Production of hydrogen by steam gasification of dehydrochlorinated poly(vinyl chloride) or activated carbon in the presence of various alkali compounds

Steam gasification of dehydrochlorinated poly(vinyl chloride) (PVC) or activated carbon was carried out in the presence of various alkali compounds at 3.0 MPa and 560°C–660°C in a batch reactor or in a semi-batch reactor with a flow of nitrogen and steam. Hydrogen and sodium carbonate were the main products, and methane and carbon dioxide were the minor products. Yields of hydrogen were high in the presence of sodium hydroxide and potassium hydroxide. The acceleration effect of the alkali compounds on the gasification reaction was as follows: KOH > NaOH > Ca(OH)₂ > Na₂CO₃. The rate of gasification increased with increasing partial steam pressure and NaOH/C molar ratio. However, the rate became saturated at a molar ratio of NaOH/C greater than 2.0.     

Comparison of marginal abatement cost curves for 2020 and 2030: longer perspectives for effective global GHG emission reductions

This study focuses on analyses of greenhouse gas (GHG) emission reductions, from the perspective of interrelationships among time points and countries, in order to seek effective reductions. We assessed GHG emission reduction potentials and costs in 2020 and 2030 by country and sector, using a GHG emission reduction-assessment model of high resolution regarding region and technology, and of high consistency with intertemporal, interregional, and intersectoral relationships. Global GHG emission reduction potentials relative to baseline emissions in 2020 are 8.4, 14.7, and 18.9 GtCO₂eq. at costs below 20, 50, and 100 $/tCO₂eq., corresponding to +19, −2, and −7 %, respectively, relative to 2005. The emission reduction potential for 2030 is greater than that for 2020, mainly because many energy supply and energy-intensive technologies have long lifetimes and more of the current key facilities will be extant in 2020 than in 2030. The emission reduction potentials in 2030 are 12.6, 22.0, and 26.6 GtCO₂eq. at costs below 20, 50, and 100 $/tCO₂eq., corresponding to +19, −2, and −7 %, respectively, relative to 2005. The emission reduction potential for 2030 is greater than that for 2020, mainly because many energy supply and energy-intensive technologies have long lifetimes and more of the current key facilities will be extant in 2020 than in 2030. The emission reduction potentials in 2030 are 12.6, 22.0, and 26.6 GtCO₂eq. at costs below 20, 50, and 100 /tCO₂eq., corresponding to +33, +8, and −3 %, respectively, relative to 2005. Global emission reduction potentials at a cost below 50 $/tCO₂eq. for nuclear power and carbon capture and storage are 2.3 and 2.2 GtCO₂eq., respectively, relative to baseline emissions in 2030. Longer-term perspectives on GHG emission reductions toward 2030 will yield more cost-effective reduction scenarios for 2020 as well.     

Consistent assessments of pathways toward sustainable development and climate stabilization

Many of the numerous difficult issues facing the world today involve relationships entailing trade‐offs and synergies. This study quantitatively assesses some alternative scenarios using integrated assessment models, and provides several indicators relating to sustainable development and climate change, such as indicators of income (per capita GDP), poverty, water stress, food access, sustainable energy use, energy security, and ocean acidification, with high consistencies among the indicators within a scenario. According to the analyses, economic growth helps improve many of the indicators for sustainable development. On the other hand, climate change will induce some severe impacts such as ocean acidification under a non‐climate intervention scenario (baseline scenario). Deep emission reductions, such as to 2°C above the pre‐industrial level, could cause some sustainable development indicators to worsen. There are complex trade‐offs between climate change mitigation levels and several sustainable development indicators. A delicately balanced approach to economic growth will be necessary for sustainable development and responses to climate change.     

Shedding light on a neglected area: a new approach to knowledge creation

Awareness is needed of sustainability issues that are currently neglected but potentially important. A computer-based approach can highlight unconscious and neglected areas because it can structure vast amounts of knowledge. In this article, we propose a methodology to perceive unconscious areas of sustainability with the support of a computer-based approach, which creates a matrix, named the recognized-unrecognized matrix, which highlights both local and globally neglected problems. A case study is conducted to consider the potential contribution of the aviation industry to sustainability issues. We demonstrate that a citation network analysis is an effective methodology to chart the recognized-unrecognized matrix. We highlight issues of water use in the aviation industry by designing an innovative water and air circulation system, which significantly reduces water and fuel consumption on board airplane flights. We also suggest a new approach to integrating both explicit and tacit knowledge to enable knowledge creation.     

Greenhouse gas reduction potential by household waste prevention

Journal of Material Cycles and Waste Management - We used a life-cycle assessment (LCA) approach to estimate the greenhouse gas (GHG) reduction effects of preventing 50% of all avoidable household...