Contributions to ecological chemistry CXII balance of conversion of buturon‐14C in wheat under outdoor conditions 1

Abstract

The urea herbicide buturon (N‐[p‐chlorophenyl] ‐N’ ‐methyl‐N’ ‐isobutinyl‐urea), ¹⁴C‐labeled, was sprayed on winter wheat as an aqueous formulation (2.98 kg/ha) under outdoor conditions. Upon harvest (three months after application), a total of 49. 2% of the applied radiocarbon was recovered: 2.0% in the plants, 46.9% in the soil, and 0.3% in the leaching water (depth > 50 cm); less than 0.1% was in the grains (0.464 ppm). Only about half of the radioactivity present in plants could be recovered under mild extraction conditions; about half of this was unchanged buturon. In straw and husk extracts, the following metabolites were identified by gaschromatography/mass spectrometry: N‐(p‐chlorophenyl)‐N‐methyl‐O‐methyl‐carbamate (metabolite I), N‐phenyl‐N’ ‐formyl‐urea (metabolite II), two unstable metabolites giving (p‐chlorophenyl)‐isocyanate upon purification (metabolites III and IV), N‐(p‐chlorophenyl)‐N’ ‐methyl‐N’ ‐isobutenylol‐urea (metabolite V), p‐chloroformanilide (metabolite VI) and biologically bound p‐chloroaniline (metabolite VII). In the root and basal stem extract, the following metabolites were identified by gas chromatography/mass spectrometry: N‐(p‐chlorophenyl)‐O‐methyl‐carbamate (metabolite VIII) and N‐(p‐chlorophenyl)‐N’ ‐methyl‐urea (metabolite IX).     

Water quality in the Elbe estuary: Significance of different processes for the oxygen deficit at Hamburg

A simple zero‐dimensional model was developed which describes the oxygen concentrations and major nutrient processes in the tidal influenced Elbe estuary. The model was calibrated by way of comparison with continuous measurements of the oxygen‐ and chlorophyll concentrations at the non‐tidal part of the estuary. A special calibration method was applied which utilised the fact that natural steady‐state conditions are often found during which the range and the average value of the day–night fluctuations remain constant over a period of several days. Subsequent model runs were carried out to simulate the oxygen concentrations downstream, i.e., after a few days of transport time of the water body. The varying depth of the Elbe downstream of Hamburg harbour was taken into account by altering the model parameters ‘light penetration’ and ‘aeration’. The oxygen concentrations resulting from the model showed a distinct minimum, which agreed well with the minimum measured in longitudinal profiles, thus indicating that the occurrence of the oxygen minimum in the Elbe estuary can mainly be explained by the processes included in our simple model. Sensitivity checks identified some relationships, e.g., light intensity ? growth rate, which are critical for the oxygen balance. With this work it could be demonstrated that even simple zero‐dimensional models can improve our understanding of the complex interrelationship of different physical, chemical and biological processes in rivers and that such models can be used for simple scenarios in water quality management.     

Bioconcentration potential (BCP) of 2,3,7,8-Tetrachlorodibenzop-dioxin (2,3,7,8-TCDD) in terrestrial organisms including humans

The bioconcentration factors (BCFs) of 2,3,7,8-TCDD in adipose tissue of rats, beef cattle and monkeys have been calculated. The bioconcentration potential of TCDD in man was calculated by two indirect methods: 1) from daily intake of TCDD and its measured concentrations in adipose tissues and 2) from measured half-life and measured concentrations in body fat at steady state using a linear one compartment pharmacokinetic model. The BCFs in humans calculated by both methods are between 104 and 206, or 153, respectively.     

The booklet “Genetically modified crops”, published from the German Research Foundation, does not meet the given claim - Discussion article

In December 2009 the German Research Foundation published the booklet "Grüne Gentechnik" (Genetically modified crops) claiming to give a scientifically well balanced information about GMO's in agriculture. In this paper we analyse this approach resulting in a critical review regarding the intention of the booklet. We conclude that the evaluation of GMO's in agriculture primarily from a crop breeding perspective is lacking crucial positions in terms of ecology, socio-economy, agronomy, nutritional sciences and finally ethics in life science.     

Floods and Other Possible Adverse Environmental Effects of Meadowland Area Decline in Former West Germany

6   ha, or 6% of the country's total area. The environmental implications of this large-scale conversion have so far received little attention; the present study examined some of these implications. A review of research on soil physical and chemical aspects of the conversion of permanent grassland into arable land reveals that such a large-scale conversion may have considerable effects upon the environment. For example, due to the mineralization of soil organic matter a release of NO₃ and CO₂ into the environment can be expected on the order of 10 t N and 100 t C per hectare. Environmentally equally severe, if not worse, is the increased amount of surface runoff that can be expected from converted grassland soils in arable land during winter because of surface sealing and soil compaction. This increased surface runoff, in combination with the runoff from other farmland, may be one of the reasons for the growing frequency of floods along major German rivers in recent years. In view of the lasting adverse environmental effects of permanent grassland conversion and the subsidized agricultural surpluses in Germany today, we conclude that a reconversion of arable land into permanent grassland may be beneficial both environmentally and economically.     

Die Funktion des Arginins in den Enzymen

The Science of Nature - The average arginine content of proteins is 3.9%. Its frequency among the 20 amino acids of the proteins (13th position) is far lower than would be anticipated from the fact...     

The effects of organic environmental chemicals on the growth of the alga Scenedesmus subspicatus: A contribution to environmental biology

The effective concentrations of 15 chemicals, inhibiting the cell growth of the alga $\text{Scenedesmus subspicatus}$ by 10 % and 50 % during 96 hours, have been investigated in a static test under controlled laboratory conditions.