Use of activated dry flowers (ADF) of Alstonia Scholaris for chromium (Vl) removal: equilibrium, kinetics and thermodynamics studies

In this study, a natural adsorbent (activated dry flowers (ADF)) was prepared from plant-derived waste biomass by chemical activation and employed for chromium (VI) removal from aqueous medium using experimental batch technique. Experiments were carried out as function of adsorbent dosage, pH, and contact time. The maximum chromium (Vl) removal was observed at initial pH 3 (~94 % removal). The equilibrium data was fitted well to Langmuir isotherm. The adsorption capacity of ADF was found to be 4.40 (mg chromium (Vl)/g) which was comparable to the adsorption capacity of some other adsorbents documented. Among various kinetic models applied, pseudo second-order model was found to explain the kinetics of chromium (VI) adsorption most effectively (R ² >0.99). Thermodynamic parameters such as ΔG, ΔS, and ΔH shows that adsorption process was spontaneous and endothermic at all the concentration ranges studied. Desorption of chromium (Vl) with 2 N NaOH was effective (~71 %) and, hence, there exists the possibility of recycling the ADF. The major advantages of using ADF as an adsorbent are due to its effectiveness in reducing the concentration of chromium (Vl) to very low levels. It requires little processing and is reversible as well as eco-friendly in contrast to traditional methods.     

生活在土地上的人们:20世纪全球人口和耕地的变化

本研究评述了20世纪全球耕地分布发生的主要变化.在20世纪,耕地基数大幅度减小,人均耕地从1900年的0.75hm2/人下降到1990年的0.35 hm2/人.     

ARSENIC IN THE SHALLOW GROUND WATERS OF CONTERMINOUS UNITED STATES: ASSESSMENT,HEALTH RISKS,AND COSTS FOR MCL COMPLIANCE1

A methodology consisting of ordinal logistic regression (OLR) is used to predict the probability of occurrence of arsenic concentrations in different threshold limits in shallow ground waters of the conterminous United States (CONUS) subject to a set of influencing variables. The analysis considered a number of maximum contaminant level (MCL) options as threshold values to estimate the probabilities of occurrence of arsenic in ranges defined by a given MCL of 3, 5, 10, 20, and 50 μg/l and a detection limit of 1 μg/l. The fit between the observed and predicted probability of occurrence was around 83 percent for all MCL options. The estimated probabilities were used to estimate the median background concentration of arsenic in the CONUS. The shallow ground water of the western United States is more vulnerable than the eastern United States. Arizona, Utah, Nevada, and California in particular are hotspots for arsenic contamination. The risk assessment showed that counties in southern California, Arizona, Florida, and Washington and a few others scattered throughout the CONUS face a high risk from arsenic exposure through untreated ground water consumption. A simple cost effectiveness analysis was performed to understand the household costs for MCL compliance in using arsenic contaminated ground water. The results showed that the current MCL of 10 μg/l is a good compromise based on existing treatment technologies.     

Sustainability of ground water quality considering land use changes and public health risks

One of the major environmental issues of concern to policy-makers is the increased vulnerability of ground water quality (GWQ). Another issue of equal interest is the sustainability of natural resources for future generations. To understand the sustainability of the natural resources such as water in general, one needs to understand the impact of future land use changes on the natural resources. This work proposes a methodology to address sustainability of GWQ considering land use changes, aquifer vulnerability to multiple contaminants, and public health risks. The methodology was demonstrated for the Sumas-Blaine aquifer in Washington State. The land transformation model predicted that nearly 60 percent of the land use practices would change in the Sumas-Blaine Aquifer by the year 2015. The accuracy of the LTM model predictions increased to greater levels as the spatial resolution was decreased. Aquifer vulnerability analysis was performed for major contaminants using the binary logistic regression (LR) method. The LR model, along with the predicted future land use, was used to estimate the future GWQ using two indices-carcinogenic and non-carcinogenic ground water qualities. Sustainability of GWQ was then analyzed using the concept of 'strong' sustainability. The sustainability map of GWQ showed improvements in many areas where urbanization is expected to occur. The positive impact of urbanization on GWQ is an indication of the extensive damage caused by existing agricultural activities in the study area.     

Anaerobic ammonia-oxidizing bacteria in tropical bioaugmented zero water exchange aquaculture ponds

Environmental Science and Pollution Research - Bioaugmented zero water exchange aquaculture production systems (ZWEAPS) maintained with minimal or no water exchange prevent the ammonia accumulation...     

Coal fly ash utilization: low temperature sintering of wall tiles

We present here a study of the sintering of fly ash and its mixture with low alkali pyrophyllite in the presence of sodium hexa meta phosphate (SHMP), a complex activator of sintering, for the purpose of wall tile manufacturing. The sintering of fly ash with SHMP in the temperature range 925-1050 degrees C produces tiles with low impact strength; however, the incremental addition of low alkali pyrophyllite improves impact strength. The impact strength of composites with 40% (w/w) pyrophyllite in the fly ash-pyrophyllite mix satisfies the acceptable limit (19.6J/m) set by the Indian Standards Institute for wall tiles. Increasing the pyrophyllite content results in an increase in the apparent density of tiles, while shrinkage and water absorption decrease. The strength of fly ash tiles is attributed to the formation of a silicophosphate phase; in pyrophyllite rich tiles, it is attributed to the formation of a tridymite-structured T-AlPO(4) phase. Scanning electron micrographs show that the reinforcing rod shaped T-AlPO(4) crystals become more prominent as the pyrophyllite content increases in the sintered tiles.     

Population dynamics of vibrio species in the river Narmada at Jabalpur

Several studies on the presence and ecology of various Vibrio sp have been reported in coastal and estuarine waters throughout the world, but there is trifling information available on the distribution of this organism of colossal pathogenic potential in the fresh water riverine environment. Thus, we conducted a multiyearenvironmental study to scrutinize the occurrence of members of genus Vibrio in the largest west flowing river of the Indian subcontinent, which is also the largest river of central India, the Narmada. Statistical analysis was done to reveal major environmental factors controlling the presence of Vibrio sp in the river Narmada. Monthly field samplings were conducted between January 2002 and December 2003 at four different sites in Jabalpur (MP), India. At each site, water samples were taken and physicochemical and bacteriological parameters were measured. The identity of the isolates was confirmed by employing 16S rRNA analysis. The organisms were found to be widely distributed in the river with regular seasonal variations. The density of Vibrio was found to be correlated with temperature, coliforms and other heterotrophic bacteria. Water temperature accounted for most of the variability in the concentration of Vibrio spAs typical fecal pollution indicators may not access public health risk from potential pathogens such as vibrios, hence special monitoring programme for vibrios may adequately be included in the water quality management.     

People on the land: changes in global population and croplands during the 20th century

This study reviews the major changes in global distribution of croplands during the 20th century. During the 20th century, the cropland base diminished greatly (from approximately 0.75 ha person-1 in 1900 to approximately 0.35 ha person-1 in 1990). This loss of croplands was not globally uniform: more than half the world's population, living in developing nations, lost nearly two-thirds of their per capita cropland base. The distribution of croplands has become increasingly skewed--in 1990, 80% of the population lived off less than 0.35 ha person-1. While agricultural yields have generally increased, they have barely kept pace with population growth in developing nations. Overall, the global food production system is becoming increasingly vulnerable to regional disruptions because of our increasing reliance on expensive technological options to increase agricultural production, or on global food trade.