全文获取类型
收费全文 | 853篇 |
免费 | 9篇 |
国内免费 | 40篇 |
专业分类
安全科学 | 43篇 |
废物处理 | 104篇 |
环保管理 | 88篇 |
综合类 | 115篇 |
基础理论 | 130篇 |
环境理论 | 2篇 |
污染及防治 | 315篇 |
评价与监测 | 72篇 |
社会与环境 | 27篇 |
灾害及防治 | 6篇 |
出版年
2023年 | 11篇 |
2022年 | 12篇 |
2021年 | 13篇 |
2020年 | 7篇 |
2019年 | 13篇 |
2018年 | 32篇 |
2017年 | 41篇 |
2016年 | 37篇 |
2015年 | 24篇 |
2014年 | 33篇 |
2013年 | 85篇 |
2012年 | 51篇 |
2011年 | 67篇 |
2010年 | 46篇 |
2009年 | 60篇 |
2008年 | 65篇 |
2007年 | 60篇 |
2006年 | 57篇 |
2005年 | 45篇 |
2004年 | 45篇 |
2003年 | 22篇 |
2002年 | 19篇 |
2001年 | 16篇 |
2000年 | 7篇 |
1999年 | 5篇 |
1998年 | 5篇 |
1997年 | 1篇 |
1996年 | 1篇 |
1995年 | 1篇 |
1994年 | 4篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1991年 | 2篇 |
1990年 | 1篇 |
1989年 | 3篇 |
1985年 | 1篇 |
1982年 | 2篇 |
1981年 | 1篇 |
1978年 | 1篇 |
1976年 | 1篇 |
1973年 | 1篇 |
1970年 | 1篇 |
1969年 | 1篇 |
排序方式: 共有902条查询结果,搜索用时 17 毫秒
1.
When combined in the lining and covering of waste-containment facilities, soil and geosynthetic components protect the environment by acting as a hydraulic barrier. Equipment loading may significantly increase the tensile stress induced in geosynthetic components, leading to a potential stability problem. Large equipment loadings may also result in a localized circular slip surface during construction operations. New analytical method based on discrete element modelling is proposed for estimating the distribution of tensile force developed in the individual geosynthetic components of the lining system and for evaluating the safety factor of slope failure due to equipment loading. The analytical results of an example are presented to demonstrate the applicability of the analytical method for the lining system of a waste landfill. The analyses of the example show that equipment loading provide a substantial increase in the tensile forces of the geosynthetic components of a lining system and that the possibility of shallow failure due to equipment loading increases as the slope becomes steeper. This method is a useful tool for analysing the lining system of waste landfills with complex lining components. 相似文献
2.
3.
J. Y. Kim M.-C. Shin J.-R. Park K. Nam 《Journal of Material Cycles and Waste Management》2003,5(1):0055-0062
The effect of the soil solids concentration in batch tests on the measured values of the partition coefficient (K
p) of organic pollutants in landfill liner-soil material was investigated. Since this study was based on the results of batch
and column tests conducted independently, there were limitations to the conclusions derived. The organic compounds tested
were benzene, methylene chloride, toluene, trichloroethylene, and p-xylene. The results of this study showed that as soil solids concentrations increased, the measured K
p values of these organic compounds strongly decreased. The observed values of K
p stabilized when the soil solids concentration was above a certain value. Typical K
p values obtained from batch tests conducted under high soil solids concentrations were close to those obtained from column
tests. It was concluded that the K
p values of organic compounds measured under low soil solids concentrations, i.e., less than 100 g/l, may not correctly simulate
the field situation. Consequently, the values of K
p obtained with low soil solids concentrations can result in an overestimation of the retardation factor of the landfill liner
material.
Received: March 14, 2002 / Accepted: August 25, 2002 相似文献
4.
A data analysis of three major Korean cities was conducted to assess roadside inhalable particulate matter 10 μm or smaller
in aerodynamic diameter (PM10), including temporal and meteorological variations, over a recent period of 4 to 6 years. The yearly roadside PM10 concentrations presented a well-defined increasing trend or no trend depending on the roadside monitoring station. Most mean
values exceeded or approximated the Korean standard of 70 μg/m3 per year for PM10. A representative roadside diurnal trend was characterized by a distinct morning maximum. In most cases, the Sunday roadside
concentrations were similar to or somewhat lower than the weekday concentrations, and the PM10 concentrations presented a well-defined seasonal variation, with the maximum concentration in March. The monthly maximum
concentrations observed in March were most likely attributable to Asian dust storms. In two metropolitan cities (Seoul and
Busan), the frequency of days with roadside PM10 concentrations exceeding the standard of 150μg/m3 per 24 h was much lower for the roadside monitoring stations than for the residential monitoring station, whereas in the
third city (Daegu), this result was reversed. Interestingly, the average maximum concentrations observed for the roadside
sites in Seoul and Busan during March were higher than those for the residential sites, suggesting that the roadside concentrations
responded more to the dust storms than the residential areas. The relationship between the pollutant concentrations and five
important meteorological parameters (solar radiation, wind speed, air temperature, relative humidity, and precipitation) showed
that the number and type of meteorological variables included in the equations varied according to the monitoring station
or season. Finally, the current results confirmed that attention should be given to the PM10 exposure of residents living near roadways. 相似文献
5.
Assessment of Soil Erodibility Indices for Conservation Reserve Program Lands in Southwestern Kansas Using Satellite Imagery and GIS Techniques 总被引:2,自引:0,他引:2
The soil erodibility index (EI) of Conservation Reserve Program (CRP) lands, which was the major criterion for CRP enrollment,
was assessed for six counties in southwestern Kansas using USGS seamless digital elevation model data and Geographical Informational
System techniques. The proportion of land areas with EI values of 8 or lower was less than 1% of the entire study area and
most of the land areas (72.5%) were concentrated on EI values between 8 and 24. Although land acreage with EI values of 24
or higher decreased dramatically, the proportion of CRP lands to the other land-use types did not change much from low to
high EI levels. The soil EI and physical soil characteristics of the CRP lands were compared to those of other land-use types.
In general, the mean EI values of the land-use types were strongly correlated with physical soil properties, including organic
matter content, clay content, available water capacity, permeability, and texture. CRP lands were compared in detail with
cropland in terms of their soil characteristics to infer the pivotal cause of the land transformation. Although there was
no significant statistical difference in EI between cropland and CRP soils, soil texture, soil family, and permeability were
statistically different between the two. Statistical analyses of these three variables showed that CRP soils had coarser texture
and higher permeability on average than cropland soils, indicating that CRP lands in the study area are drier than cropland
soils. Therefore, soil moisture characteristics, not necessarily soil erosion potential, might have been the key factor for
CRP enrollment in the study area. 相似文献
6.
Repeated application may increase rates of pesticide dissipation in soil and reduce persistence. The potential for this to occur was investigated for the fungicide, tebuconazole (alpha-[2-(4-chlorophenyl)ethyl]-alpha-(1,1-dimethylethyl)-1H-1,2,4-triazole-1-ethanol), when used for peanut (Arachis hypogaea L.) production. Soil samples were collected from peanut plots after each of four tebuconazole applications at 2-wk intervals. Soil moisture was adjusted to field capacity as necessary and samples were incubated in the laboratory for 63 d at 30 degrees C. Untreated plot samples spiked with the compound served as controls. Results indicated accelerated dissipation in field-treated samples with the time to fifty percent dissipation (DT50) decreasing from 43 to 5 d after three tebuconazole applications. Corresponding increases in rates of accumulation and decay of degradates were also indicated. Best-fit equations (r2 = 0.84-0.98) to dissipation kinetic data combined with estimates of canopy interception rates were used to predict tebuconazole and degradates concentration in soil after each successive application. Predicted concentrations compared with values measured in surface soil samples were from twofold less to twofold greater. Use of kinetic data will likely enhance assessments of treatment efficacy and human and ecological risks from normal agronomic use of tebuconazole on peanut. However, the study indicated that varying soil conditions (in particular, soil temperature and water content) may have an equal or greater impact on field dissipation rate than development of accelerated dissipation. Results emphasize that extension of laboratory-derived kinetic data to field settings should be done with caution. 相似文献
7.
Kwanyong Lee Phrompol Chantrasakdakul Daegi Kim Mingeun Kong Ki Young Park 《Waste management (New York, N.Y.)》2014,34(6):1035-1040
The filamentous alga Hydrodictyon reticulatum harvested from a bench-scale wastewater treatment pond was used to evaluate biogas production after ultrasound pretreatment. The effects of ultrasound pretreatment at a range of 10–5000 J/mL were tested with harvested H. reticulatum. Cell disruption by ultrasound was successful and showed a higher degree of disintegration at a higher applied energy. The range of 10–5000 J/mL ultrasound was able to disintegrated H. reticulatum and the soluble COD was increased from 250 mg/L to 1000 mg/L at 2500 J/mL. The disintegrated algal biomass was digested for biogas production in batch experiments. Both cumulative gas generation and volatile solids reduction data were obtained during the digestion. Cell disintegration due to ultrasound pretreatment increased the specific biogas production and degradation rates. Using the ultrasound approach, the specific methane production at a dose of 40 J/mL increased up to 384 mL/g-VS fed that was 2.3 times higher than the untreated sample. For disintegrated samples, the volatile solids reduction was greater with increased energy input, and the degradation increased slightly to 67% at a dose of 50 J/mL. The results also indicate that disintegration of the algal cells is the essential step for efficient anaerobic digestion of algal biomass. 相似文献
8.
Organic matters (OMs) and their oxidization products often influence the fate and transport of heavy metals in the subsurface aqueous systems through interaction with the mineral surfaces. This study investigates the ethanol (EtOH)-mediated As(III) adsorption onto Zn-loaded pinecone (PC) biochar through batch experiments conducted under Box–Behnken design. The effect of EtOH on As(III) adsorption mechanism was quantitatively elucidated by fitting the experimental data using artificial neural network and quadratic modeling approaches. The quadratic model could describe the limiting nature of EtOH and pH on As(III) adsorption, whereas neural network revealed the stronger influence of EtOH (64.5%) followed by pH (20.75%) and As(III) concentration (14.75%) on the adsorption phenomena. Besides, the interaction among process variables indicated that EtOH enhances As(III) adsorption over a pH range of 2 to 7, possibly due to facilitation of ligand–metal(Zn) binding complexation mechanism. Eventually, hybrid response surface model–genetic algorithm (RSM–GA) approach predicted a better optimal solution than RSM, i.e., the adsorptive removal of As(III) (10.47 μg/g) is facilitated at 30.22 mg C/L of EtOH with initial As(III) concentration of 196.77 μg/L at pH 5.8. The implication of this investigation might help in understanding the application of biochar for removal of various As(III) species in the presence of OM. 相似文献
9.
A bias in clear-sky conditions that will be involved in estimating particulate matter(PM)concentration from aerosol optical depth(AOD) was examined using PM_(10) from two Aerosol Robotic Network sites in Korea. The study periods were between 2004 and 2007 at Anmyon and between 2003 and 2011 at Gosan, when both PM_(10) and AOD were available. Mean PM_(10) when AOD was available(PM AOD) was higher than that from all PM_(10)data(PM all) by 5.1 and9.9 μg/m~3 at Anmyon and Gosan, which accounted for 11% and 26% of PM all, respectively.Because of a difference between mean PM_(10) under daytime clear-sky conditions(PM clear)and PM AOD, the variations in ΔPM_(10), the difference of PM all from PM clear rather than from PM AOD, were investigated. Although monthly variations in ΔPM_(10)at the two sites were different, they were positively correlated to those in ΔT, similarly defined as ΔPM_(10)except for temperature, at both sites. ΔPM_(10)at Anmyon decreased to a negative value in January due to an influence of the Siberian continental high-pressure system while ΔPM_(10)at Gosan was high in winter due to an effect of photochemical production at higher temperatures than at Anmyon. 相似文献
10.
Formic acid was used for the nitrate reduction as a reductant in the presence of Pd:Cu/γ-alumina catalysts. The surface characteristics of the bimetallic catalyst synthesized by wet impregnation were investigated by SEM, TEM-EDS. The metals were not distributed homogeneously on the surface of catalyst, although the total contents of both metals in particles agreed well with the theoretical values. Formic acid decomposition on the catalyst surface, its influence on solution pH and nitrate removal efficacy was investigated. The best removal of nitrate (50 ppm) was obtained under the condition of 0.75 g/L catalyst with Pd:Cu ratio (4:1) and two fold excess of formic acid. Formic acid decay patterns resembled those of nitrate removal, showing a linear relationship between kf (formic acid decay) and k (nitrate removal). Negligible amount of ammonia was detected, and no nitrite was detected, possibly due to buffering effect of bicarbonate that is in situ produced by the decomposition of formic acid, and due to the sustained release of H2 gas. 相似文献