Ionic liquids as lubricants or lubrication additives: An ecotoxicity and biodegradability assessment

This paper reports on the (eco)toxicity and biodegradability of ionic liquids considered for application as lubricants or lubrication additives. Ammonium- and pyrrolidinium-based cations combined with methylsulphate, methylsulphonate and/or (CF₃SO₂)₂N⁻ anions were investigated in tests to determine their aquatic toxicity using water fleas Daphnia magna, green algae Selenastrum capricornutum and marine bacteria (Vibrio fischeri). Additional test systems with an isolated enzyme (acetylcholinesterase) and isolated leukaemia cells from rats (IPC-81) were used to assess the biological activity of the ionic liquids. These compounds generally exhibit low acute toxicity and biological activity. Their biodegradability was screened according to OECD test procedures 301 B and 301 F. For choline and methoxy-choline ionic liquids ready biodegradability was observed within 5 or 10 d, respectively. Some of the compounds selected have a considerable potential to contribute to the development of more sustainable products and processes.     

A fouling suppression system in submerged membrane bioreactors using dielectrophoretic forces

A novel method was developed to suppress membrane fouling in submerged membrane bioreactors. The method is based on the dielectrophoretic (DEP) motion of particles in an inhomogeneous electrical field. Using a real sample of biomass as feed, the fouling-suppression performance using DEP with different electrical field intensities (60–160 V) and different frequencies (50–1000 Hz) was investigated. The fouling-suppression performance was found to relate closely with the intensity and frequency of the electrical field. A stronger electrical field was found to better recover the filtrate flux. This is because of a stronger DEP force acting on the biomass particles close to the membrane's surface. Above an intensity and frequency value of 130 V and 1 kHz, respectively the permeate flux was reduced due to an electrothermal effect.     

Risk and resilience lessons from Venice

In the history of disasters in Venice, there are implications for modern times in terms of complex systems management and emerging threats, in particular from examples of risk management and resilience achieved by the Venetian state during outbreaks of the plague. In fourteenth century Venice, risk assessment the way we practice it today would fail to provide meaningful recommendations to reduce the casualty rate of the plague epidemic because the cause and transmission of the disease was not understood. Instead, a set of systemic actions across the social, economic, and transportation networks of the city taken by officials and doctors eventually slowed and arguably stopped the spread of the disease. These latter actions are an early example of what is now considered resilience management. Resilience management improves a complex system’s ability to prepare, absorb, recover, and adapt to unexpected threats and does so by address the capabilities at a system, rather than component, level. Resilience management can be a guide to addressing current issues of population growth and rising sea level in modern day Venice and across the globe. This paper calls for integration of resilience assessment in comprehensive risk and resilience management framework.     

Diapycnal Mixing in the Thermocline of Lakes: Estimations by Different Methods

In order to evaluate the performance of different methods for estimation of the vertical eddy diffusivity in thermally stratified lakes, two field studies were conducted in Lake Biwa, Japan and Lake Kinneret, Israel. Lake Biwa experienced three typhoons during the campaign while Lake Kinneret experienced high winds in the afternoons. Microstructure profiles were collected by a portable flux profiler (PFP) during calm and disturbed periods. Then, the vertical eddy diffusivity was estimated by three indirect methods. The estimated vertical eddy diffusivities varied more than one order of magnitude, from 4.7× 10⁻⁷ to 7.7× 10⁻⁶ m² s⁻¹. The comparison of results with previous buoyancy flux measurements and scaling arguments showed that the Dillon–Park’s method is not appropriate and Osborn–Cox method performs better than Osborn method in the studied case. Furthermore, the low value of vertical eddy diffusivity within the thermocline suggests that within the thermocline of these lakes, diffusive vertical transport can be neglected.     

Biodegradation potential of cyano-based ionic liquid anions in a culture of Cupriavidus spp. and their in vitro enzymatic hydrolysis by nitrile hydratase

Biodegradation tests with bacteria from activated sludge revealed the probable persistence of cyano-based ionic liquid anions when these leave waste water treatment plants. A possible biological treatment using bacteria capable of biodegrading similar compounds, namely cyanide and cyano-complexes, was therefore examined. With these bacteria from the genera Cupriavidus, the ionic liquid anions B(CN)₄ ^?, C(CN)₃ ^?, N(CN)₂ ^? combined with alkaline cations were tested in different growth media using ion chromatography for the examination of their primary biodegradability. However, no enhanced biodegradability of the tested cyano-based ionic liquids was observed. Therefore, an in vitro enzymatic hydrolysis test was additionally run showing that all tested ionic liquid (IL) anions can be hydrolysed to their corresponding amides by nitrile hydratase, but not by nitrilase under the experimental conditions. The biological stability of the cyano-based anions is an advantage in technological application, but the occurrence of enzymes that are able to hydrolyse the parent compound gives a new perspective on future cyano-based IL anion treatment.     

ECO-design of reuse and recycling networks by multi-objective optimization

An ECO-optimized reuse of process liquors addresses the financial gain and the effective use of resources. In processes that have a potential for process liquor recovery, the minimization of both economic and environmental burdens can be realised by an ECO-optimal design of reuse and recycling network (RRN).In this paper, a procedure for synthesizing such an RRN for a metal finishing process is investigated. The simultaneous analysis of environmental impact sensitivity (SAEIS) based on a superstructure approach, combined with multi-objective optimization is performed by mixed-integer nonlinear programming (MINLP). This allows an “eco–eco” trade-off i.e. total annualized cost and environmental impacts are minimized simultaneously. By varying the weighting factor, different RRN alternatives were generated. A replacement of the standard and closed-loop system by these solutions, even for the environmentally friendliest case, yielded a reasonable cost saving on raw material's inputs.     

欧洲铝工业部门可持续指标系统的开发

2001年欧洲铝工业委托乌珀塔尔研究所完成一个项目叫做"朝着可持续性发展的铝工业:利益相关者的期望值和核心指标".该项目的目的是检查可持续性议程和利益相关者的期望值.其后为了用来测定企业的可持续行为建立了一个指标框架.参与的利益相关者能够看到他们的投入正在被采用.本文介绍了开发这个部门的可持续性指标系统的论证经验,并陈述了主要的可持续发展主题.     

Hepatitis E Virus in Farmed Rabbits,Wild Rabbits and Petting Farm Rabbits in the Netherlands

Rabbits have been suggested as a zoonotic source of Hepatitis E virus. Phylogenetic analysis of HEV isolates from farmed, wild and pet rabbits in the Netherlands (23, 0, and 60 % respectively) showed them to be grouped amongst published rabbit HEV sequences and distinct from most human isolates. Dutch rabbits are unlikely to be a zoonotic source.