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1.
Cadmium and lead were determined simultaneously in seawater by differential pulse stripping voltammetry (DPSV) preceded by
adsoptive collection of complexes with 8-hydroxyquinoline (oxine) on to a hanging mercury drop electrode (HMDE). In preliminary
experiments the optimal analytical condition for oxine concentration was found to be 2.10−5 M, at pH 7.7, the accumulation potential was −1.1 V, and the initial scannig potential was −0.8 V. The peak potentials were
found −0.652 V for Cd and −0.463 V for Pb At the 60 s accumalation time. The limit of detection (LOD) and limit of quantitatification
(LOQ) were found to be by voltammetry as 0.588 and 1.959 μg l−1 (RSD, 5.50%) for Cd and 0.931 and 3.104 μg l−1 (RSD, 4.10%) for Pb at 60 s stirred accumulation time respectively. In these conditions the most of the seawater samples
are amenable for direct voltammetric determination of cadmium and lead using a HMDE. An adsorptive stripping mechanism of
the electrode reaction was proposed. For the comparison, seawater samples were also analysed by ICP-atomic emission spectrometry
method (ICP-AES). The applied voltammetric technique was validated and good recoveries were obtained. 相似文献
2.
Ulas Im Kostandinos Markakis Alper Unal Tayfun Kindap Anastasia Poupkou Selahattin Incecik Orhan Yenigun Dimitros Melas Christina Theodosi Nikos Mihalopoulos 《Atmospheric environment (Oxford, England : 1994)》2010,44(26):3085-3094
High winter-time PM10, sulfate, nitrate and ammonium levels in Istanbul were investigated using a high resolution WRF/CMAQ mesoscale model system. A model-ready anthropogenic emission inventory on 2 km spatial resolution was developed for the area and the present study is the first attempt to test these emissions. The results suggested that the system was capable of producing the magnitudes. PM10 levels calculated by the model underestimated the observations with an average of 10 per cent at Bogazici University sampling station, whereas an overestimation of 12 per cent is calculated for all stations. High uncertainties, particularly in traffic and coal combustion, led to over estimations around emission hot spots. Base case results together with the sensitivity studies pointed significant contribution of local sources, pointing to the need of control strategies focusing on primary particulate emissions. 相似文献
3.
Ceyla Güngör Hasan Serin Selahattin Serin Kadir Aydın 《International Journal of Green Energy》2015,12(1):98-105
The overall objective of this study was to explore the utility of waste plastics as a potential source of diesel fuel. An experimental study was conducted to evaluate the use of various blends of plastic oil produced from waste polyethylene (WPE) with diesel fuel (D). WPE was degraded thermally and catalytically using sodium aluminum silicate as a catalyst. The oil collected at optimum conditions (414°C–480°C range and 1 h reaction time) was fractionated at different temperatures and fuel properties of the fractions were measured. Plastic oil was blended with diesel fuel at the volumetric ratios of 5%, 10%, 15%, 20%, and 100%. Fuel properties of blends are found comparable with those of diesel fuel within the EN 590 Diesel Fuel standard and they can also be used as fuel in compression ignition engines without any modification. Engine performance and exhaust emission studies of 5% WPE-D (WPE5) blend were performed. Experimental results showed that carbon monoxide (CO) emission is decreased by 20.63%, carbon dioxide (CO2) emission is increased by 3.34%, and oxides of nitrogen (NOx) emission is increased by 9.17% with WPE-D (WPE5) blend compared to diesel fuel. 相似文献
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5.
Sahin M Incecik S Topcu S Yildirim A 《Journal of the Air & Waste Management Association (1995)》2001,51(7):972-982
This paper presents a detailed analysis of the meteorological conditions that are associated with strong air pollution episodes in Ankara, Turkey. Based on climatological and air quality data [SO2 and TSP (total suspended particulates)] obtained for the winter months during 1989-1994, the analysis showed that the presence of weak atmospheric pressure gradients and warm air advection were the most important factors leading to high SO2 and TSP concentrations. In addition, the onset of the high air pollution episodes was generally associated with a trend toward negative vorticity at the 850-hPa level. 相似文献
6.
Topcu S Incecik S Unal YS 《Environmental science and pollution research international》2003,10(1):24-32
Istanbul has faced serious air pollution problems since the mid-80s. This is mainly due to particulate air pollution coming from poor quality lignite in areas, which are heavily populated and industrialized. As a consequence of severe air pollution problems, stringent control on the emissions in the city started in the year of 1994. In this work, in order to study the relationship between emissions and meteorological conditions, an assessment of air pollution episodes and air pollution potential in the city is presented for the terms at the changed emission schedule as the influence of an emission reduction strategy. The influence of meteorological conditions on the TSP (total suspended particulates) levels is considered for two consecutive winter periods. On this occasion, the city has faced different TSP levels and episode characteristics depending on stringent emission reductions covering the banned, poor-quality lignite and fuel switching. For this purpose, climatological conditions and air quality analyses were performed. 相似文献
7.
Yurdanur Sezginer Unal Selahattin Incecik Yunus Borhan Sibel Mentes 《Journal of the Air & Waste Management Association (1995)》2013,63(1):75-84
ABSTRACT The correlation between sulfur dioxide (SO2) concentrations measured at the European and Asian sides of Istanbul and meteorological parameters is investigated using principal component analysis (PCA) and multiple regression analysis techniques. Several meteorological parameters are selected to represent the atmospheric conditions during two winter periods: 1993–1994 and 1994–1995. Six principal components are found to explain the majority of the observed meteorological variability. Surface pressure, 850-mb temperature, and surface zonal (east-west) and meridional (north-south) winds show high loadings on separate factors identified by PCA. We seek dominant meteorological parameters that control the SO2 levels at each monitoring station. Several multiple regression analysis models are fitted to the data from each monitoring station using six principal components and previous day SO2 concentrations as independent variables. Results suggest that the most important parameters, highly correlated with SO2 concentrations in the Istanbul metropolitan area, are atmospheric pressure and surface zonal and meridional winds. These components have more influence on the determination of the air pollution levels at the Asian side than at the European side. 相似文献
8.
Unal YS Incecik S Borhan Y Mentes S 《Journal of the Air & Waste Management Association (1995)》2000,50(1):75-84
The correlation between sulfur dioxide (SO2) concentrations measured at the European and Asian sides of Istanbul and meteorological parameters is investigated using principal component analysis (PCA) and multiple regression analysis techniques. Several meteorological parameters are selected to represent the atmospheric conditions during two winter periods: 1993-1994 and 1994-1995. Six principal components are found to explain the majority of the observed meteorological variability. Surface pressure, 850-mb temperature, and surface zonal (east-west) and meridional (north-south) winds show high loadings on separate factors identified by PCA. We seek dominant meteorological parameters that control the SO2 levels at each monitoring station. Several multiple regression analysis models are fitted to the data from each monitoring station using six principal components and previous-day SO2 concentrations as independent variables. Results suggest that the most important parameters, highly correlated with SO2 concentrations in the Istanbul metropolitan area, are atmospheric pressure and surface zonal and meridional winds. These components have more influence on the determination of the air pollution levels at the Asian side than at the European side. 相似文献
9.
Mustafa Sahin Selahattin Incecik S. Topcu Ahmet Yildirim 《Journal of the Air & Waste Management Association (1995)》2013,63(7):972-982
ABSTRACT This paper presents a detailed analysis of the meteorological conditions that are associated with strong air pollution episodes in Ankara, Turkey. Based on climatological and air quality data [SO2 and TSP (total suspended par-ticulates)] obtained for the winter months during 19891994, the analysis showed that the presence of weak atmospheric pressure gradients and warm air advection were the most important factors leading to high SO2 and TSP concentrations. In addition, the onset of the high air pollution episodes was generally associated with a trend toward negative vorticity at the 850-hPa level. 相似文献
10.
Yayintaş OT Yilmaz S Türkoğlu M Colakoğlu FA Cakir F 《Environmental monitoring and assessment》2007,134(1-3):321-331
Waste water pollution in industrial areas is one of the most important environmental problems. Heavy metal pollution, especially chromium species in waste water sources from tannery affects our lives. Kocabas Stream is located in south-west Marmara region and Biga town is positioned in the sub basin on the stream. This water source functions as the water for irrigation in agriculture, drinking water for animals and for human use. Thus, this study is of great importance. Waste water pollution can affect all ecosystems and human health by directly or indirectly as in food chain. The concentration of heavy metals (Pb, Cd, Cu, Zn and Cr) were pre-analysed by ICP-AES method in water samples taken from sub-basin of Kocabas stream. In the results of these analyses, concentrations of the metals except chromium were founded at the limit value. But the total concentration of the Cr was found at high levels of between 0.0082 +/- 0.0001 and 5.7231 +/- 0.0921 mg l(-1) over the limit value (0.05 mg l(-1); WHO, EPA, TSE 266 and inland water quality classification) at sampling points very close to tannery factories. Also physicochemical and microbiological parameters of Kocabas Stream were determined. The effects of the experimental results on environment were investigated. 相似文献