Effects of acidic attack on chemical,mineralogical, and morphological properties of geomaterials

Environmental Science and Pollution Research - Exposure of geomaterials to acidic leachates may compromise their structure and functionality due to changes in physicochemical, mineralogical, and...     

Chemical-mineralogical characterization of C&D waste recycled aggregates from São Paulo, Brazil

This study presents a methodology for the characterization of construction and demolition (C&;D) waste recycled aggregates based on a combination of analytical techniques (X-ray fluorescence (XRF), soluble ions, semi-quantitative X-ray diffraction (XRD), thermogravimetric analysis (TGA-DTG) and hydrochloric acid (HCl) selective dissolution). These combined analytical techniques allow for the estimation of the amount of cement paste, its most important hydrated and carbonated phases, as well as the amount of clay and micas. Details of the methodology are presented here and the results of three representative C&;D samples taken from the São Paulo region in Brazil are discussed. Chemical compositions of mixed C&;D aggregate samples have mostly been influenced by particle size rather than the visual classification of C&;D into red or grey and geographical origin. The amount of measured soluble salts in C&;D aggregates (0.15–25.4 mm) is lower than the usual limits for mortar and concrete production. The content of porous cement paste in the C&;D aggregates is around 19.3% (w/w). However, this content is significantly lower than the 43% detected for the C&;D powders (<0.15 mm). The clay content of the powders was also high, potentially resulting from soil intermixed with the C&;D waste, as well as poorly burnt red ceramic. Since only about 50% of the measured CaO is combined with CO₂, the powders have potential use as raw materials for the cement industry.     

Separability studies of construction and demolition waste recycled sand

The quality of recycled aggregates from construction and demolition waste (CDW) is strictly related to the content of porous and low strength phases, and specifically to the patches of cement that remain attached to the surface of natural aggregates. This phase increases water absorption and compromises the consistency and strength of concrete made from recycled aggregates. Mineral processing has been applied to CDW recycling to remove the patches of adhered cement paste on coarse recycled aggregates. The recycled fine fraction is usually disregarded due to its high content of porous phases despite representing around 50% of the total waste.This paper focus on laboratory mineral separability studies for removing particles with a high content of cement paste from natural fine aggregate particles (quartz/feldspars). The procedure achieved processing of CDW by tertiary impact crushing to produce sand, followed by sieving and density and magnetic separability studies. The attained results confirmed that both methods were effective in reducing cement paste content and producing significant mass recovery (80% for density concentration and 60% for magnetic separation). The production of recycled sand contributes to the sustainability of the construction environment by reducing both the consumption of raw materials and disposal of CDW, particularly in large Brazilian centers with a low quantity of sand and increasing costs of this material due to long transportation distances.