Effects of sulfur dioxide and nitric oxide on mercury oxidation and reduction under homogeneous conditions

This paper is particularly related to elemental mercury (Hg0) oxidation and divalent mercury (Hg2+) reduction under simulated flue gas conditions in the presence of nitric oxide (NO) and sulfur dioxide (SO2). As a powerful oxidant and chlorinating reagent, Cl2 has the potential for Hg oxidation. However, the detailed mechanism for the interactions, especially among chlorine (Cl)-containing species, SO2, NO, as well as H2O, remains ambiguous. Research described in this paper therefore focused on the impacts of SO2 and NO on Hg0 oxidation and Hg2+ reduction with the intent of unraveling unrecognized interactions among Cl species, SO2, and NO most importantly in the presence of H2O. The experimental results demonstrated that SO2 and NO had pronounced inhibitory effects on Hg0 oxidation at high temperatures when H2O was also present in the gas blend. Such a demonstration was further confirmed by the reduction of Hg2+ back into its elemental form. Data revealed that SO2 and NO were capable of promoting homogeneous reduction of Hg2+ to Hg0 with H2O being present. However, the above inhibition or promotion disappeared under homogeneous conditions when H2O was removed from the gas blend.     

Formation of PCDD/Fs in the sintering process: role of the grid-Cr2O3 catalyst in the de novo synthesis

The sintering process is among the major sources of the very toxic polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/Fs) in the environment. At the industrial scale, it has been shown that dust collected on the grid, which supports the feed, contains PCDD/Fs amounts between the values found in the bottom of the cake and the values found on dust collected during gas sampling in the wind boxes. This fact suggests that the grid, containing 25wt.% of chromium, could have a catalytic activity in PCDD/Fs formation during the sintering process. This research tries to study this potential role. The de novo synthesis of PCDD/Fs is simulated at laboratory scale by thermal treatments of samples mixed with grid filings or Cr2O3. The thermal experiments performed with E.S.P. dust (dust collected in the electrostatic precipitator of a sintering plant) or graphite mixed with grid filings do not allow to confirm a role of the grid in PCDD/Fs formation during the industrial process. On the other hand, it has been shown that Cr2O3 can be considered as a catalyst in the de novo synthesis of PCDD/Fs. This compound takes place in the two steps of the de novo synthesis: the degradation of the carbon matrix as well as the chlorination reactions.     

Why businessmen should be honest: The argument from rational egoism

You are a business owner who has just taken out a loan to manufacture a new high technology product, for which you have lucrative orders. Although you thought you could make the product to specifications, you have not been able to do so. You will not be able to meet the delivery deadline and cash is running short — so short that it is threatening the viability of the rest of your business. Things are in a critical state, but you desperately want the product to succeed. You have several options. You could tell the customers about your problems, ask for a postponement of the deadline, and hire an outside consultant to help with the product. But this will anger your customers, take time and not solve your cash flow problem. You could also get another bank loan by telling the bank's president that you need it to expand an old line of business. You know he will refuse more money for the new product, but he does not have to be told how you will actually use the money. The loan will take a while to process but you need money now. You can get it from your children's college savings accounts; it would upset your wife (who helped fund the accounts) and the kids, but you do not have to tell them and can repay later. You can also borrow money from the employee pension fund. The employees do not have to know. Finally, you can ship the products even though they do not meet specs, and hope that nobody finds out right away. You can use customers' payment to pay back the various loans and worry about fixing the product later. What should you do? Should you take the honest route or the dishonest route? Clearly, you have to make a moral choice, but you can only do so by reference to a moral code. In this essay we will address three questions: (1) What are the main moral codes that have been accepted throughout the centuries and what are their views on honesty? (2) Why are they inadequate and what would be a rational moral code and its argument for honesty? (3) How would one apply it to the issue of businessmen being honest?     

Effects of long-term chlorpyrifos exposure on mortality and reproductive tissues of Banded Gourami (Trichogaster fasciata)

Abstract

This study assessed the long-term toxicity of chlorpyrifos on survival and reproduction of Banded Gourami by using mortality, gonado-somatic index (GSI) and histopathological observations as endpoints. Adult fish were exposed to five different concentrations of chlorpyrifos (0, 15, 50, 150, 500?µg/L) in 15 PVC tanks for 15, 30, 45, 60 and 75?days. Results showed that all male and female fish died after 15?days of 500?µg/L chlorpyrifos exposure. No consistent significant effect was observed for both male and female GSI. Furthermore, results showed dose- and time-dependent histopathological alterations for both ovary and testes. The 60-d No Observed Effect Concentration (NOEC) for most histopathological alterations of Banded Gourami ovary and testes was 50?μg/L, while 60-d NOEC for mortality of both male and female fish was < 15?μg/L. The results show that the long-term exposure to chlorpyrifos not only affect the reproductive tissues of Banded Gourami at exposure concentrations but also cause their mortality. Future studies should evaluate effects at lower concentrations.     

ESTIMATING THE WATER QUALITY BENEFITS FROM SOIL EROSION CONTROL1

ABSTRACT: A framework for estimating the water quality benefits from soil erosion was developed. The framework is based on the linkages between soil erosion and offsite damages. The linkages are: erosion on the field, movement of eroded materials to waterways, impact of discharged material on water quality parameters, impact of water quality changes on ability of water to provide economic services, and the economic value of the changes in water use. These linkages need to be modeled in order to estimate the water quality benefits from reductions in soil erosion. Methods for modeling each link on a geographic level, which enables the analyses of national soil conservation, were examined. Areas where data or models were found to be lacking include transport of sediment and nutrients to water systems, impact of discharged materials on water quality parameters, and impact of water quality on ability of water to provide economic services. An economic evaluation of 1983 soil conservation programs was presented as an example of how the framework could be used. A number of simplifying assumptions were made to represent links that could not be modeled with available data.     

Channelization and levee construction in Illinois: Review and implications for management

The environmental impact of loss of natural stream and riparian habitat is of concern throughout the United States and Europe. Environmental impacts related to such activities as channelization of and levee construction along streams and rivers are particularly apparent in the Midwestern United States. The objective of the research presented here was to delineate the extent, relative degree of impact, and implications for management of channelization and levee construction along watercourses located in the state of Illinois. According to records maintained through the Illinois Streams Information System data base (Illinois Department of Conservation), nearly 25% of surface water resources in the state have been modified directly by channelization and/or levee construction. Reviews of agency records, elaboration of case histories, interviews with agency personnel, and inspections of impacted sites indicated that these alterations have occurred without the benefit of effective mitigation. Although permit records may provide suggestions for mitigation to be incorporated in the design of a particular project, permits issued generally do not require even minimal instream habitat and bank stabilization efforts in conjunction with channel alteration. Information derived from policy and case study analyses suggests that institutional constraints, rather than lack of particular understanding about mitigation, provide major barriers to protecting the state's surface water resources in terms of regulatory review, policy interpretation and implementation, and project evaluation. Recommendations for environmental management efforts regarding these and similar channel alterations are elaborated from these findings.