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The ability of bentonite to remove malachite green from aqueous solutions has been studied for different adsorbate concentrations by varying the amount of adsorbent, temperature, pH and shaking time. Maximum adsorption of the dye, i.e. >90% has been achieved in aqueous solutions using 0.05 g of bentonite at a pH of 9. Thermodynamic parameters such as ΔH°, ΔS° and ΔG° were calculated from the slope and intercept of the linear plots of ln KD against 1/T. Analysis of adsorption results obtained at 298, 308, 318 and 328 K showed that the adsorption pattern on bentonite seems to follow the Langmuir, Freundlih and D–R isotherms. The temperature increase reduces adsorption capacity by bentonite, due to the enhancement of the desorption step in the mechanism. The numerical values of sorption free energy (Ea) of 1.00–1.12 kJ mol−1 indicated physical adsorption. The kinetic data indicated an intraparticle diffusion process with sorption being first order. The rate constant k was 0.526 min−1. The concentration of malachite green oxalate was measured before and after adsorption by using UV–Vis spectrophotometer. 相似文献
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Akhter Faheem Jamali Abdul Rauf Abbasi Mahmood Nabi Mallah Mukhtiar Ali Rao Ahsan Atta Wahocho Shafeeque Ahmed Anees-ur-Rehman Hafiz Chandio Zubair Ahmed 《Environmental science and pollution research international》2023,30(5):11226-11245
Environmental Science and Pollution Research - The hydrophobicity of silica and composite aerogels has enabled them to acquire applications in a variety of fields. With remarkable structural,... 相似文献
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Ananga M Chandra Suhana Ghosh Rauf Iqbal Nachiketa Sadhu 《International journal of occupational safety and ergonomics》2007,13(3):271-278
An ergonomic assessment of the involvement of static muscular forces like back strength, grip strength and pinch strength in different occupations was made. A study was conducted on 45 normal adult males (15 subjects per group) which included video display terminal (VDT) operators, industrial workers and safety inspectors. Their maximum back strength, handgrip strength and pinch strength were measured with dynamometers. The observed values of back strength were significantly lower in VDT operators while significantly higher in safety inspectors and moderate in industrial workers. The values of grip strength and pinch strength of all sample groups were more or less similar. The findings clearly indicate that static muscular strength varies significantly in different occupations. Heavy static muscular load might lead to an accumulation of metabolic waste and toxins on the back resulting in lower back strength in VDT operators and industrial workers. 相似文献
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Rehman Abdul Ma Hengyun Ozturk Ilhan Ahmad Munir Rauf Abdul Irfan Muhammad 《Environmental science and pollution research international》2021,28(26):33735-33750
Environmental Science and Pollution Research - The present study seeks to investigate the sector-level energy consumption of oil and natural gas and to explore the linkage between economic growth,... 相似文献
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Rauf Abdur Shariati Mohammad Ali Imran Muhammad Bashir Kashif Khan Shahid Ali Mitra Saikat Emran Talha Bin Badalova Kamala Uddin Md. Sahab Mubarak Mohammad S. Aljohani Abdullah S. M. Alhumaydhi Fahad A. Derkho Marina Korpayev Serdar Zengin Gokhan 《Environmental science and pollution research international》2022,29(21):31025-31041
Environmental Science and Pollution Research - Though the incidence of several cancers in Western societies is regulated wisely, some cancers such as breast, lung, and colorectal cancer are... 相似文献
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Manzoor Maria Gul Iram Manzoor Aamir Kamboh Usman Rauf Hina Kiran Kallerhoff Jean Arshad Muhammad 《Environmental science and pollution research international》2020,27(32):39753-39762
Environmental Science and Pollution Research - Availability of lead (Pb) in soil is a major factor controlling the phytoremediation efficiency of plants. This study was focused on investigating the... 相似文献
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Ahmad Munir Ahmed Naseer Jabeen Maria Jabeen Gul Qamar Shoaib Chandio Abbas Ali Rehman Abdul Rauf Abdul 《Environmental science and pollution research international》2020,27(31):38937-38950
Environmental Science and Pollution Research - This study investigates the heterogeneous causal linkages between urbanization, the intensity of electric power consumption, water-based pollutant... 相似文献
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Bentonite clay has been used for the adsorption of Fe(II) from aqueous solutions over a concentration range of 80-200 mg/l, shaking time of 1-60 min, adsorbent dosage from 0.02 to 2 g and pH of 3. The process of uptake follows both the Langmuir and Freundlich isotherm models and also the first-order kinetics. The maximum removal (>98%) was observed at pH of 3 with initial concentration of 100 mg/l and 0.5 g of bentonite. The efficiency of Fe(II) removal was also tested using wastewater from a galvanized pipe manufacturing industry. More than 90% of Fe(II) can be effectively removed from the wastewater by using 2.0 g of the bentonite. The effect of cations (i.e. zinc, manganese, lead, cadmium, nickel, cobalt, chromium and copper) on the removal of Fe(II) was studied in the concentration range of 10-500 mg/l. All the added cations reduced the adsorption of Fe(II) at high concentrations except Zn. Column studies have also been carried out using a certain concentration of wastewater. More than 99% recovery has been achieved by using 5 g of the bentonite with 3M nitric acid solution. 相似文献