Radioactive sulphate (35SO4) was applied to the soil below a Scots pine forest on 23 June 1989, and its movement into the canopy and into throughfall and stemflow was measured over 4 months. The specific activity, Bq (mg S)(-1), of the canopy increased monotonically; uptake by current-year (1989) expanding needles was initially twice as fast as by older needles or live twigs. By 10 October the canopy average specific activity was 62 Bq (mg S)(-1). The specific activity of net throughfall (throughfall + stemflow - rain), deduced from measurements from six throughfall collectors, six stemflow collectors and two rain collectors, fell rapidly from 12.6 Bq (mg S)(-1) in late July to <1 Bq (mg S)(-1) in mid-August. The results suggest (assuming rapid equilibration of 35S with sulphate in soil) that root-derived sulphate contributed c. 3% of sulphate in net throughfall and that dry deposition of SO2 and sulphate particles contributed c. 97% of the 0.56 g S m(-2) measured in net throughfall over the period. Simultaneous measurements of SO2 at canopy height and of NH3 above and within the canopy gave mean concentrations of 5.9 and 0.86 microg m(-3), respectively, sufficient to account for the sulphate measured in net throughfall only if codeposition of NH3 and SO2 occurred to canopy surfaces. The large values of specific activity observed in July, however, indicate that throughfall composition may be closely related to recent soil input of sulphate, and that equilibrium cannot be safely assumed. The possibility of a significant contribution of soil-derived sulphate to sulphate deposition in net throughfall cannot be ruled out on the basis of this experiment. 相似文献
Chromium concentrations of up to 91 mg l(-1) were found by ICP-OES for ground water from nine boreholes at four landfill sites in an area of S.E. Glasgow/S. Lanarkshire where high-lime chromite ore processing residue (COPR) from a local chemical works had been deposited from 1830 to 1968. Surface water concentrations of up to 6.7 mg l(-1) in a local tributary stream fell to 0.11 mg l(-1) in the River Clyde. Two independent techniques of complexation/colorimetry and speciated isotope dilution mass spectrometry (SIDMS) showed that Cr was predominantly (>90%) in hexavalent form (CrVI) as CrO4(2-), as anticipated at the high pH (7.5-12.5) of the sites. Some differences between the implied and directly determined concentrations of dissolved CrIII, however, appeared related to the total organic carbon (TOC) content. This was most significant for the ground water from one borehole that had the highest TOC concentration of 300 mg l(-1) and at which < 3% of Cr was in the form of CrVI. Subsequent ultrafiltration produced significant decreases in Cr concentration with decreasing size fractions, e.g. <0.45 microm, < 100 kDa, <30 kDa and < 1 kDa by the tangential-flow method. As this appeared related more to concentrations of humic substances than of TOC per se, horizontal bed gel electrophoresis of freeze-dried ultrafilter retentates was carried out to further characterise the CrIII-organic complex. This showed for the main Cr-containing fraction, 100 kDa-0.45 microm, that the Cr was associated with a dark brown band characteristic of organic (humic) matter. Comparison of gel electrophoresis and FTIR results for ultrafilter retentates of ground water from this borehole with those for a borehole at another site where CrVI predominated suggested the influence of carboxylate groups, both in reducing CrVI and in forming soluble CrIII-humic complexes. The implications of this for remediation strategies (especially those based on the addition of organic matter) designed to reduce highly mobile and carcinogenic Cr(VI)O4(2-) to the much less harmful CrIII as insoluble Cr(OH)3 are discussed. 相似文献
While many studies and reviews into the practices conducted by industry and academia to recycle and remanufacture carbon fibre-reinforced plastic (CFRP) exist, to date no investigation exists which regards the correctness of the use of the terms recycling and remanufacturing. As such, this paper seeks to analyse the CFRP reuse industry’s attempt to recycle and remanufacture manufacturing waste CFRP and end-of-life (EOL) CFRP with an emphasis on the terminology used to describe these practices. Firstly, this paper presents a justification of the importance of using EOL terminology correctly; outlining the benefits and problems associated with using the correct and incorrect terminology. This paper finds that in the case of CFRP remanufacturing, terminology is being applied incorrectly and in the case of CFRP recycling, particular care should be taken when applying the term recycled to CFRP or stating that CFRP has been recycled. Further, this paper proposes new terminology (in keeping with EU directives) which could be adopted by industry and academia working in this area. This paper also finds that in the case of remanufacture, CFRP is incapable of being remanufactured. 相似文献
Soil water/distribution coefficients (Kd) have been measured for the partitioning of naphthalene, phenanthrene and pyrene between aqueous surfactant solutions and a clean soil. The surfactants used are ABA block copolymers constructed from ethylene oxide (the monomer used to synthesise the hydrophilic A blocks) and propylene oxide (used for the manufacture of the hydrophobic B block). Three of these surfactants comprising the same size propylene oxide block but different ethylene oxide/propylene oxide ratios were investigated. Increasing amounts of surfactant in the system result in a progressive decrease in the Kd values signifying an increasing tendency for the hydrophobic solutes to be dispersed in aqueous solution due to the action of the surfactant. More significantly for equal surfactant doses the most hydrophobic surfactant possessing the lowest ethylene oxide/propylene oxide ratio reduces Kd by the greatest amount whereas the most hydrophilic surfactant reduces Kd the least. Finally micellar HPLC using the above surfactants and hydrophobic solutes was undertaken. Interpolated capacity factors evaluated for particular surfactant doses correlated well with Kd values calculated for the same surfactant doses. The relationship between Kd and capacity was found to be log-linear and the correlation line could be fitted to the data obtained for all three surfactants. It is therefore concluded that micellar HPLC may be used for preliminary evaluations of the effectiveness of particular surfactants proposed for contaminated soils restoration schemes. 相似文献
With lack of affordable housing being clearly identified as a social and economic exclusion issue for most communities, innovative ways of addressing this deficiency should be considered. Increasingly local communities are engaging with the possibility of direct provision themselves and discussion around this notion has profound implications for community cohesion. One community-based solution gaining popular support within communities, and with government ministers, is the Community Land Trust mechanism. This involves control and ownership of land to help ensure affordable housing is built and remains affordable in perpetuity for the community. The language and difficulties with definition of terms, together with the complexity of engaging relevant stakeholders in a changing policy and legislative framework can be problematic. This may lead to apparent lack of consensus within communities on the way forward. Perceptions of local housing issues and ways to address them are sometimes vague, sometimes diverse but rarely apathetic. This paper includes data from two case studies in North East England, which are examined using interviews with key players, as a means of seeking some practical solutions. 相似文献
Regional Environmental Change - Plausible scenarios of future land use derived from model projections may differ substantially from what is actually desired by society, and identifying such... 相似文献
Mitigation and Adaptation Strategies for Global Change - The objective of the study was to outline a global scheme for furthering mitigation of climate change in the Managed Forest subsector of the... 相似文献
The continuously growing global demands on a finite land resource will require better strategic policies and management of trade-offs to avoid conflicts between different land-use sectors. Visions of the future can support strategic planning by stimulating dialogue, building a consensus on shared priorities and providing long-term targets. We present a novel approach to elicit stakeholder visions of future desired land use, which was applied with a broad range of experts to develop cross-sectoral visions in Europe. The approach is based on (i) combination of software tools and facilitation techniques to stimulate engagement and creativity; (ii) methodical selection of stakeholders; (iii) use of land attributes to deconstruct the multifaceted sectoral visions into land-use changes that can be clustered into few cross-sectoral visions, and (iv) a rigorous iterative process. Three cross-sectoral visions of sustainable land use in Europe in 2040 emerged from applying the approach in participatory workshops involving experts in nature conservation, recreation, agriculture, forestry, settlements, energy, and water. The three visions—Best Land in Europe, Regional Connected and Local Multifunctional—shared a wish to achieve a land use that is sustainable through multifunctionality, resource use efficiency, controlled urban growth, rural renewal and widespread nature. However, they differ on the scale at which land services are provided—EU-wide, regional or local—reflecting the land-sparing versus land-sharing debate. We discuss the usefulness of the approach, as well as the challenges posed and solutions offered by the visions to support strategic land-use planning.
Adsorption at the air–water interface and soil sorption from aqueous solution have been investigated for a group of ethylene oxide (EO)–propylene oxide (PO) block copolymeric surfactants. The group which have a common structural formula of EOm POn EOm is distinguished by the fact that they have large critical micelle concentration (CMC) values and therefore do not readily form micelles at common environmental concentrations and temperatures. Adsorption at the air–water interface is readily shown to be driven by the size of the hydrophobic PO block. The size of the reduction in surface tension produced by a common concentration of 10−5 mol dm−3 linearly increases with the size of the PO block as does the efficiency of adsorption at the air–water interface as measured by pC20 – the negative logarithm of the surfactant concentration that produces a reduction in surface tension of 20 mN m−1. Soil sorption data have also been captured for these compounds and the data are readily fitted to the Freundlich adsorption isotherm. However soil sorption is shown to be inversely related to the molecular mass of the molecules and appears to be related to the size of the hydrophilic EO blocks in the molecule. 相似文献