Towards a rational design of materials for the removal of environmentally relevant cations: polymer inclusion membranes (PIMs) and surface-modified PIMs for Sn2+ sequestration in aqueous solution

Environmental Science and Pollution Research - This work is focused on the design and preparation of polymer inclusion membranes (PIMs) for potential applications for stannous cation sequestration...     

The 2006 war and its inter-temporal economic impact on agriculture in Lebanon

The July 2006 war waged by Israel on Lebanon caused an estimated USD 1 billion of direct (financial) damage to infrastructure. However, it generated also significant indirect (economic/inter-temporal) costs. One sector that suffered considerably in this respect was agriculture, the main source of income for 30–40 per cent of Lebanese. This paper's main objective is to develop a methodology to estimate the total—direct and indirect—cost of the war to agricultural crop production, using an area of south Lebanon as a focal point. The indirect loss assessment viewed inter-temporal reductions in crop production values as the opportunity cost of not working fields due to the presence of unexploded ordnance (UXO). Various crops were evaluated for two scenarios (50 and 100 per cent damage due to UXO) over UXO-clearance periods of five and 10 years. The results indicate that any damage estimates that include only direct losses will under-estimate total losses by 80 and 87 per cent for the five- and 10-year periods, respectively.     

Impact of overland traffic on heavy metal levels in highway dust and soils of Istanbul, Turkey

The purpose of this study was to investigate the impact of overland traffic on the spatial distribution of heavy metals in urban soils (Istanbul, Turkey). Road dust, surface, and subsurface soil samples were collected from a total of 41 locations along highways with dense traffic and secondary roads with lower traffic and analyzed for lead (Pb), zinc (Zn), and copper (Cu) concentrations. Statistical evaluation of the heavy metal concentrations observed along highways and along the secondary roads showed that the data were bimodally distributed. The maximum observed Pb, Zn, and Cu concentrations were 1,573, 522 and 136 mg/kg, respectively, in surface soils along highways and 99.3, 156, and 38.1 mg/kg along secondary roads. Correlation analysis of the metal concentrations in road dust, surface and 20-cm depth soils suggests the presence of a common pollution source. However, metal concentrations in the deeper soils were substantially lower than those observed at the surface, indicating low mobility of heavy metals, especially for Pb and Zn. A modified kriging approach that honors the bimodality of the data was used to estimate the spatial distribution of the surface concentrations of metals, and to identify hotspots. Results indicate that despite the presence of some industrial zones within the study area, traffic is the main heavy metal pollution source.     

Identifying forest ecosystem services through socio-ecological bundles: a case study from northern Jordan

This study aims to identify services provided by forest ecosystems based on locals’ perceptions in the northern part of Jordan. By better understanding preferences of locals and by understanding why they value certain services more heavily, policy-makers and planning managers can make more effective decisions regarding development and conservation. Three hundred respondents were interviewed in order to collect information about forest ecosystem services (ES). Data collection was conducted using a structured questionnaire regarding ES provided by three forest types situated in northern Jordan. ES trade-offs and socio-ecological bundles were identified by analyzing respondents’ socioeconomic demographics and preferences of forest ES through multivariate canonical corresponding analysis (CCA). The statistical analysis indicated that the socioeconomic factors and forest type have an effect on social preferences toward ES. Results displayed a clear trade-off between provisioning services and regulating and cultural services. CCA demonstrated that 73% of the variation in ES value is explained by social factors (i.e. education level, income level, and gender), while 26% of perception variation was attributable to categories of ES supplied by each forest ecosystem. These findings imply that involving people in the place-specific management of public forests using the ES approach gives managers a clearer understanding of the benefits people recognize and value, as well as those they either are not aware of or do not value. Such information is useful in forest management and in public outreach. Although direct policy applications are limited by the research’s nature, the paper provides a starting point for incorporating forest users’ voices into policy discussions and management design.     

Prevalence and predictors of occupational asthma among workers in detergent and cleaning products industry and its impact on quality of life in El Asher Men Ramadan,Egypt

Environmental Science and Pollution Research - Cleaning products are mixtures of many chemical ingredients that are known to contain sensitizers, disinfectants, and fragrances, as well as strong...     

The three-dimensional structure of 3,3',4,4'-tetrachlorobiphenyl, a dioxin-like polychlorinated biphenyl (PCB)

The crystal structure of PCB 77 (3,3',4,4'-tetrachlorobiphenyl, C(12)H(6)Cl(4)), a dioxin-like PCB congener, is described. The dihedral angle of PCB 77 is 43.94(6) degrees, which is slightly larger than calculated or experimental dihedral angles of biphenyl derivatives in solution but smaller than experimental dihedral angles in the gas phase.     

Impact of dilution on the transport of poly(acrylic acid) supported magnetite nanoparticles in porous media

This paper investigates the impact of dilution on the mobility of magnetite nanoparticles surface coated with poly(acrylic acid) (PAA). Transport experiments were conducted in a water-saturated sand-packed column for input nanoparticle solutions with total Fe concentrations ranging from 100 to 600mg/L. Particle size analysis of the synthesized nanoparticle solutions showed that PAA provides good size stability for Fe concentrations as low as about 1mg/L. Time-moment analysis of the nanoparticle breakthrough curves, on the other hand, revealed that nanoparticle mass recovery from the column decreased consistently with dilution, with greater attenuation, sharper fronts and longer tails compared to that of the tracer. Particle size analysis of the eluted solutions shows that the nanoparticle size is negatively correlated with nanoparticle concentration. Modeling results suggest that the decrease in nanoparticle mobility with input concentration can be represented using a kinetic time-dependent deposition term with finite deposition capacity and a kinetic detachment term. For field applications, the increase in particle size and detachment resulting from dilution means reduced transport efficiency of nanoparticles and reaction potential with travel distance.     

The cardioprotective effects of L-carnitine on rat cardiac injury,apoptosis, and oxidative stress caused by amethopterin

Amethopterin is used as a chemotherapeutic agent, and its antioxidant activity is used to treat many cancer types. This study aimed to study the ameliorating effect of L-carnitine against amethopterin-induced cardiac injury and oxidative stress in male rats. Sixty male albino rats were equally divided into six groups; the first and second groups were the control and L-carnitine groups, respectively, while the third group was treated with amethopterin rat group; the fourth and fifth groups were co-treated and post-treated with amethopterin rat with L-carnitine, respectively, and the sixth group was self-treated with amethopterin rat group. Cholesterol, triglycerides, low-density lipoprotein (LDL), glutathione, and total protein levels in amethopterin group showed a significant decrease when compared with control group, while high-density lipoprotein (HDL), glutamic oxaloacetic transaminase (GOT), malondialdehyde (MDA), catalase, and nitric oxide (NO) levels in amethopterin group showed a significant increase when compared with control group. Cholesterol, triglycerides, LDL, GOT, MDA, and catalase levels in the self-treated group showed a significant increase when compared with amethopterin group, while glutathione, total protein, and NO levels in the self-treated group showed significant decrease when compared with amethopterin group. Many of abnormalities as moderate hydrophobic changes of myofibrillar structure with striations, myocardial atrophy, cytoplasmic vacuoles, edema, and leukocyte infiltration were detected in cardiac tissues in amethopterin rat group. A significant increase of the apoptotic protein p53 and CD68 immunoreactivity, despite a significant decrease in the antiapoptotic Bcl–2 proteins after amethopterin injection when compared with control group, was observed. Treatment (co and post) with L-carnitine improved the biochemical, histopathological, and immunohistochemical alterations in the heart treated with amethopterin.