Strontium isotope study of coal utilization by-products interacting with environmental waters

Sequential leaching experiments on coal utilization by-products (CUB) were coupled with chemical and strontium (Sr) isotopic analyses to better understand the influence of coal type and combustion processes on CUB properties and the release of elements during interaction with environmental waters during disposal. Class C fly ash tended to release the highest quantity of minor and trace elements-including alkaline earth elements, sodium, chromium, copper, manganese, lead, titanium, and zinc-during sequential extraction, with bottom ash yielding the lowest. Strontium isotope ratios ((87)Sr/(86)Sr) in bulk-CUB samples (total dissolution of CUB) are generally higher in class F ash than in class C ash. Bulk-CUB ratios appear to be controlled by the geologic source of the mineral matter in the feed coal, and by Sr added during desulfurization treatments. Leachates of the CUB generally have Sr isotope ratios that are different than the bulk value, demonstrating that Sr was not isotopically homogenized during combustion. Variations in the Sr isotopic composition of CUB leachates were correlated with mobility of several major and trace elements; the data suggest that arsenic and lead are held in phases that contain the more radiogenic (high-(87)Sr/(86)Sr) component. A changing Sr isotope ratio of CUB-interacting waters in a disposal environment could forecast the release of certain strongly bound elements of environmental concern. This study lays the groundwork for the application of Sr isotopes as an environmental tracer for CUB-water interaction.     

Photo-dissociation of dimethylamine by KrBr excilamp

A study of dimethylamine photo-dissociation in the gas phase has been conducted using UV radiation delivered from a KrBr^* excilamp, driven by a sinusoidal electronic control gear with maximum emission at wavelength of 207 nm. The electrical input power and radiant power of the lamp were measured to determine their effects on the degradation. The influence of flow velocity and initial concentration of dimethylamine were also examined. In order to evaluate the photo-dissociation process comprehensively, several parameters were investigated, including removal efficiency, energy yield, carbon balance and CO₂ selectivity. It is shown that the removal efficiency increases with enhanced input power and decreased gas flow rate. A high removal efficiency of 68% is achieved for lamp power 102 W and flow velocity 15 m³ h⁻¹. The optimum dimethylamine initial concentration is around 3520 mg m⁻³, for which the energy yield reaches up to 442 g kW h⁻¹ when the input power is 65 W. In addition, two chain compounds (1,3-bis-dimethylamino-2-propanol; 3-penten-2-one, 4-amino) and three ring organic matters (1-azetidinecarboxaldehyde, 2,2,4,4-tetramethyl; N-m-tolyl-succinamic acid; p-acetoacetanisidide), were identified by GC–MS as secondary products, in order to demonstrate the pathways of the dimethylamine degradation.     

Comparison of criteria for prediction of runaway reactions in the sulphuric acid catalyzed esterification of acetic anhydride and methanol

Loss of temperature control is one of the major reasons that can lead to runaway reaction. This occurrence is commonly named thermal runway. The aim of this paper is the application of thermal runaway criteria in order to predict the onset of runaway phenomena and define the range of stability related to operating conditions in the reactor, with specific reference to the esterification of acetic anhydride and methanol catalysed by sulphuric acid tested in isoperibolic conditions. The isoperibolic calorimeter has also been used to obtain thermodynamic, kinetic and physical chemistry data necessary to develop a model for the reaction. Some runaway criteria applied in this work require a model for the process, so a model for the analyzed system been developed.Because of the modest reaction enthalpy and low activation energy this reacting system provide a severe test to the runaway criteria.In this work, various runaway criteria have been applied to the experimental and simulated data and the results obtained have been compared.     

A Systems Approach to Biodiversity Conservation Planning

With a recent media-fueled transition from a scientific to a political perspective, biodiversity has become an issue of ethics and ensuing values, beyond its traditional ecological roots. More fundamentally, the traditional perspective of biodiversity is being challenged by the emergence of a post-normal or systems-based approach to science. A systems-based perspective of living systems rests on the central tenets of complexity and uncertainty, and necessitates flexibility, anticipation and adaptation rather than prediction and control in conservation planning and management. What are the implications of this new perspective? This paper examines these challenges in the context of biodiversity conservation planning. The new perspectives of biodiversity are identified and explored, and the emergence of a new ecological context for biodiversity conservation is discussed. From the analysis, the challenges and implications for conservation planning are considered, and a systems-based or post-normal approach to conservation planning and management is proposed. In light of the new perspectives for biodiversity, conservation planning and management approaches should ultimately reflect the essence of living systems: they should be diverse, adaptive, and self-organizing, accepting the ecological realities of change.     

Practical and ethical considerations of agricultural research assistance for the Third World

The right to eat and to an adequate standard of living for everyone motivates agricultural research assistance to developing countries with the primary objective of assuring sufficient food supply. This article focuses on aspects of food production and related agricultural research with specific examples from animal production. It discusses ethics of agricultural research in light of the utilitarian theory and compares livestock production in developing and developed countries. Major reasons for low outputs of animal production in developing countries are identified, and the potential for increasing the productivity of original, extensive production systems is evaluated. The article reviews the current status of biotechnology in developing countries and discusses several advanced animal technologies. The conclusions emphasize the need to involve local professionals in all phases of research and technology transfer in developing countries, avoidance of research that may worsen the situation of the recipients, sustainability of production systems, and the need for detailed assessment of potential impacts of technology on recipients.     

Using DNA barcoding to track seafood mislabeling in Los Angeles restaurants

Seafood mislabeling is common in both domestic and international markets. Studies on seafood fraud often report high rates of mislabeling (e.g., >70%), but these studies have been limited to a single sampling year, which means it is difficult to assess the impact of stricter governmental truth‐in‐labeling regulations. We used DNA barcoding to assess seafood labeling in 26 sushi restaurants in Los Angeles over 4 years. Seafood from 3 high‐end grocery stores were also sampled (n = 16) in 2014. We ordered 9 common sushi fish from menus, preserved tissue samples in 95% ethanol, extracted the genomic DNA, amplified and sequenced a portion of the mtDNA COI gene, and identified the resulting sequence to known fish sequences from the National Center for Biotechnology Information nucleotide database. We compared DNA results with the U.S. Food and Drug Administration (FDA) list of acceptable market names and retail names. We considered sushi‐sample labels that were inconsistent with FDA names mislabeled. Sushi restaurants had a consistently high percentage of mislabeling (47%; 151 of 323) from 2012 to 2015, yet mislabeling was not homogenous across species. Halibut, red snapper, yellowfin tuna, and yellowtail had consistently high (<77%) occurrences of mislabeling on menus, whereas mislabeling of salmon and mackerel were typically low (>15%). All sampled sushi restaurants had at least one case of mislabeling. Mislabeling of sushi‐grade fish from high‐end grocery stores was also identified in red snapper, yellowfin tuna, and yellowtail, but at a slightly lower frequency (42%) than sushi restaurants. Despite increased regulatory measures and media attention, we found seafood mislabeling continues to be prevalent.     

Fast-track remediation for redevelopment of a former integrated steel mill site

Remedial action was initiated and completed on an approximately 500-acre brownfield site in southern California within a period of five months during the summer of 1995. Remedial actions included design and construction of an approximately 14-acre cap, including a synthetic membrane; design, construction, and testing of an in-situ soil vapor extraction system; excavation, on-site treatment, and off-site disposal of approximately 7,000 cubic yards of residual waste and affected soil; and verification sampling, analysis, and health risk screening in 20 units of a former integrated steel mill. Completion of remedial action on this portion of the mill site within this time frame was required due to site redevelopment plans which included construction of an auto raceway with scheduled races in early 1997. Rapid remedial action was possible only through simultaneous completion of multiple remediation tasks. This could be done only with continuous communication and close coordination among the site owner, lead regulatory agency, and contractors.