Development of an efficient and sensitive analytical method for the determination of copper at trace levels by slotted quartz tube atomic absorption spectrometry after vortex-assisted dispersive liquid-liquid microextraction in biota and water samples using a novel ligand

This study describes the determination of trace levels of copper by slotted quartz tube atomic absorption spectrometry after dispersive liquid-liquid microextraction. A ligand synthesized from the reaction of salicylaldehyde and 1-naphthylamine was used to form coordinate copper complex prior to extraction. All parameters that influence the output of complex formation, extraction, and instrumental measurement were optimized to enhance the absorbance signal of copper. Under the optimum conditions, about 104-fold enhancement in sensitivity was recorded over the conventional flame atomic absorption spectrometer, corresponding to a 0.51 ng/mL detection limit. The percent relative standard deviation calculated for the lowest concentration (4.8%) indicated high precision for the experimental procedure. Accuracy and applicability of the optimum method were determined by performing spiked recovery tests on urine, lake water, and mineral water samples. Satisfactory recovery results were obtained between 82.2 and 106.3% at four different concentrations. Matrix matching method was also performed to increase the accuracy of quantification, and the percent recovery calculated for 175 ng/mL was 105.14%.     

Energy and exergy analysis of a solid-oxide fuel cell power generation system for an aerial vehicle (ISSA- 2015–139)

This paper presents the performance of the solid-oxide fuel cell/gas turbine hybrid power generation system with heat recovery waste unit based on the energy and exergy analyses. The effect of air inlet temperature and air/fuel ratio on exergy destruction and network output is determined. For the numerical calculations, air inlet temperature and air fuel ratio are increased from 273 to 373 K and from 40 to 60, respectively. The results of the numerical calculations bring out that total exergy destruction quantity increases with the increase of air inlet temperature and air/fuel ratio. Furthermore, the maximum system overall first and second law efficiencies are obtained in the cases of air inlet temperature and air/fuel ratio equal to 273 K and 60, respectively, and these values are 62.09% and 54.91%.     

Fuzzy Logic Model to Estimate Seasonal Pseudo Steady State Chlorophyll-A Concentrations in Reservoirs

A fuzzy logic model is developed to estimate pseudo steady state chlorophyll-a concentrations in a very large and deep dam reservoir, namely Keban Dam Reservoir, which is also highly spatial and temporal variable. The estimation power of the developed fuzzy logic model was tested by comparing its performance with that from the classical multiple regression model. The data include chlorophyll-a concentrations in Keban lake as a response variable, as well as several water quality variables such as PO₄ phosphorus, NO₃ nitrogen, alkalinity, suspended solids concentration, pH, water temperature, electrical conductivity, dissolved oxygen concentration and Secchi depth as independent environmental variables. Because of the complex nature of the studied water body, as well as non-significant functional relationships among the water quality variables to the chlorophyll-a concentration, an initial analysis is conducted to select the most important variables that can be used in estimating the chlorophyll-a concentrations within the studied water body. Following the outcomes from this initial analysis, the fuzzy logic model is developed to estimate the chlorophyll-a concentrations and the advantages of this new model is demonstrated in model fitting over the traditional multiple regression method.     

Taguchi optimization of geopolymer concrete produced with rice husk ash and ceramic dust

Environmental Science and Pollution Research - Metakaolin, fly ash, and mostly granulated blast furnace slag (GBFS) are traditionally used in the production of geopolymer. This study, adding to the...     

Evaluating the circular economy–based big data analytics capabilities of circular agri-food supply chains: the context of Turkey

Environmental Science and Pollution Research - Agri-food supply chains (AFSCs) are one of the significant building blocks of agricultural production, and their sustainability aims are advanced by...     

A study on the environmental and economic aspects of aircraft emissions at the Antalya International Airport

Environmental Science and Pollution Research - In the last decade, aircraft-induced environmental issues have attracted much research interest. In addition to studies on performance related...     

Detection of current and potential hazelnut plantation areas in Trabzon, North East Turkey using GIS and RS

Monitoring agricultural products requires the periodic determination of land cover and the production of land use policies in an optimum way. The hazelnut is one of the important Turkish agricultural exports and Turkey provides 77% of the world's hazelnuts. In Turkey, hazelnut production exceeds the demand; new regulations have been enacted to create new land use policies. By putting into practice regulations restricting hazelnut plantation areas, a more efficient and productive hazelnut harvest policy could be created. Therefore, more information on existing land cover is required to determine optimum (or ideal) potential hazelnut areas (PHA) and to forecast future crop production. The principle aim of this study is to create a methodology for determining existing PHA, using Geographic information system (GIS) and remote sensing (RS) techniques regarding to support hazelnut policy developers and economists. This study was basically carried out in the province of Trabzon, which is one of the most important hazelnut production areas in Turkey. Landsat ETM+ image was used to generate a current land cover classification. Using the supervised classification method, overall accuracy was determined to be 84.7%. Suitable hazelnut areas were determined according to criteria settled by government regulations.     

BMP estimation of landfilled municipal solid waste by multivariate statistical methods using specific waste parameters: case study of a sanitary landfill in Turkey

The main objective of this study was to determine whether methane potential of waste could be estimated more easily by a limited number of waste characterization variables. 36 samples were collected from 12 locations and 3 waste depths in order to represent almost all waste ages at the landfill. Actual remaining methane potential of all samples was determined by the biochemical methane potential (BMP) tests. The cumulative methane production of closed landfill (cLF) samples reached 75–125 mL at the end of experiment duration, while the samples from active landfill (aLF) produced in average 216–266 mL methane. The average experimental k and L ₀ values of cLF and aLF were determined by non-linear regression using BMP data with first-order kinetic equation as 0.0269 day^?1–30.38 mL/g dry MSW and 0.0125 day^?1–102.1 mL/g dry MSW, respectively. The principal component analysis (PCA) was applied to analyze the results for cLF and aLF along with BMP results. Three PCs for the data set were extracted explaining 72.34 % variability. The best MLR model for BMP prediction was determined for seven variables (pH–Cl–TKN–NH4–TOC–LOI–Ca). R ² and Adj. R ² values of this best model were determined as 80.4 and 75.3 %, respectively.     

Assessment of some trace heavy metals and radioactivity concentration in water of Bendimahi River Basin (Van, Turkey)

The levels of heavy metals were determined in the water of Bendimahi River Basin, statistically analysed and compared to natural gross radioactivity concentration. Fifteen samples of water were collected from Bendimahi River and Van Lake for two seasons in 2005. Water samples were analyzed for eight trace elements and concluded together with gross-alpha and gross-beta radioactivity concentrations. Atomic absorption spectrometry (AAS) was used to determine the concentrations of heavy metals in water samples collected from Bendimahi River basin. Correlation analysis was made for radioactivity and heavy metal concentrations and the Pearson correlation coefficients between gross-alpha and gross-beta radioactivity and heavy metal were determined. The concentrations of all metals were found to be higher than WHO, EC, EPA and TSE-266 guidelines for drinking water, except for Zn and Cu. Generally, the heavy metal concentrations in water samples obtained in May and in August were found to be in sequence of Fe>Zn>Pb>Cr>Cu>Mn>Co>Cd and Fe>Zn>Cu>Pb>Cr>Mn>Co>Cd, respectively. The gross-alpha and gross-beta activity concentration varies between 0.063 and 0.782, 0.021 and 0.816 Bq l(-1) in samples collected in May, and 0.009 and 0.037, 0.081 and 3.116 Bq l(-1) in samples collected in August.     

Gross alpha and beta radioactivity concentration in water, soil and sediment of the Bendimahi River and Van Lake (Turkey)

The concentrations of the natural radioactivity in water, soil and sediment samples collected from Bendimahi River which originates near the Tendürek Mountain (Van, Turkey), its tributaries and Van Lake (Turkey) were measured. The gross-alpha and gross-beta radioactivity concentrations were investigated in May and August in 2005. Determination of the gross-alpha and gross-beta radioactivity of river water, soil and sediment samples was obtained by using gas-flow proportional counter, PIC-MPC 9604-alpha/beta counter. In water samples, the obtained results show that in May; gross-alpha and gross-beta activity concentrations varied between 0.063-0.782 and 0.021-0.816 Bq l(-1) and in August the values were 0.009-0.037 and 0.081-3.116 Bq l(-1), respectively. The gross-alpha and gross-beta activity concentrations in soil samples ranged from 0.800 to 4.277 Bq g(-1) and 0.951 to 11.773 Bq g(-1) in May and 0.686 to 4.713 Bq g(-1) and 0.073 to 9.524 Bq g(-1) in August, respectively. Concentrations ranging from 0.782 to 4.596 Bq g(-1) and from 0.482 to 10.372 Bq g(-1) in May and from 0.580 to 5.824 Bq g(-1) and from 0.303 to 9.702 Bq g(-1) in August for gross-alpha and gross-beta radioactivity were observed in sediments, respectively.