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The concentrations of ammonium NH4+, nitrate NO3-, and nitrite NO2- ions were recorded along with ammonia (NH(3)) emission from a fertilized rice field located in the Kwangju province in South Korea over a period of 4 months (June to October 2006). The highest magnitude of NH(3) flux was 20,754 microg m(-2) h(-1), while the average flux value over the entire sampling period was 2,395 microg m(-2) h(-1). The highest ionic concentrations were 1.67, 0.44, and 0.71 ppm for NH4+, NO3-, and NO2- ions, respectively. Possible effects of soil pH on NH(3) fluxes were detected, as they concurrently exhibited a gradual and periodic change during the sampling period. Positive correlations existed between concentrations of NH4+ and NO2- ions and the soil pH. Positive correlations also existed between NH(3) emission flux and ambient (and water) temperatures. Results indicated that fertilizer application to rice can lead to significant emission of NH(3) along with NH4+ and NO3- ions. 相似文献
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还田秸秆配施外源纤维素酶效应研究 总被引:3,自引:1,他引:3
为探求促进秸秆降解的新途径,采用室内培养法研究了外源纤维素酶对秸秆降解速率及土壤速效养分的影响。结果表明,整个培养期内,小麦秸秆,玉米秸秆加酶处理与不加酶处理降解率都存在极显著差异(p<0.01),到培养结束时小麦秸秆加酶处理降解率高出不加酶处理7.10%~11.86%,玉米秸秆高出8.01%~14.04%;整个培养期内,小麦秸秆,玉米秸秆加酶处理与不加酶处理间土壤速效氮、磷、钾含量都存在极显著差异(p<0.01),培养结束时,小麦秸秆最优处理速效氮、磷、钾含量高出对照4.15mg·kg-1,3.60mg·kg-1,32.35mg·kg-1,玉米秸秆高出6.50mg·kg-1,4.27mg·kg-1,47.97mg·kg-1。结果说明添加外源纤维素酶能够提高秸秆降解速率,促进秸秆养分矿化。 相似文献
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Dragan R. Milićević Verica B. Jurić Srđan M. Stefanović Slavica M. Vesković-Moračanin Saša D. Janković 《Journal of environmental science and health. Part. B》2013,48(8):781-787
This study was undertaken to compare two different analytical methods for the determination and confirmation of ochratoxin A (OTA) in blood serum, kidney and liver of pigs. Sample clean-up was based on liquid-liquid phase extraction. The detection of OTA was accomplished with high-performance liquid chromatography (HPLC) combined either with fluorescence detection (FL) or electro spray ionization (ESI+) tandem mass spectrometry (MS–MS). Comparative method evaluation was based on the investigation of 90 samples of blood serum, kidney and liver per animal originating from different regions of Serbia. The analytical results are discussed in view of the respective method validation data and the corresponding experimental protocols. In general, analytical data obtained with (LC–MS–MS) liquid chromatography electro spray tandem mass spectro metry detection offered comparable good results at the sub-ppb concentration level. The results indicate that the liquid chromatography electro spray tandem mass spectrometric (LC-MS/MS) method was more specific and sensitive for the analysis and confirmation of ochratoxin A in pig tissues then high pressure liquid chromatography (HPLC) method after methylation of OTA. 相似文献
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油田作业废水高效处理技术中试研究 总被引:1,自引:0,他引:1
文章根据新疆油田作业废水特征及油田地处干旱区的地理特点,结合国内外含聚合物污水处理的技术现状,以及油田连续生产稳定运行的要求,在含油污水处理技术的基础上,开展了作业废水处理关键技术研究和工艺优化,采用了"隔油—絮凝气浮—深层过滤"技术。中试试验结果表明:处理后废水COD_(Cr)、石油类、SS可分别由680 mg/L、98.6 mg/L、56.2 mg/L降至98.8 mg/L、5.4 mg/L、4.5 mg/L,去除率分别为85.5%、94.5%、92.0%。 相似文献
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Moreno-Jiménez E Vázquez S Carpena-Ruiz RO Esteban E Peñalosa JM 《Journal of environmental management》2011,92(6):1584-1590
Re-vegetation is the main aim of ecological restoration projects, and in Mediterranean environments native plants are desirable to achieve successful restoration. In 1998, the burst of a tailings dam flooded the Guadiamar river valley downstream from Aznalcóllar (Southern Spain) with sludges that contained elevated concentrations of metals and metalloids, polluting soils and waters. A phytoremediation experiment to assess the potential use of native shrub species for the restoration of soils affected by the spillage was performed from 2005 to 2007, with soils divided into two groups: pH < 5 and pH > 5. Four native shrubs (Myrtus communis, Retama sphaerocarpa, Rosmarinus officinalis and Tamarix gallica) were planted and left to grow without intervention. Trace element concentrations in soils and plants, their extractability in soils, transfer factors and plant survival were used to identify the most-interesting species for phytoremediation. Total As was higher in soils with pH < 5. Ammonium sulphate-extractable zinc, copper, cadmium and aluminium concentrations were higher in very-acid soils, but arsenic was extracted more efficiently when soil pH was >5. Unlike As, which was either fixed by Fe oxides or retained as sulphide, the extractable metals showed significant relationships with the corresponding total soil metal concentration and inverse relationships with soil pH. T. gallica, R. officinalis and R. sphaerocarpa survived better in soils with pH > 5, while M. communis had better survival at pH < 5. R. sphaerocarpa showed the highest survival (30%) in all soils. Trace element transfer from soil to harvestable parts was low for all species and elements, and some species may have been able to decrease trace element availability in the soil. Our results suggest that R. sphaerocarpa is an adequate plant species for phytostabilising these soils, although more research is needed to address the self-sustainability of this remediation technique and the associated environmental changes. 相似文献
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Sa V. Ho B. Mason Hughes Philip H. Brodsky John S. Merz Larry P. Egley 《补救:环境净化治理成本、技术与工艺杂志》1999,9(3):103-116
Originated from a recognized need for significantly more effective technologies for soil cleanup, the LasagnaTM project provides an interesting case study in which industry, government, and academia successfully collaborated to rapidly advance the technology from the laboratory to the field. Called LasagnaTM because of its layered configurations, the technology combines electrically induced contaminant transport in soils, treatment in place, and geotechnical methods to achieve completely in situ clean-up of contaminated soils. Experiences with respect to the partnership, the development of technology and its current commercialization status are described. 相似文献