Elemental and isotopic determination of lead (Pb) in particulate matter in the Brazilian city of Goiânia (GO) using ICP-MS technique

Environmental Science and Pollution Research - The toxic metal lead (Pb) can be harmful to human health in various manners, but is also considered as a distinguished tracer of environmental...     

BENEFITS OF ITERATIVE WATER SUPPLY FORECASTING IN THE WASHINGTON,D.C., METROPOLITAN AREA1

The three largest water utilities in the Washington, D.C., metropolitan area (WMA) rely on the Potomac River and its reservoirs for water supply. These utilities have committed to a periodic review of the system's adequacy to meet future demands. In 1990, 1995, 2000, and again in 2004 (for publication in 2005) the utilities requested that the Interstate Commission on the Potomac River Basin (ICPRB) conduct a 20‐year water demand and resource adequacy study to fulfill this need. The selection of the five‐year interval provides multiple benefits. It allows regular updates and incorporation of recent demographic forecasts, and it increases visibility and understanding of the adequacy of the region's water resources. It also provides adequate time to conduct research on the physical system and to incorporate modifications based on this research into subsequent studies. The studies and lessons learned are presented in this case study of the WMA. The work has been a natural outgrowth of a long history of cooperative water supply planning and management among the main WMA water utilities and ICPRB.     

Evaluation of diffusive gradients in thin films technique (DGT) for measuring Al, Cd, Co, Cu, Mn, Ni, and Zn in Amazonian rivers

Studies concerning the lability and bioavailability of trace metals have played a prominent role in the search for contamination of water resources. This work describes the first application yet of the diffusive gradients in thin films technique (DGT) to the determination of the fraction of free plus labile metals in waters from the Amazon Basin. Due to the complexity of the use of DGT for samples with low ionic strength and high organic matter content (characteristic of Amazonian rivers), a new analytical procedure was developed. The method is based on the determinations of apparent diffusion coefficients (D_ap) in the laboratory, by performing deployments in samples collected in the corresponding sites of study. The D_ap thereby determined is then used for in situ measurements. The suitability of the proposed approach for determination of labile Al, Cd, Co, Cu, Mn, Ni, and Zn in the Amazon River and Rio Negro (English: Black River) was evaluated. Except for Co, Mn (in a deployment at Rio Negro), Ni and Zn (in a deployment at Amazon River), labile in situ measurements were lower or similar to dissolved concentrations, indicating suitability of the proposed approach.     

用大型底栖动物和ODP系统评价珠江的有机污染

采用大型底栖动物需氧有机体百分率ODP(oxygen demander percentage)法对广州珠江前航道、西航道和流溪河的下游段进行河流有机污染评价.结果显示:底栖动物需氧类群密度在三河段间分布确有显著性差异,并根据其ODP可以判断流溪河水质相对较好,水质级别为中国地表水环境质量标准(EQSSW)Ⅳ级,西航道和前航道水质级别都为Ⅴ级.通过测试,这一方法能成功地应用在珠江及流溪河,且该法可以较好地匹配于EQSSW五级评价系统,初步认为ODP系统可以成为一个较好的河流水质生物监测方法.图3表4参13     

Implications of 'low maternal serum alpha-fetoprotein levels: Are maternal age risk criteria obsolete?

An association has been reported between “low” maternal serum alpha-fetoprotein (MSAFP) and fetal chromosome abnormalities, notably Down syndrome. We suggest the predictive value be used for genetic counselling when a “low” MSAFP is found, and present an illustrative risk table. It can also be seen that normal MSAFP in a woman may lower her age-related risks below that previously defined as “high risk”. However, until good estimates of sensitivity and specificity are available from prospective, population based studies, patients should be told that any risk estimates are rough approximations. When good estimates are available, use of age risks alone may become obsolete.     

Short-term temporal variation in PM2.5 mass and chemical composition during the Atlanta Supersite Experiment, 1999

Measurements in urban Atlanta of transient aerosol events in which PM2.5 mass concentrations rapidly rise and fall over a period of 3-6 hr are reported. The data are based on new measurement techniques demonstrated at the U.S. Environmental Protection Agency (EPA) Atlanta Supersite Experiment in August 1999. These independent instruments for aerosol chemical speciation of NO3-, SO4(2-), NH4+, and organic and elemental carbon (OC and EC), reconstructed the observed hourly dry PM2.5 mass to within 20% or better. Data from the experiment indicated that transient PM2.5 events were ubiquitous in Atlanta and were typically characterized by a sudden increase of EC (soot) and OC in the early morning or SO4(2-) in the late afternoon. The frequent temporal decoupling of these events provides insights into their origins, suggesting mobile sources in metro Atlanta as the main contributor to early morning PM2.5 and more regionally located point SO2 sources for afternoon PM2.5 events. The transient events may also have health implications. New data suggest that short-term PM2.5 exposures may lead to adverse health effects. Standard integrated filter-based techniques used in PM2.5 compliance monitoring networks and in most past PM2.5 epidemiologic studies collect samples over 24-hr periods and thus are unable to capture these transient events. Moreover, health-effects studies that focus on daily PM2.5 mass alone cannot evaluate the health implications of the unique and variable chemical properties of these episodes.     

大气细粒子的快速捕集及化学成分在线分析方法研究

本文介绍了一种新型的大气细粒子快速捕集及其化学成分在线分析方法。该方法中大气细粒子与过饱和水蒸气绝热混和而增长成大粒子 ,并在气流的带动下惯性撞击到一垂直玻璃板上 ,一含有内标物的去离子水流自上而下将撞击到玻璃板上的粒子收集 ,收集液被直接输送到离子色谱、总有机碳分析仪 ,在线分析其中的化学成分。该方法每 12min可完成单个样品分析 ,每小时可连续采集分析 5个样品。离子色谱最低检测限约为 0 .0 5 μg/m3(NH+4 )到 0 .2 0 μg/m3(SO2 -4 ) ,不确定度约为 3 % ,TOC最低检测限为 5× 10 -5μg/m3,不确定度约为 3 %。真实的大气细粒子观测结果表明 ,该方法快速、简捷、灵敏度高 ,是实时监测大气中细粒子化学成分的有效工具     

Introduction to the Featured Collection on “Nonstationarity,Hydrologic Frequency Analysis,and Water Management”1

Kiang, Julie E., J. Rolf Olsen, and Reagan M. Waskom, 2011. Introduction to the Featured Collection on “Nonstationarity, Hydrologic Frequency Analysis, and Water Management.”Journal of the American Water Resources Association (JAWRA) 47(3):433‐435. DOI: 10.1111/j.1752‐1688.2011.00551.x     

Distributions and determinants of mercury concentrations in toenails among American young adults: the CARDIA Trace Element Study

Since data on mercury (Hg) levels in Caucasians and African Americans (AAs) of both genders are lacking, this study aims to present toenail Hg distributions and explore the potential determinants using data from the Coronary Artery Risk Development in Young Adults Trace Element Study. Data from 4,344 Americans, aged 20–32 in 1987, recruited from Oakland, Chicago, Minneapolis, and Birmingham were used to measure toenail Hg levels by instrumental neutron-activation method. The Hg distribution was described with selected percentiles and geometric means. Multivariable linear regression (MLR) was used to examine potential determinants of Hg levels within ethnicity–gender subgroups. The geometric mean of toenail Hg was 0.212 (95 % CI?=?0.207–0.218)?μg/g. Hg levels varied geographically with Oakland the highest [0.381 (0.367–0.395) μg/g] and Minneapolis the lowest [0.140 (0.134–0.147) μg/g]. MLR analyses showed that male gender and AA ethnicity were negatively associated with toenail Hg levels, and that age, living in Oakland city, education level, alcohol consumption, and total fish intake were positively associated with toenail Hg concentrations within each ethnicity–gender subgroup. Current smokers were found to have higher Hg only in AA men. This study suggested age, gender, ethnicity, study center, alcohol, education level, and fish consumption consistently predict toenail Hg levels. As fish consumption was the key determinant, avoiding certain types of fish that have relatively high Hg levels may be crucial in reducing Hg intake.