全文获取类型
收费全文 | 102篇 |
免费 | 0篇 |
国内免费 | 4篇 |
专业分类
安全科学 | 6篇 |
废物处理 | 9篇 |
环保管理 | 11篇 |
综合类 | 8篇 |
基础理论 | 19篇 |
污染及防治 | 31篇 |
评价与监测 | 13篇 |
社会与环境 | 9篇 |
出版年
2022年 | 10篇 |
2021年 | 5篇 |
2020年 | 2篇 |
2019年 | 2篇 |
2018年 | 5篇 |
2017年 | 7篇 |
2016年 | 10篇 |
2015年 | 4篇 |
2014年 | 10篇 |
2013年 | 13篇 |
2012年 | 4篇 |
2011年 | 7篇 |
2010年 | 5篇 |
2009年 | 1篇 |
2008年 | 1篇 |
2007年 | 1篇 |
2006年 | 2篇 |
2005年 | 1篇 |
2004年 | 2篇 |
2003年 | 1篇 |
2001年 | 1篇 |
2000年 | 2篇 |
1999年 | 1篇 |
1989年 | 2篇 |
1977年 | 1篇 |
1974年 | 1篇 |
1972年 | 3篇 |
1971年 | 1篇 |
1959年 | 1篇 |
排序方式: 共有106条查询结果,搜索用时 15 毫秒
1.
Analysis of endosulfan, chlorpyrifos, and their nonpolar metabolites in extracts from environmental aqueous and soil samples was performed using a gas chromatography-tandem mass spectrometry (GC–MS/MS) technique. Full-scan GC–MS analysis showed poor sensitivity for some of the metabolites (endodiol and endosulfan ether). A multisegment MS/MS method was developed and MS/MS parameter isolation time, excitation time, excitation voltage, and maximum excitation energy were optimized for chosen precursor ions to enhance selectivity and sensitivity of the analysis. The use of MS/MS with optimized parameters quantified analytes with significantly higher accuracy, and detection limits were lowered to ~1/6th compared with the full-scan method. Co-eluting compounds, chlorpyrifos and chlorpyrifos oxon, were also analyzed successfully in the MS/MS mode by choosing exclusive precursor ions. Analysis of soil and water phase samples from contaminated soil slurry bioreactors showed that the MS/MS method could provide more reliable estimates of these pesticide and metabolites (especially those present in low concentrations) by annulling interferences from soil organic matter. 相似文献
2.
P. Manoj Kumar Reddy Sk. Mahammadunnisa B. Ramaraju B. Sreedhar Ch. Subrahmanyam 《Environmental science and pollution research international》2013,20(6):4111-4124
Activated carbons (ACs) were developed from bio-waste materials like rice husk and peanut shell (PS) by various physicochemical activation methods. PS char digested in nitric acid followed by treatment at 673 K resulted in high surface area up to ~585 m2/g. The novelty of the present study is the identification of oxygen functional groups formed on the surface of activated carbons by infrared and X-ray photoelectron spectroscopy and quantification by using temperature programmed decomposition (TPD). Typical TPD data indicated that each activation method may lead to varying amounts of acidic and basic functional groups on the surface of the adsorbent, which may be a crucial factor in determining the adsorption capacity. It was shown that ACs developed during the present study are good adsorbents, especially for the removal of a model textile dye methylene blue (MB) from aqueous solution. As MB is a basic dye, H2O2-treated rice husk showed the best adsorption capacity, which is in agreement with the acidic groups present on the surface. Removal of the dye followed Langmuir isotherm model, whereas MB adsorption on ACs followed pseudo-second-order kinetics. 相似文献
3.
Bhaskar Kumar Anurag Al-Hashimi Abdulrahman Meena Mahesh Meena Vijay Singh Langyan Sapna Shrivastava Manoj Sayyed Riyaz Zafar El-Enshasy Hesham A Almunqedhi Bandar Mohsin Ahmed Singh Renu 《Environmental science and pollution research international》2022,29(7):9792-9804
Environmental Science and Pollution Research - A large amount of ammonia volatilization from the agricultural system causes environmental problems and increases production costs. Conservation... 相似文献
4.
The dissipation of chlorpyrifos (20 EC) at environment-friendly doses in the sandy loam and loamy sand soils of two semi-arid fields and the presence of pesticide residues in the harvested groundnut seeds, were monitored. The movement of chlorpyrifos through soil and its binding in the loamy sand soil was studied using 14C chlorpyrifos. Chlorpyrifos was moderately stable in both loamy sand and sandy loam soils, with half-life of 12.3 and 16.4 days, respectively. With 20 EC treatments the dissipation was slower for standing crop than seed treatment, indicative of the high degradation rates in the bioactive rhizosphere. In soil, 3,5,6-trichloro-2-pyridinol (TCP) was the principal breakdown product. Presence of 3,5,6-trichloro-2-methoxypyridine (TMP), the secondary metabolite, detected in the rhizospheric samples during this study, has not been reported earlier in field soils. The rapid dissipation of the insecticide from the soil post-application might have resulted from low sorption due to the alkalinity of the soil and its low organic matter content, fast topsoil dissipation possibly by volatilization and photochemical degradation, aided by the low water solubility, limited vertical mobility due to confinement of residues to the upper 15 cm soil layers and microbial mineralization and nucleophilic hydrolysis. Contrary to the reports of relatively greater mobility of its metabolites in temperate soils, TMP and TCP remained confined to the top 15 cm soil. The formation of bound residues (half-life 13.4 days) in the loamy sand soil was little and not "irreversible." A decline in bound residues could be correlated to decreasing TCP concentration. Higher pod yields were obtained from pesticide treated soils in comparison to controls. Post-harvest no pesticide residues were detected in the soils and groundnut seeds. 相似文献
5.
A. K. Srivastava D. S. Bisht K. Ram S. Tiwari Manoj K. Srivastava 《Environmental science and pollution research international》2014,21(14):8610-8619
The mass concentration of carbonaceous species, organic carbon (OC), and elemental carbon (EC) using a semicontinuous thermo-optical EC-OC analyzer, and black carbon (BC) using an Aethalometer were measured simultaneously at an urban mega city Delhi in Ganga basin from January 2011 to May 2012. The concentrations of OC, EC, and BC exhibit seasonal variability, and their concentrations were ~2 times higher during winter (OC 38.1?±?17.9 μg m?3, EC 15.8?±?7.3 μg m?3, and BC 10.1?±?5.3 μg m?3) compared to those in summer (OC 14.1?±?4.3 μg m?3, EC 7.5?±?1.5 μg m?3, and BC 4.9?±?1.5 μg m?3). A significant correlation between OC and EC (R?=?0.95, n?=?232) indicate their common emission sources with relatively lower OC/EC ratio (range 1.0–3.6, mean 2.2?±?0.5) suggests fossil fuel emission as a major source of carbonaceous aerosols over the station. On average, mass concentration of EC was found to be ~38 % higher than BC during the study period. The measured absorption coefficient (babs) was significantly correlated with EC, suggesting EC as a major absorbing species in ambient aerosols at Delhi. Furthermore, the estimated mass absorption efficiency (σabs) values are similar during winter (5.0?±?1.5 m2 g?1) and summer (4.8?±?2.8 m2 g?1). Significantly high aerosol loading of carbonaceous species emphasize an urgent need to focus on air quality management and proper impact assessment on health perspective in these regions. 相似文献
6.
Elavarasan Rajvikram Madurai Pugazhendhi Rishi Shafiullah G. M. Kumar Nallapaneni Manoj Arif Mohammad Taufiqul Jamal Taskin Chopra Shauhrat Singh Dyduch Joanna 《Environmental science and pollution research international》2022,29(23):33957-33987
Environmental Science and Pollution Research - In the pursuit of constructing a sustainable world for all through the instrumental seventeen Sustainable Development Goals, the COVID-19 pandemic... 相似文献
7.
Khan Syed Abdul Rehman Mathew Manoj Dominic P. D. D. Umar Muhammad 《Environment, Development and Sustainability》2022,24(9):10633-10665
Environment, Development and Sustainability - Environmental deterioration and global warming has created a substantial impact on international companies to incorporate eco-friendly, green supply... 相似文献
8.
Rahul Jain Makkhan Lal Meena Manoj Kumar Sain Govind Sharan Dangayach 《International journal of occupational safety and ergonomics》2019,25(4):614-620
Purpose. The current research was carried out to determine grip strength (GS) with change in posture and upper-limb muscle activity of manual workers and investigate the impacts of these changes. Methods. For the current research, 120 male and 80 female participants were selected and GS was assessed using a digital hand grip dynamometer in various conditions. Results. The outcomes showed that male participants had higher GS as compared to female participants. Maximum GS was found in a standing posture with the fixed forward shoulder at 45°, elbow at 90° and a neutral position of the wrist and forearm for all participants. Conclusions. Higher values of GS were attained in standing postures which may result in attainment of higher performance levels by the workers. The outcomes justify the importance of correct postures during manual work in industries employing traditional methods. 相似文献
9.
Manoj Roy Robin Curry Geraint Ellis 《Journal of Environmental Planning and Management》2015,58(10):1749-1769
Studies of urban metabolism provide important insights for environmental management of cities, but are not widely used in planning practice due to a mismatch of data scale and coverage. This paper introduces the Spatial Allocation of Material Flow Analysis (SAMFA) model as a potential decision support tool aimed as a contribution to overcome some of these difficulties and describes its pilot use at the county level in the Republic of Ireland. The results suggest that SAMFA is capable of identifying hotspots of higher material and energy use to support targeted planning initiatives, while its ability to visualise different policy scenarios supports more effective multi-stakeholder engagement. The paper evaluates this pilot use and sets out how this model can act as an analytical platform for the industrial ecology–spatial planning nexus. 相似文献
10.
Jyothi S. Menon 《Journal of the Air & Waste Management Association (1995)》2018,68(5):415-429
In the present study, personal exposure to fine particulate matter (particulate matter with an aerodynamic diameter <2.5 μm [PM2.5]) concentrations in an urban hotspot (central business district [CBD]) was investigated. The PM monitoring campaigns were carried out at an urban hotspot from June to October 2015. The personal exposure monitoring was performed during three different time periods, i.e., morning (8 a.m.?9 a.m.), afternoon (12.30 p.m.–1.30 p.m.), and evening (4 p.m.–5 p.m.), to cover both the peak and lean hour activities of the CBD. The median PM2.5 concentrations were 38.1, 34.9, and 40.4 µg/m3 during the morning, afternoon, and evening hours on the weekends. During weekdays, the median PM2.5 concentrations were 59.5, 29.6, and 36.6 µg/m3 in the morning, afternoon, and evening hours, respectively. It was observed that the combined effect of traffic emissions, complex land use, and micrometeorological conditions created localized air pollution hotspots. Furthermore, the total PM2.5 lung dose levels for an exposure duration of 1 hr were 8.7 ± 5.7 and 12.3 ± 5.2 µg at CBD during weekends and weekdays, respectively, as compared with 2.5 ± 0.8 µg at the urban background (UB). This study emphasizes the need for mobile measurement for short-term personal exposure assessment complementing the fixed air quality monitoring.Implications: Personal exposure monitoring at an urban hotspot indicated space and time variation in PM concentrations that is not captured by the fixed air quality monitoring networks. The short-term exposure to higher concentrations can have a significant impact on health that need to be considered for the health risk–based air quality management. The study emphasizes the need of hotspot-based monitoring complementing the already existing fixed air quality monitoring in urban areas. The personal exposure patterns at hotspots can provide additional insight into sustainable urban planning. 相似文献