光催化降解有机磷农药废水的可行性

在ＴｉＯ２粉末的存在下，研究光催化降解有机磷农药废水的可行性。结果表明，ＣＯＤｃｒ６５０ｍｇ／Ｌ，有机磷１９．８ｍｇ／Ｌ的有机磷农药废水在３７５Ｗ中压汞灯照射４ｈ，ＣＯＤ去除率为９０％，有机磷将完全转化为无机磷。同时还研究了光催化剂ＴｉＯ２的用量，反应液初始ｐＨ值，空气流量，外加Ｆｅ３＋浓度等多种因素对光降解的影响；并利用太阳聚光做了室外实验     

Two-step harmless treatment of secondary aluminum dross (SAD) by vacuum distillation and alkaline roasting

Journal of Material Cycles and Waste Management - Secondary aluminum dross (SAD) is classified as hazardous waste by many countries in the world because it contains a large number of toxic and...     

Boron sorption from aqueous solution by hydrotalcite and its preliminary application in geothermal water deboronation

Hydrotalcite and its calcination product were used to treat pure water spiked with various concentrations of boron and geothermal water containing boron as a major undesirable element. The kinetics process of boron sorption by uncalcined hydrotalcite is controlled by the diffusion of boron from bulk solution to sorbent-solution boundary film and its exchange with interlayer chloride of hydrotalcite, whereas the removal rate of boron by calcined hydrotalcite rests with the restoration process of its layered structure. The results of isotherm sorption experiments reveal that calcined hydrotalcite generally has much stronger ability to lower solution boron concentration than uncalcined hydrotalcite. The combination of adsorption of boron on the residue of MgO–Al₂O₃ solid solution and intercalation of boron into the reconstructed hydrotalcite structure due to “structural memory effect” is the basic mechanism based on which the greater boron removal by calcined hydrotalcite was achieved. As 15 geothermal water samples were used to test the deboronation ability of calcined hydrotalcite at 65 °C, much lower boron removal efficiencies were observed. The competitive sorption of the other anions in geothermal water, such as HCO₃ ^?, SO₄ ^2?, and F^?, is the reason why calcined hydrotalcite could not remove boron from geothermal water as effectively as from pure boron solution. However, boron removal percents ranging from 89.3 to 99.0 % could be obtained if 50 times of sorbent were added to the geothermal water samples. Calcined hydrotalcite is a good candidate for deboronation of geothermal water.     

DEM格网尺度对AnnAGNPS预测山地小流域径流和物质输出的影响

为了解流域地形空间参数和其它参数的精度对农业非点源污染模型AnnAGNPS预测准确性的影响,利用三峡库区黑河小流域观测资料校准了AnnAGNPS模型,分析了1.5-12.5m格网尺度DEM对地形参数和模型负载输出的影响.结果表明,1.5～12.5m格网尺度DEM对流域径流量、洪峰流量、总N输出影响不显著,但对泥沙、总P、有机碳输出影响显著.三峡库区类似小流域宜采用5m格网尺度DEM,AnnAGNPS模型较不适合于尺度较小、坡度较大的小流域泥沙负载预测.     

Reductions in non-point source pollution through different management practices for an agricultural watershed in the Three Gorges Reservoir Area

Non-point source water pollution generated by agricultural production is considered a major environmental issue in the Three Gorges Reservoir Area(TGRA) of China.The Annualised Agricultural Non-Point Source Pollution(AnnAGNPS) model was selected to assess the impact of the application of various management treats,including seven crops,five fertilizer levels and three-group management practice scenarios,on water quality from Heigou River Watershed in TGRA.The scenario subsets include conservation tillage practice(CTP),conservation reserve program(CRP) and conversion of cropland into forestland program(CCFP).Results indicated that tea can not be replaced by other crops because comparatively tea resulted in a higher sediment yield.CTP with no-tillage was more effective to reduce sediment yield,but could increased nutrient loss.CRP reduced sediment yield significantly,but slightly benefited on nutrient loss.CCFP reduced not only sediment yield but also the nutrient loss significantly.The conversion of cropland with a slope greater than 10 ° into forestland was found to be the best scenario as the sediment yield export is less than 5 tons/ha and nutrient loss is within the permissible limit.     

玻璃载体TiO2薄层光催化降解久效磷农药

研究了利用TiO₂薄层光催化降解久效磷农药的可行性。结果表明,0.65×10-4mol/L的久效磷经375W中压汞灯照射60min,被完全光催化降解至PO₄3-;加入微量的Fe3++或H2O2可提高久效磷农药的光解率;另外还研究了TiO₂薄层的附着量、反应液初始pH值、空气流量等因素对光催化降解的影响。光照80 h,TiO₂的光催化活性没有减弱,可连续使用。      

城市湿地生态系统保护的现状与思考

湿地是人类生态系统的重要组成部分,而城市湿地更是生态系统保护不可或缺的一环,本文通过对湿地的功能、生态学意义,以及城市湿地生态系统保护的现状的阐述,对城市湿地生态系统保护的有效措施———城市湿地公园的建设原则和生态保护对策进行了初步探讨。     

Reductions in non-point source pollution through di erent management practices for an agricultural watershed in the Three Gorges Reservoir Area

Non-point source water pollution generated by agricultural production is considered a major environmental issue in the Three Gorges Reservoir Area(TGRA) of China.The Annualised Agricultural Non-Point Source Pollution(AnnAGNPS) model was selected to assess the impact of the application of various management treats,including seven crops,five fertilizer levels and three-group management practice scenarios,on water quality from Heigou River Watershed in TGRA.The scenario subsets include conservation tillage pra...     

陕西苹果果区冰雹灾害分布特征及风险区划

选取陕西省1961-2010年气象观测站冰雹观测数据,分析38个苹果基地县冰雹的时空分布特征,结合基础地理信息数据、社会经济统计数据和历史灾情等方面资料,基于自然灾害风险形成原理,从致灾因子危险性、承灾体易损性以及防灾减灾能力3个方面,构建陕西苹果冰雹灾害风险评估模型,利用GIS技术完成陕西苹果果区冰雹灾害风险区划。结果表明:1陕西苹果果区冰雹北多南少,高原和高山多于平川、盆地;延安、渭北西部果区多于渭北东部、关中西部果区;1970-1980年代是冰雹高发期且波动较大,1990年以后有所减少;降雹随季节变化明显,夏季冰雹日数最多,春秋次之;冰雹日变化呈单峰型,14∶00-19∶00是陕西苹果果区降雹的高峰时段,出现频次为78.7%。2陕西苹果果区冰雹灾害重度风险区主要分布在延安中西部,该区年平均雹日约2 d;中度风险区主要包括韩城、合阳、澄城、蒲城、富平北部、耀州区、淳化、彬县、长武大部及其北部所有非重度风险区,该区年平均雹日1~2 d;轻度风险区主要分布在关中西北部及东部部分地区,该区年平均雹日不足1 d。     

洪山泉流量对气候变化和人类活动的响应

利用回归分析理论通过建立洪山泉流量的混合回归模型,揭示了洪山泉当年流量与自身前一年流量、前四年的降水量以及当年岩溶水开采量的相关性;通过分析加权平均降雨量与泉流量的关系,进一步揭示了1980年后岩溶水开采等人类活动对洪山泉流量衰减的影响,最终得出洪山泉流量对气候变化和人类活动的响应机制,并在此基础上进行了洪山泉流量预测。该研究可为合理开发洪山泉提供依据,对保护洪山泉岩溶水资源、恢复泉流量具有重要意义。