Understanding the fate and transport of petroleum hydrocarbons from coal tar within gasholders

Coal tars have been identified as posing a threat to human health due to their toxic, mutagenic and carcinogenic characteristics. Workers involved in former gasholders decommissioning are potentially exposed to relevant concentrations of volatile and semi-volatile hydrocarbons upon opening up derelict tanks and during tar excavation/removal. While information on contaminated sites air-quality and its implications on medium-long term exposure is available, acute exposure issues associated with the execution of critical tasks are less understood. Calculations indicated that the concentration of a given contaminant in the gasholder vapour phase only depends on the coal tar composition, being only barely affected by the presence of water in the gasholder and the tar volume/void space ratio. Fugacity modelling suggested that risk-critical compounds such as benzene, naphthalene and other monocyclic and polycyclic aromatic hydrocarbons may gather in the gasholder air phase at significant concentrations. Gasholder emissions were measured on-site and compared with the workplace exposure limits (WELs) currently in use in UK. While levels for most of the toxic compounds were far lower than WELs, benzene air-concentrations where found to be above the accepted threshold. In addition due to the long exposure periods involved in gasholder decommissioning and the significant contribution given by naphthalene to the total coal tar vapour concentration, the adoption of a WEL for naphthalene may need to be considered to support operators in preventing human health risk at the workplace. The Level I fugacity approach used in this study demonstrated its suitability for applications to sealed environments such as gasholders and its further refining could provide a useful tool for land remediation risk assessors.     

Book reviews

PIONEERS IN BRITISH PLANNING

Gordon Cherry (Ed.)

The Architectural Press, London, 1981. 232 pp with index and illustrations.

Price £8.95 paperback.

PLANNING PROCEDURES

John Stephenson

Northwood Books, 1982

Price £9.95 hardback, 192 pages

INDUSTRIAL LOCATION POLICY FOR ECONOMIC REVITALISATION

Morris L. Sweet

Praeger, 1981

THE POLITICS OF TOWN PLANNING

Gordon Cherry

Longmans, 1982. 165 pp.

THE POLITICS OF LOCAL GOVERNMENT IN THE UNITED KINGDOM

Alan Alexander

Longman, 1982, 143 pp. Price £3.95 paperback

LAND USE AND LIVING SPACE

Robin Best

Methuen U.P., 1981

URBAN PROJECTS MANUAL

A guide to preparing upgrading and new development projects accessable to low income groups.

Forbes Davidson and Geoff Payne (Eds)

University Press 1983 Price £7.50

LONDON'S GREEN BELT: CONTAINMENT IN PRACTICE

Richard Munton

George Allen & Unwin, 1983

OUTDOOR RECREATION AND RESOURCE MANAGEMENT

John Pigram

Croom Helm, 1983

THE IDEAL CITY — ITS ARCHITECTURAL EVOLUTION IN EUROPE

Rosenau, H.

Methuen & Co. Ltd., London & New York. Third Edition 1983. 195 pages illustrated. Hardback.

ENVIRONMENTAL HAZARDS IN THE BRITISH ISLES

A. H. Perry

George Allen and Unwin, 1981

RECREATION AND RESOURCES: LEISURE PATTERNS AND LEISURE PLACES

J. Allan Patmore

Blackwell, 1983     

Reviews

REGIONAL PLANNING: A COMPREHENSIVE VIEW

JEREMY ALDEN and ROBERT MORGAN

Leonard Hill Books, Intertext, London, 1974. £6.

MAN‐MADE FUTURES: READINGS IN SOCIETY, TECHNOLOGY AND DESIGN

NIGEL CROSS, DAVID ELLIOTT and ROBIN ROY (EDS.)

Hutchinson Educational in association with Open University Press, London, 1974. 365 pp., cased £5, paperback £2.75.

CITY OF BIRMINGHAM STRUCTURE PLAN: WRITTEN STATEMENT

NEVILLE BORG (City Engineer)

City of Birmingham, 1973.

DESIGNING FOR HUMAN BEHAVIOUR: ARCHITECTURE AND THE BEHAVIOURAL SCIENCES

(Community Development Series. Series Editor, Richard P. Dober.)

JON LANG, CHARLES BURNETTE, WALTER MOLESKI and DAVID VACHON (EDS.)

Dowden, Hutchinson & Ross, Inc., Stroudsburg, Pa., 1974. 352 pp., S20 (U.K. price not stated).

THE BOOK OF GARDEN ORNAMENT

PETER HUNT (ED.)

J. M. Dent & Co., London, 1974. £9.75.

AMENITY AND URBAN PLANNING

DAVID L. SMITH

Crosby Lockwood Staples, London, 1974. 198 pp. £4.50.     

Visual impact assessment: A neglected component of environmental impact statements in Ireland?

This paper documents the results of an analysis of Visual Impact Assessments (VIA) within a sample of Environmental Impact Statements (EIS) in Ireland. The standard of VIA conducted within the environmental impact assessment (EIA) process for three categories of development; piggeries, quarries and urban developments between 1997 and 1999 are evaluated. The extent to which VIA have complied with the Irish Environmental Protection Agency (EPA) guidelines and disparities between the results for each development category are examined. The survey concluded that (i) the standard of VIA is less comprehensive than might be expected, and (ii) the use of visualization techniques for VIA could be substantially improved.