有意违章行为动因分析与控制对策探讨

对有意违章行为的含义进行了界定 ,并对有意违章行为产生的动因进行了详细分析 ,提出了有意违章行为的动因主要包含违章行为与遵章行为满足生理心理需要作用的差值ΔXW、违章行为会受到法规惩处的作用FW、违章行为可导致人身伤害的主观感觉的作用RW3个方面。同时对 3个方面的动因按弗鲁姆的激励理论进行了转化 ,给出了各自的含义说明。笔者按动因分析的结果 ,给出了控制有意违章行为的步骤和措施     

Density functional theory (DFT) studies of vanadium-titanium based selective catalytic reduction (SCR) catalysts

Based on density functional theory (DFT) and basic structure models, the chemical reactions on the surface of vanadium-titanium based selective catalytic reduction (SCR) denitrification catalysts were summarized. Reasonable structural models (non-periodic and periodic structural models) are the basis of density functional calculations. A periodic structure model was more appropriate to represent the catalyst surface, and its theoretical calculation results were more comparable with the experimental results than a non-periodic model. It is generally believed that the SCR mechanism where NH₃ and NO react to produce N₂ and H₂O follows an Eley-Rideal type mechanism. NH₂NO was found to be an important intermediate in the SCR reaction, with multiple production routes. Simultaneously, the effects of H₂O, SO₂ and metal on SCR catalysts were also summarized.     

Metabolomic modulations in a freshwater microbial community exposed to the fungicide azoxystrobin

An effective broad-spectrum fungicide, azoxystrobin (AZ), has been widely detected in aquatic ecosystems, potentially affecting the growth of aquatic microorganisms. In the present study, the eukaryotic alga Monoraphidium sp. and the cyanobacterium Pseudanabaena sp. were exposed to AZ for 7 days. Our results showed that 0.2–0.5 mg/L concentrations of AZ slightly inhibited the growth of Monoraphidium sp. but stimulated Pseudanabaena sp. growth. Meanwhile, AZ treatment effectively increased the secretion of total organic carbon (TOC) in the culture media of the two species, and this phenomenon was also found in a freshwater microcosm experiment (containing the natural microbial community). We attempted to assess the effect of AZ on the function of aquatic microbial communities through metabolomic analysis and further explore the potential risks of this compound. The metabonomic profiles of the microcosm indicated that the most varied metabolites after AZ treatment were related to the citrate cycle (TCA), fatty acid biosynthesis and purine metabolism. We thereby inferred that the microbial community increased extracellular secretions by adjusting metabolic pathways, which might be a stress response to reduce AZ toxicity. Our results provide an important theoretical basis for further study of fungicide stress responses in aquatic microcosm microbial communities, as well as a good start for further explorations of AZ detoxification mechanisms, which will be valuable for the evaluation of AZ environmental risk.     

Effect of TiO2 nanoparticle aggregation on marine microalgae Isochrysis galbana

TiO_2 nanoparticles(NPs) could adversely impact aquatic ecosystems. However, the aggregation of these NPs could attenuate this effect. In this work, the biological effects of TiO_2 NPs on a marine microalgae Isochrysis galbana were investigated. The aggregation kinetics of TiO_2 NPs under different conditions was also investigated to determine and understand these effects. Results showed that, though TiO_2 NPs had no obvious impact on the size and reproducibility of algal cells under testing conditions, they caused a negative effect on algal chlorophyll, which led to a reduction in photosynthesis. Furthermore, fast aggregation of TiO_2 NPs occurred under all conditions, especially at the pH close to the p Hzpc. Increasing ionic strength and NP concentration also enhanced the aggregation rate.The aggregation and the following sedimentation of TiO_2 NPs reduced their adverse effects on I. galbana.     

高含硫气田用电阻探针的适用性改造

针对电阻探针在普光高含硫气田腐蚀监测系统应用中出现了大量本体焊接部位断裂、断面密封失效现象,测试分析显示高含硫、高压及高流速冲击震动导致焊缝腐蚀疲劳失效和密封材料老化失效。通过采用锻造态不锈钢棒料整体制造消除了电阻探针壳体的焊接,采用金属密封复合抗硫密封胶对测试片断面密封方式进行改进优化。现场应用表明,改进后的电阻探针不再出现断裂,密封失效现象大幅减少,使用寿命整体提高3倍以上。     

Determination of Trace Organochlorinated Pesticides and Polychlorinated Biphenyls in Water

A modified steam distillation liquid-liquid extraction (SDE) device is developed for the enrichment of trace organochlorinated pesticides (OCPs) and polychlorinated biphenyls (PCBs) in up to one litre of water samples. One ml of n-hexane is sufficient to extract the analytes. The extract can be analysed directly by a capillary gas chromatography-electron capture detector. The recoveries range from 84.6 to 102.3% for OCPs and 80.5 to 106.2% for PCBs, respectively. Matrice materials such as lipids and humic substances were removed by the SDE method from the extract and no further cleanup and concentration steps were needed.     

超声波－蒸汽蒸馏萃取技术富集沉积物样品中的氯代农药和多氯联苯

为方便快速分离沉积物中含氯农药和多氯联苯，将超声波技术和蒸汽蒸馏萃取技术相结合，萃取沉积物中的微量含氯农药和多氯联苯，所得萃取物不需进一步的净化和浓缩，可直接用于色谱分析．实验表明，在进行蒸汽蒸馏萃取之前，使用辅助的超声波技术可将大部分待测物的回收率提高２０％－３０％，较好地解决了由于沉积物的吸附作用而导致的蒸汽蒸馏萃取回收率偏低的缺陷．该法使沉积物样品中的氯代农药和多氯联苯的蒸汽蒸馏萃取富集成为可能．     

布、洛、维、肖氏硬度的相关关系

进行了布、洛、维、肖氏硬度之间的回归分析,建立了洛氏硬度与布氏、维氏、肖氏硬度之间,以及布氏硬度与维氏、肖氏硬度之间的回归关系式.     

Method of pollution sources assessment in relation to residential site selection

Much investigation supports a high incidence of disease and death rates when people live in ambient polluted air for a long time. Thus, the location of residential sites is important from a public health viewpoint. The method outlined in this paper is useful for determining the location of residential sites based on pollution sources assessment.     

加强城市灾害应急管理能力建设确保城市的可持续发展

本文通过对我国城市化与经济发展的关系,分析了我国城市面临的灾害形势及城市应急管理中存在的问题,提出了加强城市应急能力建设的途径,可供国内各大中城市参考和借鉴.