Lysimeter Experiments to Investigate the Fate of Chemicals in Soils – Comparison of Five Different Lysimeter Systems

Several lysimeter scenarios and approaches exist to study the fate of agro-chemicals or contaminants from deposition in soil columns. In many systems just transport and leaching of the parent compound is followed, in some systems the leaching and transport of the metabolites is investigated as well. In more sophisticated lysimeter systems the volatilization and also the mineralization of the applied chemicals can be additionally monitored. Depending on the lysimeter system used and on the fact whether the applied chemicals are ¹⁴C-labeled or not, different results and various interpretations of the results might be achieved. Different lysimeter systems are described in this paper and a real dataset of a specific lysimeter experiment was transferred and evaluated in a virtual approach in the different lysimeter systems in order to show the advantages and disadvantages of the various systems.     

Assessing computer waste generation in Chile using material flow analysis

The quantities of e-waste are expected to increase sharply in Chile. The purpose of this paper is to provide a quantitative data basis on generated e-waste quantities. A material flow analysis was carried out assessing the generation of e-waste from computer equipment (desktop and laptop PCs as well as CRT and LCD-monitors). Import and sales data were collected from the Chilean Customs database as well as from publications by the International Data Corporation. A survey was conducted to determine consumers’ choices with respect to storage, re-use and disposal of computer equipment. The generation of e-waste was assessed in a baseline as well as upper and lower scenarios until 2020.The results for the baseline scenario show that about 10,000 and 20,000 tons of computer waste may be generated in the years 2010 and 2020, respectively. The cumulative e-waste generation will be four to five times higher in the upcoming decade (2010–2019) than during the current decade (2000–2009). By 2020, the shares of LCD-monitors and laptops will increase more rapidly replacing other e-waste including the CRT-monitors. The model also shows the principal flows of computer equipment from production and sale to recycling and disposal. The re-use of computer equipment plays an important role in Chile. An appropriate recycling scheme will have to be introduced to provide adequate solutions for the growing rate of e-waste generation.     

Biogeometallurgical pre-mining characterization of ore deposits: an approach to increase sustainability in the mining process

Based on the knowledge obtained from acid mine drainage formation in mine waste environments (tailings impoundments and waste rock dumps), a new methodology is applied to characterize new ore deposits before exploitation starts. This gives the opportunity to design optimized processes for metal recovery of the different mineral assemblages in an ore deposit and at the same time to minimize the environmental impact and costs downstream for mine waste management. Additionally, the whole economic potential is evaluated including strategic elements. The methodology integrates high-resolution geochemistry by sequential extractions and quantitative mineralogy in combination with kinetic bioleach tests. The produced data set allows to define biogeometallurgical units in the ore deposit and to predict the behavior of each element, economically or environmentally relevant, along the mining process.     

Factors influencing farmers’ decisions on nitrogen fertilizer application in the Liangzihu Lake basin,Central China

Overuse of nitrogen (N) fertilizers in agriculture activities has caused severe water pollution in China. The lack of data at producer level hampers decision makers in the development and implementation of efficient policies to curb excessive N-fertilizer use. In a survey of 300 farm households in the Liangzihu Lake basin, we identified factors associated with farmers’ decisions on N-fertilizer use and application rate. Household survey and multiple linear regression models indicate that the average application rate in the study region is 229 kg N ha^?1, which exceeds the recommended rate for maximum profit for cereal crops (maize, wheat, and rice) in China of 150–180 kg N ha^?1. High N-application rates are associated with low farmland productivity (coefficient = ?15.66, p = 0.02), a high share of off-farm income (coefficient = 27.14, p = 0.003), and a low education level of the household head (coefficient = ?10.83, p = 0.039). Neither physical infrastructure nor access to input markets appears to be related to N-application rates. It may be concluded that excessive use of N in agriculture of Central China is mainly a problem of insufficient awareness and high share of off-farm income.     

Towards a framework for cross-scale and multi-level analysis of coastal and marine social-ecological systems dynamics

As the Anthropocene proceeds, regional and local sustainability problems are ever more likely to originate at multiple levels of the earth system. The rate of global environmental change is now vastly outpacing our policy response, and social-ecological systems analysis needs to support global environmental governance. To respond to this challenge, this paper initiates the development of a coastal social-ecological typology and applies it in an exemplary fashion to nine coastal and marine case studies. We use an explicit distinction between the definitions of scale and level and a problem or issue-specific approach to the delineation of social-ecological units. A current major challenge to social-ecological systems analysis is the identification of the cross-level and cross-scale interactions and links which play key roles in shaping coastal and marine social-ecological dynamics and outcomes. We show that the regional level is the best point of departure to generate sustainability-oriented cross-scale and multi-level analyses and offers the outline of a typology in which different disciplinary and other forms of knowledge can be integrated as both part of regionally grounded analysis and action which engages with global sustainability challenges.     

Metal contamination and solid phase partitioning of metals in urban roadside sediments

This study was undertaken to assess the anthropogenic impact on metal concentrations of urban roadside sediments (N = 633) in Seoul city, Korea and to estimate the potential mobility of selected metals (Zn, Cu, Pb, Cr, Ni, and Cd) using sequential extraction. Comparison of metal concentrations in roadside sediments with mean background values in sediments collected from first- or second-order streams in Korea shows that Zn, Cu and Pb are most affected by anthropogenic inputs. The 206Pb/207Pb ratios of roadside sediments (range = 1.1419-1.1681; mean 1.1576 +/- 0.0068) suggest that Pb is mainly derived from industrial sources rather than from leaded gasoline. A five-step sequential extraction of roadside sediments showed that Zn, Cd and to a lesser degree Ni occur predominantly in the carbonate bound fraction, while Pb is highest in the reducible fraction, Cu in the organic fraction, and Cr in the residual fraction. It was found that the concentrations in the readily available exchangeable fraction were generally low for most metals examined, except for Ni whose exchangeable fraction was appreciable (average 15.2%). Considering the proportion of metals bound to the exchangeable and carbonate fractions, the comparative mobility of metals probably decreases in the order of Zn > Ni > Cd > Pb > Cu > Cr. As potential changes of redox state and pH may remobilize the metals bound to carbonates, reducible, and/or organic matter, and may release and flush them through drain networks into streams, careful monitoring of environmental conditions appears to be very important. With respect to ecotoxicity, it is apparent the Zn and Cu pollution is of particular concern in Seoul city.     

Grassy field margins and arthropod diversity: a case study on ground beetles and spiders in eastern Austria (Coleoptera: Carabidae; Arachnida: Aranei, Opiliones)

In 1983, the species composition and diversity of carabids, spiders and harvestmen was investigated by pitfall traps in a grassy field margin and in an adjacent, biologically farmed wheat field at Obere Lobau, Vienna, Austria.The carabid fauna of both habitats was diverse; it showed a high degree of similarity, the abundant species in both habitats being represented by typical field species. Only Metophonus spp. predominantly lived in the margin. Numerous species of different habitat origin occurred in the margin at low abundances indicating transitional stay rather than permanent populations.In contrast, the spider fauna showed a low degree of similarity, with few agrobiotic species strongly dominating field fauna. In the field margin, a rich spider fauna containing rare elements indicates the general importance of grassy margins for nature conservation. The apparently low faunal exchange of spiders between the two habitat types is discussed. Harvestmen occurred mainly in the field margin; only two thermophilic species invaded the field.Seasonal fluctuations in the trapping numbers of Bembidion lampros, Platynus dorsalis and Brachinus explodens are interpreted as indicating migrations between field margin and field. Poecilus cupreus and certain other field species, however, apparently spend their entire life cycle in the field. The possible function of field margins for restoration of carabid losses due to impacts of intensive cultivation is discussed.It is concluded that both grassy field margins and sustainable farming methods, in particular biological farming, are necessary to maintain a diverse predatory arthropod fauna in agroecosystems.