全文获取类型
收费全文 | 73篇 |
免费 | 1篇 |
国内免费 | 6篇 |
专业分类
安全科学 | 2篇 |
废物处理 | 15篇 |
环保管理 | 2篇 |
综合类 | 14篇 |
基础理论 | 16篇 |
污染及防治 | 20篇 |
评价与监测 | 6篇 |
社会与环境 | 5篇 |
出版年
2022年 | 3篇 |
2018年 | 3篇 |
2017年 | 1篇 |
2016年 | 3篇 |
2014年 | 1篇 |
2013年 | 3篇 |
2012年 | 3篇 |
2011年 | 8篇 |
2010年 | 3篇 |
2009年 | 1篇 |
2008年 | 7篇 |
2007年 | 9篇 |
2006年 | 6篇 |
2005年 | 2篇 |
2004年 | 8篇 |
2003年 | 2篇 |
2002年 | 2篇 |
2001年 | 3篇 |
2000年 | 2篇 |
1998年 | 1篇 |
1995年 | 1篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1980年 | 1篇 |
1975年 | 1篇 |
1965年 | 1篇 |
排序方式: 共有80条查询结果,搜索用时 125 毫秒
1.
Mao Meizhou Liu Zihui Dong Huiru Liu Jingyi Kathe K. Bertines Minoru Koide Edward D. Goldberg 《环境科学学报(英文版)》1991,3(1):109-116
The fluxes of heavy metals and magnetite, a fly-ash component, from coal burning, to sediments of the Kunming Lake in Beijing have increased measurably over the last fifty years. Ages were introduced to the sediment strata through Pb-210 geochronologies. Even with a doubling of coal usage by the year 2000, the anthropogenic metal fluxes will still be less than those recorded in metropolitan Tokyo and U.S. lakes. 相似文献
2.
Ishii N Sakashita T Takeda H Kubota Y Fuma S Doi M Takahashi S 《Journal of environmental radioactivity》2007,97(2-3):159-167
Extracellular DNA is omnipresent in aquatic environments and is thought to be a genetic material for horizontal gene transformation between microorganisms. We studied the impact of gamma irradiation on the transformation efficiency (transformants number per ng of DNA per ml) of extracellular DNA. Plasmid pEGFP as a model extracellular DNA was irradiated by gamma rays. The transformation efficiency decreased with the increase in radiation dose. A total dose of 10Gy is normally not lethal for microorganisms but certainly affects the transformation efficiency of extracellular DNA. The decrease in the efficiency would be induced by strand breaks of extracellular DNA because the yield of both single-strand breaks (SSBs) and double-strand breaks (DSBs) increased with the increase in radiation dose. The relative transformation efficiency of SSBs and DSBs to that of covalently closed circles (CCCs) was 30.3% and 0.2%, respectively. This impact on natural transformation suggests an inability of microorganisms to acquire new characteristics which should be normally acquired. 相似文献
3.
To apply PET depolymerization in supercritical methanol to commercial recycling, the benefits of supercritical methanol usage in PET depolymerization was investigated from the viewpoint of the reaction rate and energy demands. PET was depolymerized in a batch reactor at 573 K in supercritical methanol under 14.7 MPa and in vapor methanol under 0.98 MPa in our previous work. The main products of both reactions were the PET monomers of dimethyl terephthalate (DMT) and ethylene glycol (EG). The rate of PET depolymerization in supercritical methanol was faster than that of PET depolymerization in vapor methanol. This indicates supercritical fluid is beneficial in reducing reaction time without the use of a catalyst. We depicted the simple process flow of PET depolymerization in supercritical methanol and in vapor methanol, and by simulation evaluated the total heat demand of each process. In this simulation, bis-hydroxyethyl terephthalate (BHET) was used as a model component of PET. The total heat demand of PET depolymerization in supercritical methanol was 2.35 x 10(6)kJ/kmol Produced-DMT. That of PET depolymerization in vapor methanol was 2.84 x 10(6)kJ/kmol Produced-DMT. The smaller total heat demand of PET depolymerization in supercritical methanol clearly reveals the advantage of using supercritical fluid in terms of energy savings. 相似文献
4.
Kensuke Miyazaki Noriyasu Okazaki Minoru Terano Hisayuki Nakatani 《Journal of Polymers and the Environment》2008,16(4):267-275
In this work, an oxidatively degraded polypropylene (DgPP) was studied as a novel coupling agent for fibrous cellulose (FC)/polypropylene
(PP) composite. An optimal preparation time of PP thermal oxidative degradation was 18 h at 130 °C, and the DgPP had functional
groups such as γ-lactone and acid groups. The spherulite observation of the DgPP suggested miscibility for the undegraded
PP. The addition of the DgPP presented the transparency improvement of FC/PP composite, and this behavior was found to be
originated from the grafted DgPP, which was produced by the esterification reaction between the of FC and the DgPP. The scanning
electron microscope (SEM) observation showed that the grafted DgPP coated the FC surface, and the tensile strength of the
FC/PP composite increased by an appropriate amount of the DgPP addition. These results suggested that the DgPP was suitable
for the coupling agent of FC/PP composite. 相似文献
5.
Katsuya Nakayama Kuchar Dalibor Keisuke Sakai Mitsuhiro Kubota Hitoki Matsuda 《Journal of Material Cycles and Waste Management》2008,10(2):102-109
The present work focuses on investigation of the effective recovery of heavy metals from molten fly ash by applying chloride-induced
volatilization. In particular, the effect of unburned carbon on the chloride-induced volatilization of lead, zinc, and copper
from model and real molten fly ashes was investigated in the temperature range 873–1173 K under a N2 atmosphere. As a result, almost 100% of lead and a significant proportion of zinc were volatilized from the real molten fly
ash samples at 1173 K. In contrast, for the model fly ash, volatilization ratios of lead and zinc at 1173 K were only 85%
and 25%, respectively. Further, the results of X-ray diffraction analysis suggested that PbO in molten fly ash was converted
either to Pb2OCl2 or Pb by respective chlorination and reduction reactions. Meanwhile ZnO and CuO in the molten fly ash were reduced to Zn
and Cu by reaction with unburned carbon. Subsequently, Pb, Zn, and Pb2OCl2 were volatilized, but Cu remained in the solid residue. Finally, the volatilization ratio of zinc increased with the addition
of carbon, and more than 98% of zinc was volatilized at 1173 K from a fly ash with a carbon content of 20%. 相似文献
6.
7.
Nguyen Thi Thuong Minoru Yoneda Maiko Ikegami Masato Takakura 《Environmental monitoring and assessment》2013,185(10):8065-8075
The concentrations of Mn, Fe, Ni, Cr, Cu, Pb, Zn, As, and Cd were determined to evaluate the level of contamination of To Lich River in Hanoi City. All metal concentrations in 0–10-cm water samples, except Mn, were lower than the maximum permitted concentration for irrigation water standard. Meanwhile, concentrations of As, Cd, and Zn in 0–30-cm sediments were likely to have adverse effects on agriculture and aquatic life. Sediment pollution assessment was undertaken using enrichment factor and geoaccumulation index (I geo). The I geo results indicated that the sediment was not polluted with Cr, Mn, Fe, and Ni, and the pollution level increased in the order of Cu < Pb < Zn < As < Cd. Meanwhile, significant enrichment was shown for Cd, As, Zn, and Pb. Cluster and principal component analyses suggest that As and Mn in sediment were derived from both lithogenic and anthropogenic sources, while Cu, Pb, Zn, Cr, Cd, and Ni originated from anthropogenic sources such as vehicular fumes for Pb and metallic discharge from industrial sources and fertilizer application for other metals. 相似文献
8.
Matsunaga SN Chatani S Nakatsuka S Kusumoto D Kubota K Utsumi Y Enoki T Tani A Hiura T 《Chemosphere》2012,87(8):886-893
Reactive volatile organic compounds (VOCs) are known to affect atmospheric chemistry. Biogenic VOCs (BVOCs) have a significant impact on regional air quality due to their large emission rates and high reactivities. Diterpenes (most particularly, kaur-16-ene) were detected in all of the 205 enclosure air samples collected over multiple seasons at two different sites from Cryptomeria japonica and Chamaecyparis obtusa trees, the dominant coniferous trees in Japan,. The emission rate of kaur-16-ene, was determined to be from 0.01 to 7.1 μg dwg−1 h−1 (average: 0.61 μg dwg−1 h−1) employing branch enclosure measurements using adsorbent sampling followed by solid phase-liquid extraction techniques. The emission rate was comparable to that of monoterpenes, which is known major BVOC emissions, collected from the same branches. In addition, total emission of kaur-16-ene at 30 °C was estimated to exceed that of total anthropogenic VOC emissions. 相似文献
9.
Md. Abul Kashem Bal Ram Singh Hiroshi Kubota Reiko Sugawara Nobuyuki Kitajima Toshihito Kondo Shigenao Kawai 《Environmental science and pollution research international》2010,17(5):1174-1176
Background, aim, and scope
Zinc is an essential micronutrient element but its concentrations found in contaminated soils frequently exceed those required by the plant and soil organisms, and thus create danger to animal and human health. Phytoremediation is a technique, often employed in remediation of contaminated soils, which aims to remove heavy metals or other contaminants from soils or waters using plants. Arabidopsis (A.) halleri ssp. gemmifera is a plant recently found to be grown vigorously in heavy metal contaminated areas of Japan and it contained remarkably high amount of heavy metals in its shoots. However, the magnitude of Zn accumulation and tolerance in A. halleri ssp. gemmifera need to be investigated for its use as a phytoremediation plant. 相似文献10.
Shinsuke Iijima Morito Nakamura Akira Yokoi Mitsuhiro Kubota Liwei Huang Hitoki Matsuda 《Journal of Material Cycles and Waste Management》2011,13(3):206-212
For an effective decomposition and removal of organic halogenated compounds, a packed-bed non-thermal plasma reactor with
in situ absorption of the resulting halogenated products by alkaline sorbent incorporated was proposed. In the plasma reactor,
α-Al2O3 particles of 1 and 3 mm (mean particle diameter) were packed as solid dielectric medium to enhance the plasma power density
in the reactor. Further, alkaline sorbent of Ca(OH)2 was doped onto the surface of α-Al2O3 particles, in order to remove halogenated products by in situ absorption with Ca(OH)2. A high-voltage and high-frequency pulsed power of −15 to 15 kV and 1 kHz was applied to the wire electrode of the plasma
reactor by means of a DC power source. In the present study, as the sample of an organic halogenated compound that is most
popularly used, we selected dichloromethane (CH2Cl2), and 500 ppm of the initial concentration of CH2Cl2 was fed into the reactor accompanied by air at a fixed flow rate of 500 × 10−6 m3 min−1 at room temperature. As a result, it was recognized that the amount of CH2Cl2 decomposed by non-thermal plasma in an α-Al2O3 particle bed increased with an increase in plasma input power. The ratio of decomposition of CH2Cl2 was almost 100% at 13 kV of electric power and 1 kHz frequency, and CO2, CH3Cl, COCl2, HCl, and Cl2 were observed as the major reaction products. On the other hand, when CH2Cl2 was introduced into the plasma reactor where α-Al2O3 particles doped with Ca(OH)2 were packed, the ratio of decomposition of CH2Cl2 became higher, compared to the case that α-Al2O3 particles were not doped with Ca(OH)2. Moreover, there were no halogenated by-product gases detected in the outlet gas from the reactor. As the solid reaction
products, CaClOH and Ca(ClO)2·4H2O were detected on Ca(OH)2 by X-ray diffraction. From these findings, it was recognized that CH2Cl2 was decomposed more effectively without producing unwanted harmful halogenated by-products in the proposed non-thermal plasma
reactor where α-Al2O3 particles doped with Ca(OH)2 sorbent were packed. 相似文献