Composition and management of rechargeable electric torch wastes in Ibadan,Nigeria

The consumption, disposal, material and chemical compositions of rechargeable electric torch wastes (RETWs) were investigated in Ibadan, Nigeria. Twenty-five RETWs of ten models were collected and disassembled. Their battery electrodes (BEs) and printed circuit boards (PCBs) were acid digested and leached using United States Environmental Protection Agency (USEPA) method 3050B and USEPA Method 1311, respectively. The digests and extracts were analysed for total and extractable Pb, Cd, Cr and Ni using atomic absorption spectrophotometer. The US Test method (CPSC-CH-E 1002-08) was used for digestion of the plastic components. Two hundred questionnaires were distributed to users in Ibadan to determine their usage of RETs and their management when spent. The results indicated that BEs contributed the highest percentage (44 %) component, followed by plastic (38 %). Other components include metal, PCBs, glass and wire. Of the respondents, 61.9 % dispose their spent torches in dumpsites. The mean ± SD concentrations of Pb, Cd, Cr and Ni in the BEs were 500 ± 109 g/kg, 3.94 ± 6.84 mg/kg, 0.33 ± 0.88 mg/kg, 1.68 ± 0.74 mg/kg respectively; in the PCBs, they were 684 ± 42 g/kg, 13.7 ± 17.8 mg/kg, 13.5 ± 10.2 mg/kg and 193 ± 437 mg/kg; and in the plastics, they were 14.1 g/kg, 5.33 mg/kg, 17 mg/kg, and 4.67 mg/kg respectively. The extractable Pb in BE (2670 mg/L) and PCBs (235 mg/L) exceeded the Toxicity Characteristics Leaching Procedure (TCLP) limit of 5 mg/L. RETWs present potential environmental problems in the absence of effective recycling.     

Overview of Environmental Hazards and Health Effects of Pollution in Developing Countries: A Case Study of Nigeria

Pollution has taken on a global dimension, and the effects are most obvious in developing countries. The effects take a toll on human health, animals, and vegetation, as well as on soil, air, and water quality. The objective of this article is to discuss the current relationships among pollution, environmental quality, and human health within the frame of anthropogenic activities in developing countries. In addition to personal observations, we review relevant literature on conditions throughout the developing world and case studies on conditions and activities in Nigeria. Key findings show the significant, adverse contributions to human health and environmental risk from current waste generation and handling practices, indoor and outdoor air pollution, wastewater and effluent generation and disposal, the hazardous nature and pollution potential of wastes, and the human behaviors that contribute to pollution in developing countries. There is an urgent need to create awareness among the various segments of society of the human health hazards posed by pollution as well as a need for the comprehensive development and enforcement of appropriate policies to prevent a descent into an abyss of deteriorating human and environmental health.     

Current Levels and Management of Solid Wastes in Nigeria

Solid waste is of serious concern in developing countries because of its high rate of generation and the low‐end quality of its management. Inefficient handling of solid wastes may result in deterioration of environmental quality, but it can also result in loss of potential resources. This study reviews current solid waste generation and management in Nigeria and the need for an effective collection, recovery, and recycling policy. Our review is based on literature searches and personal field surveys. Observations showed that uncontrolled electronic waste (e‐waste), agricultural‐waste (agro‐waste), scrap metals, waste polymers, and waste from the transportation sector are prevalent in Nigeria. Recent collection rates were less than 50% of the total solid waste generated (i.e., approximately 40% was collected). With an effective collection system and appropriate policies, the abundance of solid waste in the country could present material recovery and recycling opportunities that would boost the economy and move Nigeria closer to sustainable resource management.     

Sound management of brominated flame retarded (BFR) plastics from electronic wastes: State of the art and options in Nigeria

Management of flame retarded plastics from waste electrical and electronic equipment (WEEE) has been posing a major challenge to waste management experts because of the potential environmental contamination issues especially the formation of polybrominated-dioxins and -furans (PBDD/F) during processing. In Nigeria, large quantities of electronic waste (e-waste) are currently being managed—a significant quantity of which is imported illegally as secondhand electronics. As much as 75% of these illegal imports are never reused but are rather discarded. These waste electronic devices are mostly older equipment that contains brominated flame retardants (BFRs) such as penta-brominated diphenyl ethers (PBDEs), and polybrominated biphenyls (PBBs) which are presently banned in Europe under the EU WEEE and RoHS Directives. Risk assessment studies found both to be persistent, bio-accumulative and toxic. The present management practices for waste plastics from WEEE in Nigeria, such as open burning and disposal at open dumps, creates potential for serious environmental pollution. This paper reviews the options in the environmentally sound management of waste plastics from electronic wastes. Options available include mechanical recycling, reprocessing into chemicals (chemical feedstock recycling) and energy recovery. The Creasolv^® and Centrevap^® processes, which are the outcome of the extensive research at achieving sound management of waste plastics from WEEE in Europe, are also reviewed. These are solvent-based methods of removing BFRs and they presently offer the best commercial and environmental option in the sound management of waste BFR-containing plastics. Because these developments have not been commercialized, WEEE and WEEE plastics are still being exported to developing countries. The industrial application of these processes and the development of eco-friendlier alternative flame retardants will help assure sound management of WEEE plastics.     

Accumulation of lead and cadmium by four tropical forage weeds found in the premises of an automobile battery manufacturing company in Nigeria

The potentials of tropical weeds namely, Nephrolepis biserrata, Panicum maximum, Eleusine indica, and Chromolaena odorata to accumulate lead (Pb) and cadmium (Cd) from soil within the premises of an automobile battery manufacturing company in Ota, south-western Nigeria, were explored. The weed samples were collected in both wet and dry seasons. Standard analytical methods were employed to collect, digest, and analyze the weeds. Lead levels in the weeds for both seasons ranged from 1990–4870, 1090–1730, 4800–7890, and 400–1210 µg g^?1 dry weight (DW) for Nephrolepis biserata, Panicum maximum, Eleusine indica, and Chromolaena odorata, respectively, while the cadmium level in the weeds for both seasons ranged from 3.92–6.78 µg g^?1 DW for N. biserata, 1.99–6.85 µg g^?1 DW for P. maximum, 2.90–7.40 µg g^?1 DW for E. indica, and 2.90–5.09 µg g^?1 DW for C. odorata. There was no significant difference in the accumulation of both Pb and Cd for the two seasons. All the weeds showed Pb levels higher than the phytotoxic range. On the contrary, 99% of the weeds showed Cd concentration within the phytotoxic range. The weeds demonstrate good phytoremediation potentials of contaminated soil.     

Metal levels in computer monitor components discarded in the vicinities of electronic workshops

Levels of Pb, Ni, Cr, Cu, Zn, and Cd in the glass screens (GS) and printed wiring boards (PWBs) of obsolete computer monitors (OCMs) were determined by flame atomic absorption spectrophotometry (FAAS) following standard digestion. Metal concentrations (mg kg^?1) in GS were in the following ranges (medians in brackets): Pb ND – 3100 (46), Cd 0.5–2.6 (0.8), Cr ND – 18.7 (3.1), and Zn 8.1–600 (37) and in PWBs (mg kg^?1): Pb 34,600 ± 17,000, Cd 11 ± 9, Cr 59 ± 45, Zn 15,900 ± 7800, Cu79,000 ± 22,600, and Ni 3200 ± 2500. In GS, the levels of the six metals were lower than their total threshold limit concentrations (TTLC), except for Pb with a TTLC of 1000 mg kg^?1 in 10% of the samples. In the PWBs, the TTLC of Pb and Cu (2500 mg kg^?1) was exceeded many fold. For Zn (5000 mg kg^?1) and Ni (2000 mg kg^?1); they were exceeded by 90% and 65%, respectively. For OCMs manufactured in 2001 and later, Pb and Zn levels in GS and Cr, Zn, and Ni in PWBs were significantly reduced.     

Spectroscopy properties and optimization for the detection of mercury（Ⅱ） with series hydroxyl-porphyrins

结合紫外分光光度法研究系列羟基卟啉与汞离子的显色反应,并优化其检测条件.在pH=7.5的条件下,以N,N-二甲基甲酰胺（DMF）作为溶剂,加入0.4 mL表面活性剂Tween-80,系列羟基卟啉与Hg2＋发生配位反应,发现其最大吸收峰与卟啉环上（meso）位苯基对位上的羟基数目相关.热力学研究表明,单羟基卟啉化合物对Hg2＋检测效果最好,形成1∶1配位化合物,检测限可达0.042μg.L-1,且在0—50 mg.L-1范围内符合比尔定律.     

Contrasts in Livelihoods and Protein Intake between Commercial and Subsistence Bushmeat Hunters in Two Villages on Bioko Island,Equatorial Guinea

Across West and Central Africa, wildlife provides a source of food and income. We investigated the relation between bushmeat hunting and household wealth and protein consumption in 2 rural communities in Bioko Island, Equatorial Guinea. One village was dedicated to commercial hunting, the other trapped game primarily for food. We tested whether commercial‐hunter households were nutritionally advantaged over subsistence‐hunter households due to their higher income from the bushmeat trade and greater access to wild‐animal protein. We conducted bushmeat‐offtake surveys in both villages (captures by hunters and carcasses arriving to each village). Mammals (including threatened primates: black colobus [Colobus satanas], Preussi's guenon [Allochrocebus preussi], and russet‐eared guenon [Cercopithecus erythrotis]), birds, and reptiles were hunted. The blue duiker (Philantomba monticola), giant pouched rat (Cricetomys emini), and brush‐tailed porcupine (Atherurus africanus) contributed almost all the animal biomass hunted, consumed, or sold in both villages. Monkeys and Ogilbyi's duikers (Cephalophus ogilbyi) were hunted only by commercial hunters. Commercial hunters generated a mean of US$2000/year from bushmeat sales. Households with commercial hunters were on average wealthier, generated more income, spent more money on nonessential goods, and bought more products they did not grow. By contrast, households with subsistence hunters spent less on market items, spent more on essential products, and grew more of their own food. Despite these differences, average consumption of vegetable protein and domestic meat and bushmeat protein did not differ between villages. Our results highlight the importance of understanding the socioeconomic and nutritional context of commercial and subsistence bushmeat hunting to correctly interpret ways of reducing their effects on threatened species and to enable the sustainable offtake of more productive taxa. Contrastes en el Sustento y la Ingesta de Proteínas entre Carne de Caza de Subsistencia y Comercial en Dos Aldeas en Isla Bioko, Guinea Ecuatorial     

California households' willingness to pay for ‘green’ electronics

Concerns about rapid increases in the volume of electronic waste (e-waste) and its potential toxicity have sharpened policy makers' interest for extended producer responsibility to encourage manufacturers of consumer electronic devices (CEDs) to ‘design for the environment’. This paper examines consumer willingness to pay for ‘green’ electronics based on a 2004 mail survey of California households. Using ordered logit models, it was found that significant predictors of willingness to pay for ‘greener’ computers and cell phones include age, income, education, beliefs about the role of government for improving environmental quality, as well as environmental attitudes and behaviors, but neither gender nor political affiliation. Although most respondents are willing to pay only a 1% premium for ‘greener’ CEDs, innovation and EU directives may soon make them competitive with conventional CEDs.