Alnus shrub expansion increases evapotranspiration in the Swiss Alps

Regional Environmental Change - Shrub encroachment is one of the main consequences of abandonment of montane grassland. Higher surface roughness of shrubs leads to stronger aerodynamic coupling....     

Investigation of NiO/NiAl2O4 oxygen carriers for chemical-looping combustion produced by spray-drying

Chemical-looping combustion is a novel combustion technology with inherent separation of the greenhouse gas CO₂. The technology uses circulating oxygen carriers to transfer oxygen from the combustion air to the fuel. In this paper, oxygen carriers based on commercially available NiO and α-Al₂O₃ were prepared using the industrial spray-drying method, and compared with particles prepared by freeze-granulation. The materials were investigated under alternating oxidizing and reducing conditions in a laboratory fluidized bed, thus simulating the cyclic conditions of a chemical-looping combustion system. The particles produced by spray-drying displayed a remarkable similarity to the freeze-granulated oxygen carriers, with high reactivity when the bed was fluidized and similar physical properties when sintered at the same temperature. This is an important result as it shows that the scaling-up from a laboratory production method, i.e. freeze-granulation, to a commercial method suitable for large-scale production, i.e. spray-drying, did not involve any unexpected difficulties. A difference noticed between the spray-dried and freeze-granulated particles was the sphericity. Whereas the freeze-granulated particles showed near perfect sphericity, a large portion of the spray-dried particles had hollow interiors. Defluidization was most likely to occur for highly reduced particles, at low gas velocities. The apparent density and crushing strength of the oxygen carriers could be increased either by increasing the sintering temperature or by increasing the sintering time. However, the fuel conversion was fairly unchanged when the sintering temperature was increased but was clearly improved when the sintering time was increased.     

Unraveling the causes of the toxicity of extremely acid waters of volcanic origin

A river ecosystem in East Java, Indonesia, fed by a volcanic lake with high concentrations of dissolved metals and a low pH, was found to support only few macroinvertebrates. To unravel the causes of toxicity and to determine the level of dilution necessary to obtain non-toxic water, a bioassay was conducted with the fairy shrimp Thamnocephalus platyurus. A partial toxicity identification evaluation (TIE) approach was used with EDTA as a chelating agent to relate toxicity to pH and metal concentrations. Three water samples were tested, with pHs ranging from 0.72 to 4.5, and diluted with water from a neutral river to different degrees. The dilution factor necessary to achieve no more than 50% mortality in the Thamnotox test (Ldf(50)) varied from >300 at the most acidic site, to 7 for water of pH 2.6 and 1.5 for water of pH 4.5. Toxicity was best explained from both low pH and high concentrations of metals, especially Al and Fe. The key role of Al and Fe in the toxicity was confirmed by relating concentrations of the different compounds in the river water to toxicity data from the literature. EDTA addition did not significantly influence Ldf(50) or the lethal pH 50% (LpH(50)), suggesting a large effect, besides cationic components and pH, of anions (F, SO(4) and Cl).     

Inter‐organisational communication in civil–military cooperation during complex emergencies: a case study in Afghanistan1

This paper seeks to contribute to an improved information management and exchange between humanitarian organisations and military agents in complex emergencies. To do so, a theoretical information management process model was developed and applied to the case of information management between International Security Assistance Force troops and humanitarian organisations such as Cordaid, DACAAR and the International Office for Migration in Kabul, Afghanistan. Based on this analysis the main shortcomings and problems in each stage of the information management process were identified. These include a lack of structured information databases, the absence of identification of information needs, and an over‐classification of documents by the military. Using a logical framework analysis, six major improvement tactics were developed, including the creation of more overlap in rotations of personnel, the specification of aims and tasks regarding information management, the improvement of skills and competences of personnel involved, and the introduction of regular joint civil–military evaluations.     

The potential use of Atlantic silverside (Menidia menidia) for monitoring estuarine pollution

Monitoring chronic impacts of nearshore pollution on fish in Atlantic marine systems is challenging due to the mobility and seasonal nature of most habitat use. We evaluated Atlantic silverside (Menidia menidia) as a potential indicator of pollution across a gradient of contaminated sites in the Saint John River Estuary, New Brunswick, Canada. Fish returning from offshore in the spring showed no differences in length, weight, or condition factor between sites, but a graded response in condition factor appeared gradually, consistent with levels of contamination. Gonad size peaked in early June, however no differences in GSI were found among sites. By September, most fish collected were young of the year, with a significant bias towards female juveniles at the exposed site. These results indicate that Atlantic silverside are locally resident during their onshore period, and demonstrates their potential as a sentinel species. Sampling should focus on early June prior to the full moon to ensure maximal exposure periods before spawning, or in late October to evaluate growth as fish grow rapidly prior to offshore movement.