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排序方式: 共有67条查询结果,搜索用时 15 毫秒
1.
Glycosylation of bisphenol A by freshwater microalgae 总被引:1,自引:0,他引:1
Nakajima N Teramoto T Kasai F Sano T Tamaoki M Aono M Kubo A Kamada H Azumi Y Saji H 《Chemosphere》2007,69(6):934-941
The endocrine disruptor bisphenol A (BPA, 4,4'-isopropylidenediphenol) is used to manufacture polycarbonate plastic and epoxy resin linings of food and beverage cans, and the residues from these products are then sometimes discharged into rivers and lakes in waste leachates. However, the fate of BPA in the environment has not yet been thoroughly elucidated. Considering the effect of BPA on aquatic organisms, it is important that we estimate the concentration of BPA and its metabolites in the aquatic environment, but there are few data on the metabolites of BPA. Here, we focused on freshwater microalgae as organisms that contribute to the biodegradation or biotransformation of BPA in aquatic environments. When we added BPA to cultures of eight species of freshwater microalgae, a reduction in the concentration of BPA in the culture medium was observed in all cultures. BPA was metabolized to BPA glycosides by Pseudokirchneriella subcapitata, Scenedesmus acutus, Scenedesmus quadricauda, and Coelastrum reticulatum, and these metabolites were then released into the culture medium. The metabolite from P. subcapitata, S. acutus, and C. reticulatum was identified by FAB-MS and (1)H-NMR as bisphenol A-mono-O-beta-d-glucopyranoside (BPAGlc), and another metabolite, from S. quadricauda, was identified as bisphenol A-mono-O-beta-d-galactopyranoside (BPAGal). These results demonstrate that freshwater microalgae that inhabit universal environments can metabolize BPA to its glycosides. Because BPA glycosides accumulate in plants and algae, and may be digested to BPA by beta-glycosidase in animal intestines, more attention should be given to levels of BPA glycosides in the environment to estimate the ecological impact of discharged BPA. 相似文献
2.
Motoyuki Sugano Akihiro Komatsu Masanori Yamamoto Mika Kumagai Takayuki Shimizu Katsumi Hirano Kiyoshi Mashimo 《Journal of Material Cycles and Waste Management》2009,11(1):27-31
Most landfilled plastic waste is a mixture or is in the form of composites with incombustible wastes such as glass, metals,
and ceramics. After hydrothermal treatment, including a steam-explosion process, the separation of mixed waste (MW) into organic
and inorganic substances becomes easy. However, the effect of hydrothermal pretreatment on the subsequent liquefaction of
organic substances from MW is not obvious. In this study, the effects on the liquefaction of polystyrene and high-density
polyethylene are discussed. Moreover, optimum conditions for the liquefaction of organic substances from hydrothermally treated
MW are identified. By means of this hydrothermal pretreatment, including the steam-explosion process, polystyrene and high-density
polyethylene can be significantly converted to oil by liquefaction at 300°–400°C. In comparison with liquefaction of hydrothermally
pretreated mixed waste (HMW) at 300°–400°C with a batch type reactor, the yield of oil increases significantly on liquefaction
using a semi-batch type reactor. It is considered that the radical chain and termination reactions among the radicals from
HMW were inhibited in the semi-batch type reactor. On liquefaction of HMW in a semi-batch reactor, the conversion of HMW to
oil was enhanced on increasing the liquefaction temperature to 350°C and the holding time to 60 min.
Chemical Feedstock Recycling & Other Innovative Recycling Techniques 6 相似文献
3.
4.
Comprehensive temperature monitoring in an in-vessel forced-aeration static-bed composting process 总被引:6,自引:0,他引:6
Masafumi Tateda Le Duc Trung Nguyen Viet Hung Michihiko Ike Masanori Fujita 《Journal of Material Cycles and Waste Management》2002,4(1):62-69
Comprehensive temperature monitoring was done in an in-vessel forced-aeration static-bed composting process using sewage sludge.
The three layers that divided the compost pile horizontally showed different temperature distributions. The temperature of
the top layer appeared not to be influenced by the ambient temperature. The temperature of the center area of the top layer
was taken to be the representative temperature for evaluating composting start-up performance. The temperature of the bottom
layer was strongly influenced by the ambient temperature, and the temperature of the center area of the bottom layer was taken
to be the representative temperature for pathogen control as it was the minimum temperature in the reactor. Composting start-up
performance was influenced by several factors when the ambient temperature was either below or above 20°C. When the ambient
temperature was below 20°C, the time taken to reach 65°C (T
65) was influenced by the temperature of inflowing air, but when the temperature was higher than 20°C, it was influenced by
the ratio of sewage sludge to seed compost (F/S). T
65 was least when F/S was 1–2.
Received: January 9, 2001 / Accepted: October 10, 2001 相似文献
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7.
To determine whether the appearance of a reproductively parasitic tactic varies, and how this variation affects territorial
males of the Lake Tanganyika cichlid fish Telmatochromis vittatus, we examined the reproductive ecology of territorial males in Mtondwe and compared it with that of a neighboring Wonzye population,
where nest density differs from that at Mtondwe. In Wonzye, with high nest density, male tactics change with their body size
from a territorial to a non-territorial parasitic tactic called piracy in which they conquer several nests defended by territorial
males and take over the nests while females are spawning. These “pirate” males could decrease the costs incurred by travelling
among nests by exclusively targeting aggregations of nests in close proximity while avoiding separate nests. Territorial males
in Wonzye sacrifice the potential higher attractiveness offered by large nests and instead compete for nests farther from
neighbors on which pirates less frequently intrude. In contrast, the Mtondwe population had lower nest density and piracy
was absent. Given that the success of piracy depends on the close proximity of nests, nest density is likely responsible for
the observed variation in the occurrence of piracy between the two populations. Furthermore, in Mtondwe, territorial males
competed for larger nests and were smaller than the territorial males in Wonzye. Thus, this lower nest density may free territorial
males from the selection pressures for increased size caused by both defense against nest piracy and the need to develop into
pirates as they grow. 相似文献
8.
9.
Mamoru Nishioka Nakamichi Yamasaki Hiroshi Amano Masanori Higuchi 《Waste management (New York, N.Y.)》1992,12(4)
Tritium is generally disposed of as an oxide form, and immobilization of tritium oxide with Portland cement is the most popular disposal method. However, the cement solidified body is rather leachable for tritium and is poor in some physical properties. A silicate powder, such as borosilicate glass powder, forms a synthetic rock by the hydrothermal hot-pressing (HHP) technique, making it a technique for immobilization of tritium oxide. Tritium oxide with borosilicate glass powder was solidified by the HHP technique. Leachability of tritium from the produced solidified bodies and the behavior of fixed tritium oxide during the heating were studied and discussed. The amount of tritium oxide fixed by the present procedure was almost the same as that fixed by the ordinary cement solidifying procedure. The diffusivity of tritium from the body by this procedure was much lower than that from the cement body and the compressive strength of the body was higher than that of the cement body. 相似文献
10.
A sample of commercial BADGE was fractioned by HPLC and eight impurities including novel propyl derivatives (2), (5) and (6) were identified by NMR spectrometry, FAB-MS and GC-MS. The estrogenicity, both agonist and antagonist, of fractions containing these impurities was measured with a yeast two-hybrid assay incorporating the human (hER alpha) and a competitive binding assay for hER alpha (ELISA). In the yeast two-hybrid assay, estrogenic antagonist activity was found in two fractions, while estrogenic agonist activity was not found in any. In the ELISA method, the binding affinity to hER alpha was found in three fractions. It is probable that a comprehensive assessment of the estrogenic properties of commercial BADGE, and their implications for human health, will require examination of all its components as described here. 相似文献