The herbicide paraquat induces alterations in the elemental and biochemical composition of non-target microalgal species

Huge quantities of pesticides are dispersed in the environment, affecting non-target organisms. Since paraquat affects the photosynthetic process, the biochemical composition of affected species should be altered. The effect of paraquat on Chlamydomonas moewusii, a freshwater non-target species, was studied. After 48 h of herbicide exposure, growth rate, dry weight, and chlorophyll a and protein content were affected by paraquat concentrations above 0.05 μM. C/N ratio was also affected due to a decrease in nitrogen content in the dry biomass, while the carbon content remained constant for all paraquat concentrations assayed. Enzymes involved in nitrogen assimilation were affected by paraquat, being nitrate reductase activity more sensitive to paraquat than nitrite reductase. Based on the results obtained in the present study, paraquat exerts adverse effects upon a common freshwater green microalga, thus the application of this herbicide for weed control must be carried out very carefully, so that any disturbance affecting algae will have severe repercussions on higher trophic levels and on the elemental biogeochemical cycles.     

Land Evaluation in a Salt-Affected Irrigated District Using an Index of Productive Potential

2 semiarid irrigated area with salt-affected soils. The available soil map is at 1:100,000 scale and its mapping units are used for the land evaluation with the FAO framework. These data are then elaborated using the index value method. This procedure gives a map of land evaluation units and a table that rates the productive potential of these units for six crops: alfalfa, barley, maize, rice, sunflower, and wheat.     

Assessing safety culture in the Spanish nuclear industry through the use of working groups

This paper presents the design and the implementation of a methodology for measuring and improving safety culture at a nuclear power plant (NPP). The study has involved the completion of a pilot project aimed at seeing how to make use of the RADAR logic (Results, Approach, Deployment, Assessment and Review) of the EFQM model as a tool for the self assessment of safety culture in a nuclear power plant. The work was aimed at finding evidence of the safety culture that was in place at the plant and at identifying both the strengths of that culture and any areas in which it could be improved. The score obtained from an analysis of those strengths and areas for improvement has made it possible to prioritise the actions to be taken. The identification of perceptions and evidence, the agreement on the strong points and areas for improvement and the quantification of the safety culture have been performed by groups comprising volunteers who work at the NPP. The advantages of this methodology are assessed in the paper.     

The Spanish building crisis and its effect in the gypsum quarry production (1998–2012)

Gypsum is one of the most important mined mineral commodities of the world. As an industrial rock, it is primarily used by the construction industry. Therefore, the economics of the gypsum market can be correlated with parameters that have controlled the origin and development of the Spanish building bubble between years 1998 and 2006. The burst of this building bubble has been interpreted as the main triggering factor for Spain's current crisis.     

The proton binding properties of biosorbents

Environmental Chemistry Letters - A broad variety of materials of biological origin have been successfully used in recent decades for the removal of pollutants from waters. These biosorbents...     

The power and pain of market-based carbon policies: a global application to greenhouse gases from ruminant livestock production

The objectives of this research are to assess the greenhouse gas mitigation potential of carbon policies applied to the ruminant livestock sector [inclusive of the major ruminant species—cattle (Bos Taurus and Bos indicus), sheep (Ovis aries), and goats (Capra hircus)]—with particular emphasis on understanding the adjustment challenges posed by such policies. We show that market-based mitigation policies can greatly amplify the mitigation potential identified in marginal abatement cost studies by harnessing powerful market forces such as product substitution and trade. We estimate that a carbon tax of US$20 per metric ton of carbon dioxide (CO₂) equivalent emissions could mitigate 626 metric megatons of CO₂ equivalent ruminant emissions per year (MtCO₂-eq year^?1). This policy would also incentivize a restructuring of cattle production, increasing the share of cattle meat coming from the multiproduct dairy sector compared to more emission intensive, single purpose beef sector. The mitigation potential from this simple policy represents an upper bound because it causes ruminant-based food production to fall and is therefore likely to be politically unpopular. In the spirit of the Paris Agreement (UNFCCC 2015), which expresses the ambition of reducing agricultural emissions while protecting food production, we assess a carbon policy that applies both a carbon tax and a subsidy to producers to manage the tradeoff between food production and mitigation. The policy maintains ruminant production and consumption levels in all regions, but for a much lower global emission reduction of 185 MtCO₂-eq year^?1. This research provides policymakers with a quantitative basis for designing policies that attempt to trade off mitigation effectiveness with producer and consumer welfare.     

Electrowinning studies for metallic zinc production from double leached Waelz oxide

Waelz oxide is a zinc and lead concentrate pyrometallurgically derived from electric arc furnace dust. There are clear incentives to leaching and purify this oxide to produce liquors that can be electrowinned to obtain recycled metallic zinc. This study is focused on this electrolytic zinc production from previously obtained sulphuric liquor. This liquor was obtained from double leached Waelz oxide (DLWO) throughout a hydrometallurgical process. The electrolytic liquor, after the corresponding leaching and purification stages, contains around 49 kg/m³. This liquor was fed to an electrowinning process where platinum or lead anodes and aluminium cathodes were used. After optimizing the different electrowinning critical parameters, and working at these optimal conditions, almost 88 secondary zinc kg were precipitated per each initial DLWO tonne in one-through process. The zinc purity was higher than 99.5%. After some mass balance calculations, it can be concluded that, optimizing the process configuration through internal recycling, around 210 Zn kg/DLWO t with purity near to 100% could be achieved.     

The marine macroalga Cystoseira baccata as biosorbent for cadmium(II) and lead(II) removal: kinetic and equilibrium studies

This work reports kinetic and equilibrium studies of cadmium(II) and lead(II) adsorption by the brown seaweed Cystoseira baccata. Kinetic experiments demonstrated rapid metal uptake. Kinetic data were satisfactorily described by a pseudo-second order chemical sorption process. Temperature change from 15 to 45 degrees C showed small variation on kinetic parameters. Langmuir-Freundlich equation was selected to describe the metal isotherms and the proton binding in acid-base titrations. The maximum metal uptake values were around 0.9 mmol g(-1) (101 and 186 mg g(-1) for cadmium(II) and lead(II), respectively) at pH 4.5 (raw biomass), while the number of weak acid groups were 2.2 mmol g(-1) and their proton binding constant, K(H), 10(3.67) (protonated biomass). FTIR analysis confirmed the participation of carboxyl groups in metal uptake. The metal sorption was found to increase with the solution pH reaching a plateau above pH 4. Calcium and sodium nitrate salts in solution were found to affect considerably the metal biosorption.