Influence of phosphorus and trace metals in biofilters treating gaseous VOCs using a novel irrigation system

ABSTRACT

Although the appropriate supply of nutrients has been extensively researched, more information is required on the effects of nutrients in treating gaseous volatile organic compounds (VOCs) in biofiltration. In this study, the effects of phosphorous and trace metals on gaseous toluene and methyl ethyl ketone (MEK) removal were investigated. The transfer of nutrients from the irrigation liquid to the packed bed, and the consumption and holding amount of nutrients in the packing material were observed during biofiltration. Under conditions of 20–24 s of empty bed residence time, MEK removal was 95% or more in all conditions of the biofiltration reactors, whereas toluene removal was affected by the operating conditions of the reactors. Consumption ratio of phosphorus to carbon was from 1.7 × 10^?4 to 1.1 × 10^?3 in the steady state of VOC removal under the conditions of this study. When gaseous VOC treatment was restarted after nine days of shutdown, a significant decline in toluene removal was observed by the reactor in which phosphorus supply was approximately one fifth of the amount in another reactor. Two types of irrigation systems, soaking and spraying, were compared and soaking irrigation achieved a more even distribution of nutrients held inside the packed bed. Soaking irrigation was expected to lead to higher VOC removal capacity by this distribution effect of nutrients, but toluene removal in the reactor with this irrigation was lower than that in the reactor with spraying irrigation. One of the possible reasons for this was the inhibition of nutrients transfer in the bottom part of the reactor. The trend of transfer in all ingredients from the irrigation liquid to the packed bed was synchronized on the whole; however, this transfer relatively tended to be high in nitrate and sodium and low in ammonium and phosphate.

Implications: A major concern about using biofiltration systems to treat VOCs is the uncertainty regarding the appropriate nutrient supply to the filter bed to preserve microbial activity. This study showed that all the elements, except nitrogen, were retained sufficiently in the filter bed when a proper composition of nutrient solution was used for irrigation; however, phosphate addition may be needed when restarting a reactor from a prolonged period of shutdown. Distinct differences in the amount of transfer to the filter bed for different ingredients are probable, and may have to be taken into account when operating biofiltration reactors.     

Using Slides to Test for Changes in Crown Defoliation Assessment Methods. Part I: Visual Assessment of Slides

In this study we used photographs of tree crowns to test whether the assessment methods for tree defoliation in Switzerland have changed over time. We randomly selected 24 series of slides of Norway spruce with field assessments made between 1986 and 1995. The slides were randomly arranged and assessed by three experts without prior knowledge of the year when the slide was taken or the tree number. Defoliation was assessed using the Swiss reference photo guide. Although the correlations between the field assessments and slide assessments were high (Spearman's rank correlation coefficient ranged between 0.79 and 0.83), we found significant differences between field and slide assessments (4.3 to 9% underprediction by the slide assessors) and between the slide assessments. However, no significant trends in field assessment methods could be detected. When the mean differences between field and slide assessments were subtracted, in some years, field assessors consistently underpredicted (1990, 1992) or overpredicted defoliation (1987, 1991). Defoliation tended to be overpredicted in slides taken against the light, and underpredicted for trees with more than 25% crown overlap. We conclude that slide series can be used to detect changes in assessment methods. However, potential observer bias calls for more objective methods of assessment.     

Using slides to test for changes in crown defoliation assessment methods part II: Application of the image analysis system CROCO

We tested whether the semi-automatic program CROCO can replace visual assessments of slides to detect changes in defoliation assessment methods. We randomly selected a series of slides of 24 Norway spruce trees with 220 field assessments made between 1986 and 1995. The slides had been randomly arranged and assessed by three experts without knowledge of the tree number or the year when the slide was taken. Defoliation scores were computed with CROCO. Each tree had thus three different defoliation scores, field assessments, photo assessments and CROCO scores.CROCO scores were less correlated with the field assessments (Spearmans rank correlation: 0.67) than were the slide assessments with the field assessments (0.79–0.83). However, CROCO was not biased against the field scores, while slide assessments systematically underestimated defoliation.In a multi-variate mixed effect model none of the variables tree overlap, tree visibility and light conditions was significant in explaining differences between slide assessors and CROCO scores. The same model applied for the differences from the field scores yielded significant effects for poor light conditions (CROCO and all assessors), for crown overlap (CROCO and one assessor) and for visibility (one assessor). We conclude, therefore, that CROCO can be used to detect past and future changes in assessment methods without bias if poor quality photographs are avoided.     

Detecting Differences in Crown Transparency Assessments Between Countries using the Image Analysis System Croco

Estimates of crown transparency calculated using the semi-automatic image analysis system CROCO were compared withthe visual estimates of survey teams from 12 European countries.For each of five European species (Norway spruce (Picea abies (L.) Karst.), silver fir (Abies alba Mill.), Scotspine (Pinus sylvestris L.), beech (Fagus sylvatica L.), oak (Quercus robur L.)) 15 trees were assessed. In 64\% of the comparisons, CROCO estimates and the survey teams' scores differed significantly, while differences between countries were significant in 58 % of all comparisons. We calculated Spearman's rank correlation and the standard deviation of the differences between CROCO and each country and between pairs of countries. We then computed the medians for CROCO and each country. CROCO and only a few countries hadfor all species a higher median correlation and lower median standard deviation than the median for the comparison between countries. In addition no country had a consistently higher correlation or lower standard deviation than CROCO. We concludethat CROCO can provide more consistent and less variable estimates of crown transparency than visual assessments and that it can serve as a reference to detect differences in visualtransparency assessments between countries over time.     

Changes in Determinants of Deforestation and Forest Degradation in Popa Mountain Park, Central Myanmar

Implementing effective conservation requires an understanding of factors affecting deforestation and forest degradation. Previous studies have investigated factors affecting deforestation, while few studies have examined the determinants of both of deforestation and forest degradation for more than one period. To address this gap, this study examined factors influencing deforestation and forest degradation during 1989–2000 and 2000–2005 in the Popa Mountain Park, Myanmar. We applied multinomial logistic regression (MNL) using land cover maps derived from Landsat images as the dependent variables as well as spatial and biophysical factors as the independent variables. The MNL models revealed influences of the determinants on deforestation and forest degradation changes over time. For example, during 1989–2000, deforestation from closed forest was positively correlated to the distance from the park boundary and was negatively correlated with distance from villages, roads, the park circular road, slope, western aspect and elevation. On the other hand, during 2000–2005, deforestation of closed forest was positively correlated with distance from villages, roads, the park circular road, slope and western aspect, and negatively correlated with distance from the park boundary and elevation. Similar scenarios were observed for the deforestation of open forest and forest degradation of closed forest. The study also found most of the determinants influenced deforestation and forest degradation differently. The changes in determinants of deforestation and forest degradation over time might be attributable to the general decrease in resource availability and to the effect of conservation measures conducted by the park.     

Evaluation of data quality in Japanese National Forest Inventory

We evaluated the quality of data being collected for the Japanese National Forest Inventory (NFI). The inventory program commenced in 1999 but has not incorporated a quality assurance (QA) program; we sought to determine what effect this was having on the quality of data being collected. Forty-eight plots in four prefectures were measured by operational field teams and then remeasured by a control team that made careful and unhurried measurements. The paired data were evaluated, including diameter, total height, tree count, species richness, and topographic condition. Compared to the control team, all field teams of each prefecture tended to significantly underestimate all of the continuous variables. Most variables had larger variability in the inventory data than has been reported in the published literature. The findings of consistent bias and large variation in the field team measurements call for urgent implementation of a quality assurance program (extensive field training and regular remeasurement) in the Japanese NFI to improve data quality, and this conclusion could be applied to the inventory system of any country that does not include a QA program.