The Chillán River in Central Chile plays a fundamental role in local society, as a source of irrigation and drinking water,
and as a sink for urban wastewater. In order to characterize the spatial and temporal variability of surface water quality
in the watershed, a Water Quality Index (WQI) was calculated from nine physicochemical parameters, periodically measured at
18 sampling sites (January–November 2000). The results indicated a good water quality in the upper and middle parts of the
watershed. Downstream of the City of Chillán, water quality conditions were critical during the dry season, mainly due to
the effects of the urban wastewater discharge. On the basis of the results from a Principal Component Analysis (PCA), modifications
were introduced into the original WQI to reduce the costs associated with its implementation. WQIDIR2 and WQIDIR, which are both based on a laboratory analysis (Chemical Oxygen Demand) and three (pH, temperature and conductivity), respectively,
four field measurements (pH, temperature, conductivity and Dissolved Oxygen), adequately reproduce the most important spatial
and temporal variations observed with the original index. They are proposed as useful tools for monitoring global water quality
trends in this and other, similar agricultural watersheds in the Chilean Central Valley. Possibilities and limitations for
the application of the used methodology to watersheds in other parts of the world are discussed. 相似文献
Even though the neurofibromatosis type 1 (NF1) gene was cloned more than 3 years ago, the process of identifying mutations has not been fruitful, and genetic counselling is mainly based on the use of linked markers. Since 1990, we have analysed 130 NF1 families and have performed six prenatal diagnoses. In each case, genetic counselling has relied on linked markers and informativity was achieved in all of them. The use of intragenic microsatellite polymorphisms (IVS27AAAT2.1, IVS27AC28.4, IVS27AC33.1, and IVS38GT53.0) has increased the informativeness in our series of NF1 families to an average of 90 per cent, providing accurate diagnosis and confirmation of the disease status. 相似文献
A coupled solar photo-Fenton (chemical) and biological treatment has been used to remove biorecalcitrant diuron (42 mg l(-1)) and linuron (75 mg l(-1)) herbicides from water at pilot plant scale. The chemical process has been carried out in a 82 l solar pilot plant made up by four compound parabolic collector units, and it was followed by a biological treatment performed in a 40 l sequencing batch reactor. Two Fe(II) doses (2 and 5 mg l(-1)) and sequential additions of H2O2 (20 mg l(-1)) have been used to chemically degrade the initially polluted effluent. Next, biodegradability at different oxidation states has been assessed by means of BOD/COD ratio. A reagent dose of Fe=5 mg l(-1) and H2O2=100 mg l(-1) has been required to obtain a biodegradable effluent after 100 min of irradiation time. Finally, the organic content of the photo-treated solution has been completely assimilated by a biomass consortium in the sequencing batch reactor using a total suspended solids concentration of 0.2 g l(-1) and a hydraulic retention time of 24h. Comparison between the data obtained at pilot plant scale (specially the one corresponding to the chemical step) and previously published data from a similar system performing at laboratory scale, has been carried out. 相似文献
Environmental Science and Pollution Research - Nowadays, water-borne diseases including hepatitis remain the critical health challenge due to the inadequate supply of potable and safe water for... 相似文献
The cost of rolling is determined in particular by productivity and lifetime of rolls before regrinding. Adhesive wear of the sheet gives rise to transfer on the roll surface. Its occurrence depends on rolling conditions and is one of the determining factors of the maximal reduction for a given rolling speed. Abrasive wear of the roll is the second factor for roll lifetime. Both phenomena are strongly related to tribological and mechanical characteristics of the surface layer of rolls. Stainless steel is known for its high adhesiveness. Coatings with good tribological properties could help extend the roll service. In this paper, the potential of different PVD coatings (CrN, TiN and TiBN) is explored. The impact of these coatings on influential phenomena during rolling is analyzed thanks to well-adapted tribological and mechanical laboratory tests. The results show that TiN has a good potential in cold rolling of stainless steel strips. 相似文献
Fishponds are man-made shallow water bodies that are still little studied because of their small size. They represent high value ecosystems, both environmentally (biodiversity hotspot) and economically (fish production). They can have a high place on the hydrographic network, so their influence on water quality is of first importance for rivers and water bodies located downstream and monitored under the Water Framework Directive. These small water bodies can be a source of contaminants during draining period or an efficient buffer for pesticides. We wanted to evaluate whether these ponds could also be a remediation tool against metals by following the annual evolution of upstream/downstream flows. Cadmium, copper, lead and zinc concentrations were quantified in the dissolved phase upstream and downstream of three ponds, each one having a specific agricultural environment (traditional or organic). Metal concentration was quantified in sediments and water. For the dissolved phase, the predictive non-effect concentration was often exceeded, suggesting an environmental risk. Results highlighted also greater quantity of metals at the downstream of the pond compared to the upstream, suggesting remobilization into the ponds or direct cross-sectional contributions from the watershed (e.g. runoff from crops) or even remobilization. Regarding sediments, minimal contamination was shown but a high mineralogical variability. No buffer effect of ponds, which could reduce the risk of acute or chronic toxicity, was detected.
The rapidly developing Asian countries may face threatening environmental contamination, that however remains largely unassessed.
We studied persistent trace elements in three wetlands, Poyang Lake, relatively unpolluted, and Tai Lake, and Pearl River
Delta, selected as hotspots of pollution in Central China. We adopted as indicator the Little Egret, a widespread colonial
waterbird, and during 1999 and 2000 we collected and analysed the same samples as for a parallel study we conducted in Pakistan,
e.g. eggs, body feathers of chicks, prey spontaneously regurgitated by the chicks, and sediments at the areas most used by
foraging egrets. The levels of trace-metals at our three study areas were similar, or within the range, of those found in
the few other studies for East Asia, with few exceptions. The concentrations of the various elements were below the threshold
that may affect the survival or reproduction of the birds, and even the highest concentrations relative to background, i.e.
Se in eggs, and Hg in feathers at Pearl Delta, do not pose toxic hazards. In sediments, the levels of trace elements were
lower than the critical levels assumed for contaminated soil, except for alarming high levels of As at Poyang. These results
do not confirm our expectation, that Poyang was relatively uncontaminated, while Tai and Pearl were polluted. Although trace
metal concentration differed significantly among the three study areas, these differences were minor and were not consistent
among elements and samples. The bioaccumulation ratios from sediments through prey, feather and egg, were consistent with
our previous findings for Pakistan. Only Hg exhibited high bioaccumulation, while Se and Zn had low accumulation, and the
other elements no accumulation. This reasserts that feathers of predators such as egrets, may be more sensitive indicators
of environmental contamination for the elements subject to bioaccumulation, whereas the sediments or the organisms low in
the food chain are better indicators for the other elements. 相似文献
Remodelling works are frequent in harbour areas, given that they must adapt to rapidly changing market requirements. Depending on their nature (construction, demolition, etc.), these works may be carried out during long periods of time and thus exert a significant impact on the air quality at the harbours and their surroundings. The air quality at the Valencia harbour was studied during an enlargement project. Four sampling stations aimed to cover the major dust-emitting activities in the harbour. In addition, a sampling campaign was carried out to collect dust materials at their emission sources (e.g., loading and unloading of clinker and petroleum coke, as well as the enlargement works). Differences obtained between PM levels at the monitoring sites were correlated with the distance between sampling stations and enlargement works and/or harbour operations, as well as with the preferential wind direction. In all cases, the days with the highest PM_10 levels were linked to wind directions coinciding with the location of the enlargement works or the clinker and petroleum coke stocks. Classic source apportionment methodologies (PCA and CMB) were applied to the data, but their interpretation was complex due to the similar chemical signatures of PM originating from direct and fugitive emissions from stocked materials (e.g., clinker), and the enlargement works. To overcome this difficulty, a novel non-statistical approach was used to obtain quantitative estimations of the contributions from sources (petroleum coke and clinker), based on the correlation between specific PM components (e.g., carbonaceous species) and source tracers (e.g., V). Finally, a qualitative test using phenolphthalein was devised to identify the presence of clinker on the filters, which provided positive results. This novel tracer approach is thus recommended for harbour authorities. 相似文献
Dissipation and decontamination of chlorantraniliprole (Coragen 18.5 SC) in brinjal and okra fruits were studied following field application at single and double doses of 30 and 60 g ai ha?1, and the residues of the insecticide was estimated using LC-MS/MS. Initial residues of chlorantraniliprole at single and double doses on the fruits of brinjal were 0.72 and 1.48 mg kg?1, while on okra fruits, the residues were 0.48 and 0.91 mg kg?1, respectively. The residues reached below detectable level of 0.01 mg kg?1 on the 10th day. Half-life of chlorantraniliprole at 30 and 60 g ai ha?1 on brinjal was 1.58 and 1.80 days with the calculated waiting period of 0.69 and 2.38 days, whereas on okra, the values were 1.60 and 1.70 and 0 and 1.20 days, respectively. The extent of removal of chlorantraniliprole using simple decontaminating techniques at 2 h and 3 days after spraying was 40.99–91.37 % and 29.85–89.12 %, respectively, from brinjal fruits and 47.78–86.10 % and 41.77–86.48 %, respectively, from okra fruits. 相似文献