Effect of addition diatomite powder on mechanical strength,elevated temperature resistance and microstructural properties of industrial waste fly ash-based geopolymer

This study examines the use of fly ash, a thermal power plant waste, and the effect of diatomite, a fossil algae type, on waste-based geopolymers in the production of sustainable geopolymer binders. The effects of 1%, 2%, 3%, 4% and, 5% diatomite substitution on waste-based mortars were investigated. Mortars containing 10% and 12% Na⁺ by weight based on the binder material were cured at 75 °C for 48 h. The flexural and compressive strength, abrasion resistance, determination of ultrasonic pulse velocity, and resistance to high temperatures of geopolymer mortar samples were investigated. In addition, FESEM images, EDX and XRD analyses of geopolymer mortar samples were made, and their microstructures were examined. 2% diatomite substitution increased flexural and compressive strength. In parallel with this situation, it was concluded that the abrasion resistance and ultrasonic pulse velocity of the geopolymer mortar with 2% diatomite substituted increased. In addition, it has been shown in FESEM images that the microstructure has a denser morphology. All geopolymer mortars lost strength after the high temperatures of 300 °C, 600 °C and 900 °C. As a result, it was concluded that diatomite containing highly reactive silica can be used in geopolymer systems.

     

Modeling increased demand of energy for air conditioners and consequent CO2 emissions to minimize health risks due to climate change in India

Developing countries situated mostly in latitudes that are projected for the highest climate change impact in the twenty-first century will also have a predictable increase in demand on energy sources. India presents us with a unique opportunity to study this phenomenon in a large developing country. This study finds that climate adaptation policies of India should consider the significance of air conditioners (A/Cs) in mitigation of human vulnerability due to unpredictable weather events such as heat waves. However, the energy demand due to air conditioning usage alone will be in the range of an extra ～750,000 GWh to ～1,350,000 GWh with a 3.7 °C increase in surface temperatures under different population scenarios and increasing incomes by the year 2100. We project that residential A/C usage by 2100 will result in CO₂ emissions of 592 Tg to 1064 Tg. This is significant given that India's total contribution to global CO₂ emissions in 2009 was measured at 1670 Tg and country's residential and commercial electricity consumption in 2007 was estimated at 145,000 GWh.     

Factors affecting post-disaster location choices of businesses: an analysis of the 1999 earthquake

Despite global policies advocating risk reduction and community level recovery, post-disaster implementations usually focus on households, but fail to focus on businesses in spatial terms. Due to the lack of appropriate policy and tools, businesses often make their own location choices as part of their recovery strategy. In view of this, this study aims to establish the factors affecting the location choices of businesses challenged by disasters in the absence of any specific spatial strategies designed for them. In order to determine these factors, empirical research was conducted in Adapazari, Turkey on 232 firms selected as a result of a stratified random sampling procedure. According to the analysis of the results, the most notable impacts on business location choices after a disaster shock are associated with occupancy status, education level, and extent of damage. In line with these findings, the impacts of business location choices are discussed to highlight the role of businesses in spatial decisions.     

Polymer Supported Calix[4]Arene Derivatives for the Extraction of Metals and Dichromate Anions

Three newly synthesized polymer supported calix[4]arene ionophores (7–9) were synthesized, and their ion binding properties toward selected alkali (Li⁺, Na⁺, K⁺, Cs⁺) and transition metal (Hg²⁺, Ni²⁺, Cu²⁺, Co²⁺, Cd²⁺, and Pb²⁺) cations were investigated. It has been observed that these ionophores are not selective toward a particular metal cation but show better ion binding property as compared to monomeric calixarene derivatives (2 and 6). Ionophore 6 and its supported polymer were also employed in dichromate anion extraction experiments. The polymeric ionophore (9) was found an effective extractant for dichromate anion even at pH 7.     

Building community resilience: business preparedness lessons in the case of Adapazarı, Turkey

The lack of attention paid to businesses in disaster management systems from the standpoint of state policies hampers efforts to build community resilience. This paper examines, therefore, the extent of business preparedness for disasters. Empirical research was conducted in Adapazarı, Turkey, 13 years after the İzmit earthquake, which struck the northwest of the country on 17 August 1999, claiming the lives of some 17,000 people. For the study, 232 firms were selected to inquire about their preparedness before and after the event. It is hypothesised that business preparedness is influenced by the following set of variables: business size; business sector; business age; financial condition prior to the disaster; occupancy tenure; market range; education level; and previous disaster experience. In line with the findings of the research, a policy framework is constructed to rationalise the allocation of resources for building resilience at the aggregate level by facilitating business preparedness.