions and elevated O(3) could predispose trees to insect attacks and other stresses. European and US scientists studied pollution deposition, soil and plant chemistry, O(3)-sensitive plant species, forest insects, and genetic changes in the Retezat and Tatra Mountains. Results of these investigations are presented in a GIS format to allow for a better understanding of the changes and the recommendations for effective management in these two areas. 相似文献
3.
Has-Schön E Bogut I Kralik G Bogut S Horvatić J Cacić M Cacić I 《Environmental monitoring and assessment》2008,144(1-3):15-22
Heavy metals concentration (mercury, lead, cadmium, arsenic, copper, zinc and chromium) in tissues (muscles, liver, kidney and gonads) of Dalmatian barbelgudgeon, the nase, the souffie and brown trout, inhabiting waters of Busko Blato reservoir in Bosnia and Herzegovina, has been determined by atomic absorption spectrophotometry. The meat of the tested fish sorts does not contain elevated concentration of most analyzed heavy metals with exception of lead (higher than MAC in Italy, Germany and Denmark) and mercury (in muscles of brown trout higher than MAC in most countries). The lowest level of all heavy metals is always detected in gonads, with higher values in fry compared to milt for copper, zinc, chromium and arsenic. The highest copper concentration is observed in the liver from the souffie which is suggested as a suitable biomonitor for copper intoxication. In muscles of all fish sorts, lead was always present in much higher concentration than cadmium, while in kidneys of most fish sorts, lead and cadmium concentrations were similar. We showed that bioaccumulation of some heavy metals in the fish sorts analyzed is tissue and sex dependent. Also, we concluded that the small water exchange in reversible shallow reservoir does not induce elevated concentration of heavy metals in fish tissues inhabiting Busko Blato. 相似文献
4.
Milan Novakovi? Muftah Mohamed Ali Ramadan Tatjana ?olevi? Knudsen Mali?a Anti? Vladimir Be?koski Gordana Gojgi?-Cvijovi? Miroslav M. Vrvi? Branimir Jovan?i?evi? 《Environmental Chemistry Letters》2012,10(3):287-294
Phenanthrene and methyl-phenanthrenes are major aromatic pollutants originating in particular from fuel oil. Phenanthrene is usually degraded faster than methyl-phenanthrenes under geological and environmental conditions. Here, we report a preferential and accelerated biodegradation of methyl-phenanthrenes versus phenanthrene in soil contaminated by fuel oil. The polluted soil was mixed with sawdust and sand to form a homogenized biopile. The biopile was continuously sprayed with microbial consortia isolated from crude oil?Ccontaminated soil and treated by biosurfactants and nutritive substances for biostimulation. During a 6-month bioremediation experiment, a steady increase in the relative abundance of phenanthrene compared to methyl-phenathrenes was observed by gas chromatography?Cmass spectrometry. The increase was the highest for trimethyl-phenanthrenes, with a phenanthrene/trimethyl-phenanthrenes ratio increasing from 0.42 to 2.45. By contrast, the control, non-stimulated samples showed a ratio decrease from 0.85 to 0.11. Moreover, the results showed that the level of degradability depends on the number of methyl groups. 相似文献
5.
Dragović S Gajić B Dragović R Janković-Mandić L Slavković-Beškoski L Mihailović N Momčilović M Ćujić M 《Journal of environmental monitoring : JEM》2012,14(1):127-137
The specific activities of natural radionuclides ((40)K, (226)Ra and (232)Th) and Chernobyl-derived (137)Cs were measured in soil profiles representing typical soil types of Belgrade (Serbia): chernozems, fluvisols, humic gleysols, eutric cambisols, vertisols and gleyic fluvisols. The influence of soil properties and content of stable elements on radionuclide distribution down the soil profiles (at 5 cm intervals up to 50 cm depth) was analysed. Correlation analysis identified associations of (40)K, (226)Ra and (137)Cs with fine-grained soil fractions. Significant positive correlations were found between (137)Cs specific activity and both organic matter content and cation exchange capacity. Saturated hydraulic conductivity and specific electrical conductivity were also positively correlated with the specific activity of (137)Cs. The strong positive correlations between (226)Ra and (232)Th specific activities and Fe and Mn indicate an association with oxides of these elements in soil. The correlations observed between (40)K and Cr, Ni, Pb and Zn and also between (137)Cs and Cd, Cr, Pb and Zn could be attributed to their common affinity for clay minerals. These results provide insight into the main factors that affect radionuclide migration in the soil, which contributes to knowledge about radionuclide behaviour in the environment and factors governing their mobility within terrestrial ecosystems. 相似文献
6.
Ruzica Micic Snezana Mitic Biljana Arsic Anja Jokic Milan Mitic Danijela Kostic Aleksandra Pavlovic Milan Cekerevac Ljiljana Nikolic-Bujanovic Zaklina Spalevic 《Environmental monitoring and assessment》2015,187(6):389
Zinc, copper, iron, chromium and cobalt are essential elements for human health, showing toxicity only in high concentrations, while lead and cadmium are extremely toxic even as traces. Therefore, it is important to monitor the contents of toxic metals in vegetables. Large number of vegetables is grown and used in nutrition, in Kosovo. The concentrations of selected elements in vegetables (radish, onion, garlic and spinach) from Kosovo were determined using ICP-OES method. Oral intake of metals and health risk index were calculated. Statistical analysis indicated numerous positive correlations between concentrations of selected elements in vegetables. As a result of principal component analysis, 15 new variables were obtained which were characterized by eigenvalues. The sequence of health quotients for the heavy metals followed the decreasing order Zn?=?Mn?>?Pb?>?Cu?>?Ni?>?Fe?>?Cd?>?Co?>?Cr. The health quotients for all investigated heavy metals were below 1 (one), which is considered safe. The vegetables from Kosovo are mainly safe for use in everyday diet. 相似文献
7.
Milan Stra
kraba 《Ecological modelling》2001,140(3)
Based on cybernetic categories of natural control mechanisms, four generations of ecosystem models are distinguished: feed-forward, feedback, self-adaptation and self-organization models. The analysis of the natural control mechanisms in aquatic ecosystems suggests that different processes are controlled in different ways, and, although the four mechanisms were identified in historical sequence, they all operate simultaneously. The concept of self-organization of an ecosystem is introduced and specified for a model of an aquatic pelagic ecosystem. The concept of the ecosystem as a multilayer, multigoal and multiechelon hierarchical system with hierarchy of the levels of biological organization is also introduced. 相似文献
8.
Decision–support systems in the field of integrated water management could benefit considerably from social science knowledge,
as many environmental changes are human-induced. Unfortunately the adequate incorporation of qualitative social science concepts
in a quantitative modeling framework is not straightforward. The applicability of fuzzy set theory and fuzzy cognitive maps
for the integration of qualitative scenarios in a decision–support system was examined for the urbanization of the coastal
city of Ujung Pandang, Indonesia. The results indicate that both techniques are useful tools for the design of integrated
models based on a combination of concepts from the natural and social sciences.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
9.
Rosica Kalčeva Jiří Outrata Zdeněk Schindler Milan Straškraba 《Ecological modelling》1982,17(2):121-128
An interdesciplinary attempt to formalize and numerically solve problems of the management of reservoir eutrophication is presented. A dynamic ecosystem model is treated by means of a generalized penalty optimization technique to calculate the combination of control actions that minimize cost under the condition that given water-quality indices are preserved. 相似文献
10.
Milan Straškraba 《Ecological modelling》1983,18(2):85-97
Hierarchical control formulations are given for a simple predator-prey model: self-optimization of one subsystem, natural multi-goal optimization, man's multiparameter control of an ecosystem and man's control of a self-optimizing ecosystem. Natural multigoal optimization suggests how several levels of an ecosystem can be optimized simultaneously. The idea of management of a self-optimizing ecosystem takes into account the reactions of the ecosystem to man's activity. 相似文献