Preparation of black lyophilic ink using the carbon soot emitted by vehicles

Environmental Science and Pollution Research - The carbon soot is formed as a consequence of incomplete combustion of hydrocarbons and organic matter. It causes respiratory diseases like lung...     

Prenatal ultrasound diagnosis of Apert's syndrome

A mother affected with Apert's syndrome was diagnosed by ultrasound scan at 16–17 weeks to have a fetus similarly affected. The typical features of acrocephaly and symmetrical syndactyly were seen. This is probably the first time that this condition has been diagnosed at such a gestation by ultrasound scan. The patient decided to continue the pregnancy, and intrauterine death occurred at 34 weeks. The diagnosis was confirmed by pathological examination.     

Investigation of performance enhancement of solar still incorporated with Gallus gallus domesticus cascara as sensible heat storage material

In this research work, the conventional single slope still (CSS) with egg shells of breed Gallus gallus domesticus cascara as sensible heat storage (SHS) material are studied experimentally to enhance the yield. In this experimental investigation, the proposed single slope still (PSS) with SHS material was made in comparison with the CSS to evaluate the productivity of fresh water under the same ambient conditions. Comparatively, this PSS has higher thermal conductivity than the CSS. The yield obtained from the PSS is 2.46 L/m², while the yield from the CSS is 2.07 L/m². The average rate at which the rise of output fresh water obtained from the PSS is 18% more than the fresh water output obtained from the CSS. The daily energy efficiency of the PSS is 26.07%, and for the CSS, it is only 22.25%. The daily exergy efficiency of the PSS is 2.36%, and for the CSS, it is only 1.67%. Since using the egg shell will employ as organic waste management and modification in this still is economical, less initial, and maintenance cost.

     

Role of UPP pathway in amelioration of diabetes-associated complications

Environmental Science and Pollution Research - Type 2 diabetes (T2D) is one of the most widely spread metabolic disorder also called as “life style” disease. Due to the alarming number...     

Environmental forensic investigation of the air pollution from a cement manufacturing unit

Abstract

Cement manufacturing is a process that results in the emission of significant quantities of suspended particulate matter (SPM) to the ambient air. An environmental forensic investigation was carried out in the surroundings of a major cement manufacturing unit at a place called Coimbatore in the southern Indian state of Tamil Nadu. The investigation was carried out to identify the contribution of the cement manufacturing unit to the SPM concentration of the surrounding air environment. The sampling points’ selection and sample collection were done following the principles outlined in the INTERPOL Manual for Pollution Crime Forensic Investigation. On-site monitoring of the air samples was carried out using Mini Laser Aerosol Spectrometer (GRIMM, Mini-LAS Model 11R). The instrument was capable of measuring particles ranging from 0.25 to 32 µm and classifying them into 31 size channels. The test results at majority of the monitoring locations were well above the limits specified in the National Ambient Air Quality Standards of India. Microscopic studies of the dust samples were carried out for surface texture and particle shape. The spatial distribution of particles was analysed using geographic information system (GIS) for the visual identification of the extent of the pollution by keeping the cement factory as the focal point. The results from the GIS and microscopic analysis established the role of the cement factory in the particulate matter pollution of its surroundings, specifically in the areas North-West of the factory. The successfully adopted procedure can serve as a guideline for the environmental forensic investigation of similar pollution incidences.     

Survey of polyfluorinated chemicals (PFCs) in the atmosphere over the northeast Atlantic Ocean

High volume air sampling in Bermuda, Sable Island (Nova Scotia) and along a cruise track from the Gulf of Mexico to northeast coast of the USA, was carried out to assess air concentrations, particle-gas partitioning and transport of polyfluorinated chemicals (PFCs) in this region. Samples were collected in the summer of 2007. Targeted compounds included the neutral PFCs: fluorotelomer alcohols (FTOHs), perfluoroalkyl sulfonamides (FOSAs) and perfluoroalkyl sulfonamido ethanols (FOSEs).Among the FTOHs, 8:2 FTOH was dominant in all samples. Sum of the concentration of FTOHs (gas+particle phase) were higher in Bermuda (mean, 34 pg m^?3) compared to Sable Island (mean, 16 pg m^?3). In cruise samples, sum of FTOHs were highly variable (mean, 81 pg m^?3) reflecting contributions from land-based sources in the northeast USA with concentrations reaching as high as 156 pg m^?3.Among the FOSAs and FOSEs, MeFOSE was dominant in all samples. In Bermuda, levels of MeFOSE were exceptionally high (mean, 62 pg m^?3), exceeding the FTOHs. Sable Island samples also exhibited the dominance of MeFOSE but at a lower concentration (mean, 15 pg m^?3). MeFOSE air concentrations (pg m^?3) in cruise samples ranged from 1.6 to 73 and were not linked to land-based sources. In fact high concentrations of MeFOSE observed in Bermuda were associated with air masses that originated over the Atlantic Ocean.The partitioning to particles for 8:2 FTOH, 10:2 FTOH, MeFOSE and EtFOSE ranged from as high as 15 to 42% for cruise samples to 0.9 to 14% in Bermuda. This study provides key information for validating and developing partitioning and transport models for the PFCs.     

Electro-dissolution of metal scrap anodes for nickel ion removal from metal finishing effluent

This contribution reports a novel and cost efficient strategy for nickel ion removal from metal finishing effluents by electro-dissolution of scrap aluminium and iron sacrificial anodes. Electro-coagulation of effluent was carried out at 30 mA/cm² current density for 60 min. The nickel ion concentration of electroplating effluent was analysed by Atomic Absorption Spectroscopy. SEM images of iron and aluminium scrap anodes were critically analysed. Parameters such as heavy metal removal, anode dissolution rate with respect to heavy metal removal, reaction kinetics and cost estimation have been elaborately studied. Electro-coagulation at 30 mA/cm² for 60 min using iron and aluminium scrap anodes resulted in 95.9 and 94.1 % nickel ion reduction, respectively, with 0.0094 and 0.0053 g/ppm dissolution rates. The energy consumption for scrap aluminium and iron anodes was 0.0547 kWh/L. Loose internal bonding and spongy surface morphology of used metal scrap render high porosity and active surface area, enhancing reaction rate. Low cost and ready availability of waste scrap makes the process of electro-coagulation economically viable. Thus, the findings from this contribution point decisively at the superiority of waste metal scrap-based anodes for economic and environmentally sustainable heavy metal ion removal from metal finishing effluent.     

Development of a fuel cell propulsion system for the existing Mercedes B-Class 160 of petrol driven car

This paper presents a theoretical comparison between fuel cell (FC) power train and conventional petrol driven propulsion system. FC has potential to reduce the CO₂-emissions from road. However, FC power trains require energy storing device, to meet the peak power during extreme drive situations and also able to recover the kinetic energy of the vehicle during break operation. The proposed system includes a polymer electrolyte membrane fuel cell (PEMFC) based drive train and a super capacitor connected in parallel. The system is designed and dimensioned for a conventional petrol driven propulsion system of the Mercedes B-Class160. The feasibility study also includes comparison between the existing conventional systems. It is shown that although FC power train is heavier compared to existing system, urban performance is better and produces no CO₂ and other harmful emissions.     

Utilization of waste product (tamarind seeds) for the removal of Cr(VI) from aqueous solutions: Equilibrium, kinetics, and regeneration studies

In the present study, an adsorbent was prepared from tamarind seeds and used after activation for the removal of Cr(VI) from aqueous solutions. The tamarind seeds were activated by treating them with concentrated sulfuric acid (98% w/w) at a temperature of 150 °C. The adsorption of Cr(VI) was found to be maximum at low values of initial pH in the range of 1–3. The adsorption process of Cr(VI) was tested with Langmuir, Freundlich, Redlich–Peterson, Koble–Corrigan, Tempkin, Dubinin–Radushkevich and Generalized isotherm models. Application of the Langmuir isotherm to the system yielded a maximum adsorption capacity of 29.7 mg/g at an equilibrium pH value ranging from 1.12 to 1.46. The adsorption process followed second-order kinetics and the corresponding rate constants obtained were 2.605 × 10⁻³, 0.818 × 10⁻³, 0.557 × 10⁻³ and 0.811 × 10⁻³ g/mg min⁻¹ for 50, 200, 300 and 400 mg/L of initial Cr(VI) concentration, respectively. The regenerated activated tamarind seeds showed more than 95% Cr(VI) removal of that obtained using the fresh activated tamarind seeds. A feasible solution is proposed for the disposal of the contaminants (acid and base solutions) containing high concentrations of Cr(VI) obtained during the regeneration (desorption) process.     

Computation of groundwater resources and recharge in Chithar River Basin, South India

Groundwater recharge and available groundwater resources in Chithar River basin, Tamil Nadu, India spread over an area of 1,722 km² have been estimated by considering various hydrological, geological, and hydrogeological parameters, such as rainfall infiltration, drainage, geomorphic units, land use, rock types, depth of weathered and fractured zones, nature of soil, water level fluctuation, saturated thickness of aquifer, and groundwater abstraction. The digital ground elevation models indicate that the regional slope of the basin is towards east. The Proterozoic (Post-Archaean) basement of the study area consists of quartzite, calc-granulite, crystalline limestone, charnockite, and biotite gneiss with or without garnet. Three major soil types were identified namely, black cotton, deep red, and red sandy soils. The rainfall intensity gradually decreases from west to east. Groundwater occurs under water table conditions in the weathered zone and fluctuates between 0 and 25 m. The water table gains maximum during January after northeast monsoon and attains low during October. Groundwater abstraction for domestic/stock and irrigational needs in Chithar River basin has been estimated as 148.84 MCM (million m³). Groundwater recharge due to monsoon rainfall infiltration has been estimated as 170.05 MCM based on the water level rise during monsoon period. It is also estimated as 173.9 MCM using rainfall infiltration factor. An amount of 53.8 MCM of water is contributed to groundwater from surface water bodies. Recharge of groundwater due to return flow from irrigation has been computed as 147.6 MCM. The static groundwater reserve in Chithar River basin is estimated as 466.66 MCM and the dynamic reserve is about 187.7 MCM. In the present scenario, the aquifer is under safe condition for extraction of groundwater for domestic and irrigation purposes. If the existing water bodies are maintained properly, the extraction rate can be increased in future about 10 % to 15 %.