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1.
Determination of ammonium on an integrated microchip with LED-induced fluorescence detection 总被引:1,自引:0,他引:1
A simply fabricated microfluidic device integrated with a fluorescence detection system has been developed for on-line determination of ammonium in aqueous samples. A 365-nm light-emitting diode (LED) as an excitation source and a minor band pass filter were mounted into a polydimethylsiloxane (PDMS)-based microchip for the purpose of miniaturization of the entire analytical system. The ammonium sample reacted with o-phthaldialdehyde (OPA) on-chip with sodium sulfite as reducing reagent to produce a fluorescent isoindole derivative, which can emit fluorescence signal at about 425 nm when excited at 365 nm. Effects of pH, flow rate of solutions, concentrations of OPA-reagent, phosphate and sulfite salt were investigated. The calibration curve of ammonium in the range of 0.018-1.8 μupg/mL showed a good linear relationship with R2 = 0.9985, and the detection limit was (S/N = 3) 3.6 × 10-4 μupg/mL. The relative standard deviation was 2.8% (n = 11) by calculating at 0.18 μupg/mL ammonium for repeated detection. The system was applied to determine the ammonium concentration in rain and river waters, even extent to other analytes fluorescence detection by the presented device. 相似文献
2.
The present levels of anthropogenic radionuclides, 137Cs and (239,240)Pu, in surface waters of the Pacific are estimated using the HAM database, which is a comprehensive data set of 137Cs, (239,240)Pu and other anthropogenic radionuclides. The time-series data of surface 137Cs and (239,240)Pu suggests that surface 137Cs and (239,240)Pu concentrations in the Pacific since 1971 decrease exponentially in each sea area, although the temporal changes of surface 137Cs and (239,240)Pu differed between sea areas of the Pacific. The calculated 137Cs concentrations in the Pacific surface waters in 2000 are homogeneous in the Pacific, comparing with that in the 1960s and 1970s, although they are still high in the North Pacific and low in the South Pacific. The biogeochemical and physical processes are significant factors to control present levels of surface (239,240)Pu concentrations, which are high in the Subarctic and equatorial Pacific and low in the mid-latitude region of the eastern North Pacific. 相似文献
3.
Urban horticulture, defined as plant production activities that are conducted in a city or suburb that produce horticultural plants that are wholly or partially edible, and which are economically viable, has the potential to reduce CO2 emissions caused by the transportation of produce. Moreover, to increase productivity in limited areas and use limited resources effectively, closed or semi-closed systems (i.e., greenhouses) are considered more advantageous than open systems (i.e., fields) from which resources can easily escape into the surrounding environment. In this paper the significance of urban horticulture in reducing CO2 emissions in the transportation process is discussed with reference to simple case studies. In the context of building or rebuilding greenhouses suitable for urban horticulture, the present situation regarding resource inputs and outputs in greenhouses is compared to that in open fields. The reduction of resource inputs and outputs in greenhouse production is also discussed. 相似文献
4.
5.
Michael J. Miller Sam Wouthuyzen Gen Minagawa Jun Aoyama Katsumi Tsukamoto 《Marine Biology》2006,148(5):1101-1111
A survey for leptocephali around Sulawesi Island in the central Indonesian Seas during May 2001 found that the leptocephali
of the congrid eel, Ariosoma scheelei, were present in all seven areas that were sampled. A total of 551 leptocephali (22–166 mm TL) were collected, and A. scheelei was by far the most abundant species of leptocephali collected during the survey. The wide range of sizes in most areas indicated
that spawning had occurred during a period of several months in many different areas, although the exact spawning locations
were not determined. The larger size classes were more abundant in all areas except in Tomini Bay on the northeast side of
Sulawesi Island. The highest catch rates were observed at the eastern edge of the Java Sea and to the north in the Celebes
Sea near Makassar Strait. Premetamorphic leptocephali were also collected in surface samples at 11 stations (N=62), but metamorphosing leptocephali (N=86) were only caught in IKMT tows that fished from the surface to about 200 m. Metamorphosing leptocephali were collected
primarily at two stations in the Java Sea and Makassar Strait where a surface layer of lower-salinity water was detected.
Their total lengths (105.3–153.3 mm) and the largest premetamorphic individuals suggested that this species can reach maximum
sizes of about 165 mm before beginning to metamorphose. It is hypothesized that this species may be abundant in the Indonesian
Seas region and that it has ecological traits such as large size at recruitment and a small size at reproduction that have
made it successful in many regions of the Indo-Pacific. 相似文献
6.
Ryunosuke Uchiyama Hiroshi Okochi Hiroko Ogata Naoya Katsumi Daisuke Asai Takanori Nakano 《Environmental Chemistry Letters》2017,15(4):739-745
Stable isotope ratios of hydrogen and oxygen of water are useful tracers of the hydrological cycle. For example, isotopes monitor the evapotranspiration in vegetated areas, local snow ice processes and stream water flow processes. δ18O and δD in rainwater reflect the processes of evaporation, condensation and precipitation. Heavy rains thus modify the stable isotope ratio of ground water, stream water and transpiration water vapor. However, the controlling factors of δ18O and δD are not clear. Here we analyzed the inorganic ion concentration and stable isotope ratio in 38 normal rainwater and 15 heavy rainwater samples were collected in Shinjuku, Tokyo, Japan, during four years from October 2012 to December 2015. Results show a decrease in δ18O and δD values with the total rainfall amount, thus highlighting the amount effect. δ18O and δD volume-weighted mean values in typhoon heavy rain were higher than the values estimated from amount effect, whereas δ18O and δD volume-weighted mean values in urban-induced heavy rain were lower. Typhoon heavy rain has high Na+ ratio and stable isotope ratios, while urban-induced heavy rain has low Na+ ratio and stable isotope ratio. 相似文献
7.
Positive buoyancy in eel leptocephali: an adaptation for life in the ocean surface layer 总被引:1,自引:0,他引:1
Katsumi Tsukamoto Yoshiaki Yamada Akihiro Okamura Toyoji Kaneko Hideki Tanaka Michael J. Miller Noriyuki Horie Naomi Mikawa Tomoko Utoh Satoru Tanaka 《Marine Biology》2009,156(5):835-846
Many planktonic organisms have adaptations such as floats or lighter substances to obtain buoyancy to help them remain in
the surface layer of the ocean where photosynthetic primary production occurs and food is most abundant. The almost totally
transparent eel larvae, called leptocephali, are a unique member of the planktonic community of the surface layer, but their
ecology and physiology are poorly understood. We conducted a comparative study on the specific gravity of planktonic animals
including 25 taxa of 7 phyla of marine invertebrates and 6 taxa of leptocephali (vertebrate) to gain a broad perspective on
the buoyancy of the eggs and larval stages of the Japanese eel. The specific gravity values of the various freshly caught
marine invertebrate taxa varied widely from 1.020 to 1.425, but leptocephali had some of the lowest values (1.028–1.043).
Artificially cultured live leptocephali had even greater buoyancies with specific gravities of 1.019–1.025 that were close
to or lower than seawater, and their buoyancy showed ontogenetic changes among the different early life history stages. Leptocephali
appear to have a unique mechanism of buoyancy control by chloride cells all over body surface through osmoregulation of body
fluid contained in the extracellular matrix of transparent gelatinous glycosaminoglycans filling their bodies. This adaptation
is likely a key factor for their survival by helping them to remain in the surface layer where food particles are the most
abundant, while being transparent for predator avoidance. The ontogenetic change in buoyancy of eel eggs, leptocephali and
glass eels likely enhances their larval survival, transport, and recruitment to terrestrial freshwater habitats. 相似文献
8.
Rumi Chan Eiko Obuchi Katsumi Katoh Hom Nath Luitel Katsuyuki Nakano 《环境科学学报(英文版)》2013,25(7):1419-1423
TiO2 immobilized on SiO2 (TiO2/SiO2) have been prepared by sol-gel method and various ions of transition metals (Cr3+, Co2+, Ni2+, Cu2+, and Zn2+) were doped on the photocatalyst using wet impregnation method under reducing calcination atmosphere. The photocatalytic activity of metal doped TiO2/SiO2 towards phenol degradation under black light irradiation were investigated and compared with undoped TiO2/SiO2. The results showed that the photoresponse of Cu2+ and Zn2+ doped TiO2/SiO2 were larger than undoped TiO2/SiO2, indicating that the photogenerated carriers were separated more efficiently in Cu2+ and Zn2+ doped TiO2/SiO2. The reactivity was in the order of Cu2+ > Zn2+ > Ni2+ > Cr3+ > Co2+. The different photoreactivity was ascribed to combine effect of the different ionic radii and photocorrison tendency of the dopants. The sample was also characterized by surface analytical methods such as X-ray diffraction, scanning electron micrograph/electron dispersive X-ray analyzer and UV-Vis absorption spectrum. 相似文献
9.
Inomata Y Igarashi Y Chiba M Aoyama M Hirose K 《Journal of environmental monitoring : JEM》2008,10(7):837-841
We estimated the return period of an increased gamma ray dose rate (Delta gamma) derived from (222)Rn progeny deposited with precipitation. The approximate probability distribution for Delta gamma followed a Hazen plot, which is an empirical plotting equation, indicating that the distribution of Delta gamma was approximated by a nearly double-exponential. The distribution of Delta gamma was well represented by the Gumbel distribution, and the return period for Delta gamma was estimated theoretically. There was a notable regional difference in the return period between the coast of the Japan Sea and the inland or Pacific coast areas: the return period for a given Delta gamma at monitoring sites on the Sea of Japan coast was 1.5 to 2.5 times shorter than that in the inland or Pacific coast areas. This variation with locality suggests that the rate of wet-deposition of (222)Rn progeny is larger at sites on the Sea of Japan coast than inland or on the Pacific coast areas. The expected return period for the maximum Delta gamma at each site was about 10 years. This estimation of the return period of Delta gamma is a novel approach to the study of environmental science in fields such as radioactivity. 相似文献
10.
We simulated the spatial distributions and the temporal variations of 137Cs and (239,240)Pu concentrations in the ocean by using the ocean general circulation model which was developed by National Center of Atmospheric Research. These nuclides are introduced into seawaters from global fallout due to atmospheric nuclear weapons tests. The distribution of radioactive deposition on the world ocean is estimated from global precipitation data and observed values of annual deposition of radionuclides at the Meteorological Research Institute in Japan and several observed points in New Zealand. Radionuclides from global fallout have been transported by advection, diffusion and scavenging, and this concentration reduces by radioactive decay in the ocean. We verified the results of the model calculations by comparing simulated values of 137Cs and (239,240)Pu in seawater with the observed values included in the Historical Artificial Radionuclides in the HAM database, which has been constructed by the Meteorological Research Institute. The vertical distributions of the calculated 137Cs concentrations were in good agreement and are in good agreement with the observed profiles in the 1960s up to 250 m, in the 1970s up to 500 m, in the 1980s up to 750 m and in the 1990s up to 750 m. However, the calculated 137Cs concentrations were underestimated compared with the observed 137Cs at the deeper layer. This may suggest other transport processes of 137Cs to deep waters. The horizontal distributions of 137Cs concentrations in surface water could be simulated. A numerical tracer release experiment was performed to explain the horizontal distribution pattern. A maximum (239,240)Pu concentration layer occurs at an intermediate depth for both observed and calculated values, which is formed by particle scavenging. The horizontal distributions of the calculated (239,240)Pu concentrations in surface water could be simulated by considering the scavenging effect. 相似文献