The Monitoring and Risk Assessment of Zn Deposition Around a Metal Smelter in Latvia

Heavy metal concentrations in Hylocomium splendens collected around a metal smelter in Latvia showed very high concentrations of Zn (>200 g/g), and elevated concentrations of Pb (38.3 g/g) and Cu (18.3 g/g). In an attempt to better evaluate the potential toxicity of the high Zn concentrations, a serial elution method was used to determine the concentrations of zinc in intercellular, extracellular exchangeable cell wall, intracellular, and particle fractions. The intercellular Zn concentrations represent the water soluble component of the total concentrations, and were low with no clear trends. Zn concentrations in the extra- and intracellular and particle fractions decreased exponentially from the pollutant source. Intracellular Zn concentrations in moss close to the emission source are within the range considered to be potentially toxic, from other single element exposure studies. The proportion of Zn in the relatively insoluble particle fraction, which is least associated with environmental risk, was greater closer to the pollution source, reaching > 30% in the oldest Hylocomium splendens segments.     

Polychlorinated dibenzo-p-dioxins/furans and dioxin-like polychlorinated biphenyls in food and feed in the Lithuanian market

Foods and feeds were analyzed during the period of 2007–2014 employing validated and accredited methods based on gas chromatography–high-resolution mass spectrometry. Sampling has been carried out in-line with national monitoring programs as well as during import controls into Lithuania. Food samples such as eggs, milk, beef, pork, poultry, fats of plant and animal origin, fish, cod liver, and feed samples such as premixes, feeds of plant origin, compound feed, mineral feed, vegetable oil, and fish meals were analyzed. Most of the samples exhibited concentrations below maximum limits, except cod liver. Health impacts were assessed in respect to human daily intakes. Data between groups are compared.     

Acute and Chronic Toxicity of Chlorine Dioxide (ClO2) and Chlorite (ClO2ˉ) to Rainbow Trout (Oncorhynchus mykiss) (4 pp)

Goal, Scope and Background Chlorite (ClO2ˉ) is a primary decomposition product when chlorine dioxide (ClO2) is added during water treatment; therefore the toxic effects of both compounds on aquatic organisms are possible. Limited data are available concerning their toxicity to fish. The aim of this study was to investigate sensitivity of rainbow trout to acute and chronic toxicity of chlorine dioxide and chlorite, and to estimate the Maximum-Acceptable-Toxicant-Concentration (MATC) of those compounds in fish. Methods The acute and chronic toxicity of chlorine dioxide and chlorite to larval and adult rainbow trout was investigated in 96-hour to 20-day laboratory exposures evaluating the wide range spectrum of biological indices under semi-static conditions. Results and Discussion Median lethal concentration (96-hour LC50) values derived from the tests were: 2.2 mg/l for larvae; 8.3 mg/l for adult fish and 20-day LC50 for larvae was 1.6 mg/l of chlorine dioxide, respectively. Chlorite was found to be from 48 to 18 times less acutely toxic to larvae and adult fish, correspondingly. Both chemical compounds induced similar toxic effects in rainbow trout larvae during chronic tests (they affected cardio-respiratory and growth parameters), but chlorine dioxide had a higher toxic potency than chlorite. A significant decrease in the heart rate and respiration frequency of larvae was established. However, within an increase in exposure duration recovery of cardio-respiratory responses was seen to have occurred in larvae exposed to chlorite. Meanwhile, in larvae exposed to chlorine dioxide, a significant decrease in cardio-respiratory responses remained during all 20-day chronic bioassays. Chlorine dioxide also more strongly affected growth parameters of rainbow trout larvae at much lower test concentrations. Decreased rate of yolk-sack resorption occurred only in the tests with chlorine dioxide. Conclusions Maximum-Acceptable-Toxicant-Concentration (MATC) of 0.21 mg/l for chlorine dioxide and of 3.3 mg/l for chlorite to fish was derived from chronic tests based on the most sensitive parameter of rainbow trout larvae (growth rate). According to substance toxicity classification accepted for Lithuanian inland waters, chlorine dioxide and chlorite can be referred to substances of \moderate\ toxicity to fish. Recommendations and Outlook Due to its very reactive nature, chlorine dioxide is rapidly (in a few hours) reduced to chlorite, which is persistent also as a biocide but 16 times less toxic to fish, according to MATC. Therefore, it is much more likely that fish will be exposed to chlorite than to chlorine dioxide in natural waters. Presently accepted, the Maximum-Permitted-Concentration of total residual chlorine (TRC) in waste-water discharging into receiving waters is 0.6 mg/l. If this requirement will not be exceeded, it is unlikely that fish would be exposed to lethal or even to sublethal concentrations of chlorine dioxide or chlorite. Furthermore, chlorine dioxide does not generate toxic nitrogenous (chloramines) or carcinogenic organic residuals (trihalomethanes). All these properties make chlorine dioxide a more promising biocide than chlorine.     

Modelling of a Capillary Rise Height of Biochar by Modified Lucas–Washburn Equation

Environmental Modeling & Assessment - Lucas–Washburn equation is a fundamental expression which is used to describe capillary rise in porous materials according to average pore radius,...     

Integrated shoreline management and tourism development on the cross-border World Heritage Site: A case study from the Curonian spit (Lithuania/Russia)

The varied and very dynamic landscape with a high biological diversity is a distinctive feature of the Curonian spit at the regional scale. Throughout the 20th century the main morphodynamic trend in the littoral of the Curonian spit was shoreline grading on the lagoon side, whereas on the marine side the increasing erosion at the foot of the spit, and increasing accretion at the head of the spit prevailed. The results of a discriminant analysis (Wilkes’ λ = 0.001626 and F = 29.267 when p < 0.001) show that sites with prevailing erosion, accretion and sediment input from the drifting dunes form regular inter-related spatial structures in the littoral with distinctive resulting discontinuities of the sediment drift along the lagoon coast. Dune littoral cells are characterized by Aeolian sediment input and distribution ‘down-drift’, (usually northwards) from the source. The most likely changes in the current development trends of the lagoon shore zone of the Curonian spit are related to expected climate changes and further slowing down of the dune drift. The probability of storms and ice-drift events, and their impact on coasts is expected to increase as a result of climate change. The dune advance will gradually slow down, and with it, the sand input to the coastal zone will decline. In this paper, we define integrated shoreline management as a system of long-term shoreline management measures, which is based on a littoral cell approach and aimed at harmonizing human activity in the coastal zone with the natural development of the shoreline. We propose an integrated management program for the lagoon shoreline of the Curonian spit, which is site-specific for each littoral cell as a coastal management unit. Drifting dunes and seaside beaches are the natural amenities, which are best known and best appreciated on the Curonian spit by 49% of the respondents representing the total Lithuanian population. A responsible tourism development should be considered as the key means for proper appreciation of the drifting dunes and natural coasts by society, which means to acknowledge and cherish the aesthetic and conservation values of dune and coastal landscapes of the Curonian spit as a World Heritage Site. There are at least two pre-conditions for this: (1) to provide visitors with sufficient information about diverse values and functions of the Curonian dunes and coasts within a broader regional and global heritage conservation context; (2) to enable tourists to enjoy the most impressive dune and coastal landscapes at close range. In this paper we propose to encourage active dune tourism, to reintroduce grazing into the Curonian dune areas, to restore and to preserve the most impressive landscapes of the highest white drifting dunes by bringing the blown out sand from the leeward foot of the dunes back to the crest artificially.     

The degradation of cyanide by anodic electrooxidation using different anode materials

Cyanides are very popular electrolytes used in metal electroplating, metal ore processing, chemical and electrochemical applications. Due to wide utility of these technologies cyanides become increasingly harmful effluent, which has to be treated. One of the best ways to degrade cyanides is an anodic electrooxidation. In this work the destruction of free cyanide on platinum, titanium and stainless steel (SS) electrodes has been investigated. It was determined that anode material greatly influences the process of cyanide electrooxidation. The best results were obtained by using the Pt electrode. This kind of anode allows us to reduce CN^? concentration from 0.1 M to 0.06 M during the first hour of electrolysis at a current density of 200 A m^?2, with a current efficiency up to 80%. To substitute expensive Pt anodes Ti electrodes covered with nanolayers of Pt were prepared and used for the anodic oxidation of cyanide ions. An effect of a thickness of Pt layer and temperature of an electrolyte solution were studied. It was established that using platinized Ti electrodes the current efficiencies of electrooxidation of cyanides of about 60% can be obtained. The usage of chloride ions to facilitate the destruction of cyanide was also studied.     

Epiphytic lichen community dynamics in deciduous forests around a phosphorus fertiliser factory in Central Lithuania

The detailed dynamics of epiphytic lichen communities were observed while studying permanent quadrats in the zone of influence of a phosphorus fertiliser factory in central Lithuania. The most significant changes were induced by several factors: changes in macroenvironment (increase of illumination), bark scaling, succession processes, individual growth characteristics of the community members, and influence of fungal infection and invertebrate grazing. None of these changes could be directly linked with air pollution. These observations have shown that in conditions of more or less stable pollution, epiphytic community dynamics should be evaluated with care, the best indicators of the characteristics of the communities being species richness and presence/absence and abundance of indicator (nitrophilous or acidophilous) species.     

Assessing coastal management case studies around Europe using an indicator based tool

Over 350 European Integrated Coastal Zone Management (ICZM) ‘best practice’ case studies are documented in the OURCOAST online public database, to ensure that lessons learned from experiences and practices are shared and improve coastal management practices. However, concrete criteria for ‘best practice’ are missing and a critical evaluation of the success of these case studies did not take place. We present an indicator-based tool and methodology that allows assessing the progress towards sustainability of ICZM measures. An indicator-based tool was applied to 18 thematically different coastal case studies using two different methods: a fast screening and an analysis in-depth assessment. Both methods used help to identify strengths and weaknesses of ICZM and their contribution to sustainable development. However, indicator scores were highly affected by evaluators’ background and perception. The tool is user-friendly and easy to apply, it indicates what progress has made towards sustainability and to which extent targets have been met.     

Retrospective analysis of spatial and temporal variability of chlorophyll-a in the Curonian Lagoon

The Curonian Lagoon, the largest in Europe (total surface area 1584?km²), is located in the southern part of the Baltic Sea, from which it is separated by a narrow sand bar and to which it is connected by the Klaipeda Straits. It is characterised by shallow eutrophic waters (mean depth 3.8?m) with average low salinity (<5??) due to the nutrient-rich freshwaters discharged by the river Nemunas. Cyanobacteria blooms, including species producing toxic metabolites, have been a frequent phenomenon in summer. In this study a series of MERIS Full Resolution (FR) satellite images acquired between 2004 and 2009 during summer periods were used to assess the temporal evolution and spatial variability of the lagoon water quality in terms of chlorophyll-a. The models/algorithms were calibrated/validated with field data collected in 2009, based on in situ radiometric (remote sensing reflectance -Rrs-) and limnological (chlorophyll-a concentrations -chl-a-) measurements. The chl-a concentrations were estimated by developing a semi-empirical band ratio (Rrs(708)/Rrs(664)) equation applied to MERIS images after correction for atmospheric effects with the 6S code. Results from this study suggest elevated spatial and temporal variability of chl-a. Spatial variability probably arises from the mosaic of situations within the Curonian lagoon in terms of bottom sediment features, nutrient availability in the water column, water depth and hydrodynamics. Temporal variability is probably linked to complex and interplaying metereological and environmental constraints such as the length of the ice cover period, average water temperatures, wind-induced sediment re-suspension, the pattern of precipitations and river-associated nutrient transport to the lagoon. This study stresses the importance of remote sensing as a valid tool for long-term whole ecosystem studies. The preliminary results need more through analyses and intersection with other environmental data in order to better comprehend algal bloom determinants in complex and extremely dynamic systems such as coastal lagoons.