Effect of Bimetallic Soybean Oil Based Polymer on Growth and Plasma Membrane H+-ATPase Activity Among Fungi

In view of bio-inorganic importance, iron and zinc incorporated soybean oil based polymer was prepared by condensation polymerization of oil based fatty amide polyole, sebacic acid, zinc acetate and ferric chloride in a process initiated by sodium ethoxide. Microwave assisted synthesis was used throughout the reaction as it is ecofriendly and requires minimal usage of solvents. Physical techniques such as FT-IR and ¹HNMR have been used to establish the structure of the polymers. Standard laboratory methods like acid value, saponification value, iodine value, specific gravity and viscosity were used to study the chemical diversity of each product. Thermo gravimetry/differential thermal analyzer was used to analyse the thermal behavior of polymer. The synthesized compounds were subjected to biological study. The observed fungicidal characteristics of synthesized compounds indicate that these compounds might be promising antifungal agents defining a new class of antimycotics. The polymers were used in preparation of films which can be used as protective packaging material of edible items.     

EMPIRICAL MODELING OF HYDROLOGIC AND NFS POLLUTANT FLUX IN AN URBANIZING BASIN1

ABSTRACT: Long term effects of precipitation and land use/land cover on basin outflow and nonpoint source (NFS) pollutant flux are presented for up to 24 years for a rapidly developing headwater basin and three adjacent headwater basins on the urban fringe of Washington, D.C. Regression models are developed to describe the annual and seasonal responses of basin outflow and IMPS pollutant flux to precipitation, mean impervious surface (IS), and land use. To quantify annual change in mean IS, a variable called delta IS is created as a temporal indicator of urban soil disturbance. Hydrologic models indicate that total annual surface outflow is significantly associated with precipitation and mean IS (r²= 0.65). Seasonal hydrologic models reveal that basin outflow is positively associated with IS during the summer and fall growing season (June to November). NPS pollutant flux models indicate that total and storm total suspended solids (TSS) flux are significantly associated with precipitation and urban soil disturbance in all seasons. Annual NPS total nitrogen flux is significantly associated with both urban and agricultural soil disturbance (r²= 0.51). Seasonal models of phosphorus flux indicate a significant association of total phosphorus flux with urban soil disturbance during the growing season. Total soluble phosphorus (TSP) flux is significantly associated with IS (r²= 0.34) and urban and agricultural soil disturbance (r²= 0.58). In urbanizing Cub Run basin, annual TSP concentrations are significantly associated with IS and cultivated agriculture (r²= 0.51).     

Removal and pre-concentration of phenolic species onto beta-cyclodextrin modified poly(hydroxyethylmethacrylate-ethyleneglycoldimethacrylate) microbeads

Poly(Hydroxyethylmethacrylate-Ethyleneglycoldimethacrylate), poly(HEMA-EGDMA), microbeads with 150-200 microm in size, was prepared by suspension polymerization. Beta-cyclodextrin was modified onto the polymeric microbeads using glutaraldahyde activation in an acidic medium at pH=2.5. FT-IR and TGA were used for the characterization of modified polymers and the determination of the nature of the interaction between phenolic compounds and the modified polymeric microbeads. Plain and beta-cyclodextrin modified microbeads were used in adsorption-desorption studies of phenolic species in single solution. Adsorption capacities of the phenolic species onto the plain microbeads were found to be 28.2, 17.0, 14.3, 9.8, and 1.92 mg/g polymer for o-chloro phenol, p-nitro phenol, p-chloro phenol, o-nitro phenol, and phenol, respectively. However, for beta-cyclodextrin modified microbeads, adsorption capacity of phenolic species was determined as 274, 365, 128, 182, and 87 mg/g for phenol, o-nitro phenol, p-nitro phenol, o-chloro phenol, and p-chloro phenol, respectively. Desorption ratio for the phenolic species was more than 90%, except for o-nitro phenol. Detection limits of the phenolic species were improved at least 500-fold for UV-Vis spectrophotometric detection, after the pre-concentration of all phenolic species used in this study. Adsorption time for the phenolic species onto beta-cyclodextrin-modified poly(HEMA-EGDMA) microbeads was found to be reasonable short (10-60 min) and suitable for the applications. Also, synthesized microbeads were useful for the repeated use for the removal and pre-concentration of phenolic species.     

The correlation of total and extractable heavy metals from soil and domestic sewage sludge and their transfer to maize ( Zea mays L.) plants

A study to understand the mobility and transport of heavy metals (HMs) from soil and soil amended with sewage sludge to maize plants was carried out. The total and ethylenediaminetetraaceticacid (EDTA)-extractable HMs in agricultural soil and untreated domestic sewage sludge samples, and the correlation between the total and extractable metals in soil and sewage sludge were carried out. Pot experiments were performed to study the transfer of HMs to maize grains, grown in soil (control) and in soil amended with sewage sludge (test samples). The total and extractable HMs in soil, sewage sludge, and maize grains were analysed by FAAS/ETAAS (flame atomic absorption spectrometer/electrothermal atomic absorption spectrometer) after digestion in microwave oven. Statistically significant correlations were obtained between the total contents of Cu, Cd, As and their respective extractable fractions in soil, while in domestic wastewater sludge (DWS) the better correlation was observed only for Ni and Cd. The edible part of maize plants (grains) from test samples presented high concentration of Zn, Pb, Ni, Cd, Cu, As, and Cr concentrations (80.7–85.6, 3.8–3.95, 2.35–2.5, 0.75–0.82, 3.21–3.29, 0.23–0.27, and 0.22–0.29?mg?kg^?1, respectively). Good correlations were found between metals in exchangeable fractions of both soil and DWS and total metals in control and test samples of maize grains. The transfer factor of all HMs from DWS to maize grains was also determined.     

推广新能源汽车碳减排和大气污染控制的协同效益研究——以上海市为例

随着我国机动车数量的持续增长,交通运输行业已经成为仅次于工业部门的第二大能源消费部门,也是温室气体排放和空气污染物的主要贡献部门.为了支持低碳发展,自2009年起,中国便开始使用新能源汽车取代传统燃油汽车.通过上海市2016年纯电动和插电式混合动力的私家车、出租车和公交车的行驶情况、能源消耗和排放因子等数据,对新能源汽车运行过程以及所需电能生产过程中产生的大气污染物和CO₂的排放量进行了测算,利用协同控制坐标系评价和污染物减排量交叉弹性分析方法探讨了新能源汽车的协同减排能力与效果.基于协同效益潜力分析结果,对推广3类新能源汽车的协同效益进行了排序,结果表明纯电动公交车具有最佳的碳减排和大气污染控制协同效益,纯电动以及插电式混合动力私家车和出租车对CO、NO_x、NMHC、PM₁₀都具有协同效益,而插电式混合动力公交车不具备协同效益.     

Lead Content of Petrol and Diesel and its Assessment in an Urban Environment

Pakistan is one of the few countries in Asia thatcontinues to use only leaded-petrol as vehicular fuel. Theconcentration of Pb in its petrol reported in 1991 was thehighest (1.5 – 2.0 g Pb L^-1) of all produced by the various Asiancountries and far exceeded the WHOs guideline of 0.15 g Pb L^-1. We have undertaken a study to trace and quantify this toxicelement in the environs of Karachi, Pakistans major metropolis,having more than 30% of the nations total number of vehicles.In this article we report the Pb contents of petrol and dieselcurrently manufactured and marketed in the city. Samples of`Regular petrol collected in 1999 was found to contain 0.363 gPb L^-1 (range: 0.335 – 0.390 g Pb L^-1), a factor of 5 lower than thatmarketed prior to 1991. Its concentration in diesel fuel was muchlower (0.017 g Pb L^-1). Based on the available statistical data onthe type and volume of vehicular traffic, we assessed that thecurrent lead emission from vehicular traffic into the atmosphereis 391 metric tons a year, which is a factor of 2.7 lower thanthat estimated for 1989.     

Correction to: Evaluation of hydrochar efficiency for simultaneous removal of diclofenac and ibuprofen from aqueous system using surface response methodology

Environmental Science and Pollution Research - The original publication of this paper contain typographical mistakes.     

Evaluation of hydrochar efficiency for simultaneous removal of diclofenac and ibuprofen from aqueous system using surface response methodology

Environmental Science and Pollution Research - Pharmaceutically active compounds like diclofenac (DFS), ibuprofen (IBP), and other drugs that persist in the environment are listed as emerging...     

Energy and Sustainable Development at Global Environmental Summits: An Evolving Agenda

This paper presents a framework for understanding energy issues in the context of sustainable development. It posits that there are three important ways in which energy is related to sustainable development: (a) energy as a source of environmental stress, (b) energy as a principal motor of macroeconomic growth and (c) energy as a prerequisite for meeting basic human needs. These three dimensions correspond to the three dimensions of the often-used triangle of sustainable development: environmental, economic, and social. Using this framework, the paper traces how successive environmental summits at Stockholm (1972), Rio de Janeiro (1992) and Johannesburg (2002) have dealt with energy issues. It identifies a slow, surprising and important evolution of how energy issues have been treated at these global discussions. Energy has received increasing prominence at these meetings and become more firmly rooted in the framework of sustainable development. Stockholm was primarily concerned with the environmental dimension, Rio de Janeiro focused on both the environmental and economic dimensions, and the major headway made at Johannesburg was the meaningful addition of the social dimension and the linking of energy issues to the UN's Millennium Development Goals.     

The relationship between corporate social responsibility and financial performance: a moderate role of fintech technology

Environmental Science and Pollution Research - This study explores the new area of corporate social responsibility (CSR) and financial performance in the context of the fintech technology. The...