The content of fine sand (< 200 μm) in primary sludge is relatively high in Chongqing sewage treatment plant owing to the part of rainwater will be mixed with sand and discharged into the municipal pipe network. Due to the insufficient separation of the sand, different obstacles to subsequent treatment processes may increase equipment wear, reduce effective volume of the tank, or shorten the cleaning cycle. There is a common use of grit chamber for the separation. Nevertheless, the use of hydrocyclone shows an outstanding performance in cost effectiveness and ease operation. The primary sludge in a sewage plant in Chongqing was monitored, and the average concentration of total suspend solids (TSS), total sand content, and volatile suspended solid (VSS) were 40.25 g/L, 17.51 g/L, and 13.41 g/L, respectively. The size of sand in the sludge was small, and the sand below 30 μm accounted for about 70% of the total sand. It formed flocs with organic matter and was removed in subsequent process units. While the size between 30–200 μm, called fine sand, was the main separation object, accounted for about 28.5%. According to XRF and XRD analysis, the sludge composition was mainly composed of quartz (SiO2), plagioclase (Na(AlSi3O8)), and calcite (CaCO3), which were similar to the main mineral composition of surface sediments and mountain rocks in the main urban area of Chongqing. A single-factor experiment on two types (FX100 and FX50) of hydrocylones was conducted to determine their abilities concerning the separation of fine sand and enrichment of organic matters from primary sludge. FX100 and FX50 showed best performance in the case of P = 0.17 Mpa, underflow diameter (Du) = 18 mm and P = 0.20 Mpa, Du = 6 mm, respectively. The removal efficiency of fine sand by hydrocyclone FX50 was 71.39%. While, it had poor performance on organic matter enrichment and the removal efficiency of which was 17.38%. By contrast, the removal rate by FX100 reached 61.89% for fine sand and only 6.89% for organic matters detached. The superimposition effect did not appear in the serial experiments on hydrocylone FX100 and FX50, but the power is 3.5 times of that of single-stage hydrocylone FX100. Comprehensive consideration of the processing capacity per unit time and operating power, the hydrocylone FX100 was more suitable for actual operation.
Soil contamination with tetrabromobisphenol A(TBBPA) has caused great concerns;however, the presence of heavy metals and soil organic matter on the biodegradation of TBBPA is still unclear. We isolated Pseudomonas sp. strain CDT, a TBBPA-degrading bacterium, from activated sludge and incubated it with ~(14)C-labeled TBBPA for 87 days in the absence and presence of Cu~(2+)and humic acids(HA). TBBPA was degraded to organic-solvent extractable(59.4% ± 2.2%) and non-extractable(25.1% ± 1.3%) metabolites,mineralized to CO_2(4.8% ± 0.8%), and assimilated into cells(10.6% ± 0.9%) at the end of incubation. When Cu~(2+)was present, the transformation of extractable metabolites into non-extractable metabolites and mineralization were inhibited, possibly due to the toxicity of Cu~(2+)to cells. HA significantly inhibited both dissipation and mineralization of TBBPA and altered the fate of TBBPA in the culture by formation of HA-bound residues that amounted to 22.1% ± 3.7% of the transformed TBBPA. The inhibition from HA was attributed to adsorption of TBBPA and formation of bound residues with HA via reaction of reactive metabolites with HA molecules, which decreased bioavailability of TBBPA and metabolites in the culture. When Cu~(2+)and HA were both present, Cu~(2+)significantly promoted the HA inhibition on TBBPA dissipation but not on metabolite degradation. The results provide insights into individual and interactive effects of Cu~(2+)and soil organic matter on the biotransformation of TBBPA and indicate that soil organic matter plays an essential role in determining the fate of organic pollutants in soil and mitigating heavy metal toxicity. 相似文献
Photocatalytic ozonation of phenol and oxalic acid （OA） was conducted with a Ag^＋/TiO2 catalyst and different pathways were found for the degradation of different compounds. Ag^＋ greatly promoted the photocatalytic degradation of contaminants due to its role as an electron scavenger. It also accelerated the removal rate of OA in ozonation and the simultaneous process for its complex reaction with oxalate. Phenol could be degraded both in direct ozonation and photolysis, but the TOC removal rates were much higher in the simultaneous processes due to the oxidation of hydroxyl radicals resulting from synergetic effects. The sequence of photo-illumination and ozone exposure in the combined process showed quite different effects in phenol degradation and TOC removal. The synergetic effects in different combined processes were found to be highly related to the properties of the target pollutants. The color change of the solution and TEM result confirmed that Ag＋ was easily reduced and deposited on the surface of Tit2 under photo-illumination, and dissolved again into solution in the presence of ozone. This simple cycle of enrichment and distribution of Ag^＋ can greatly benefit the design of advanced oxidation processes, in which the sequences of ozone and photo-illumination can be varied according to the needs for catalyst recycling and the different properties of pollutants. 相似文献
