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1.
Morsheda Akhter Sagar Kumar Dutta Palash Kumar Dhar Jamil Ahmed Mohammed Nazrul Islam Khan Md. Khairul Amin Jahidul Islam 《环境质量管理》2023,32(4):149-160
Catalytic activity of spinel ferrite in breaking down toxic dye materials are promising due to their uniqueness. In this study, aluminum-doped copper zinc ferrite, Cu0.4Zn0.6-xAlxFe2O4 (x = 0.0, 0.2, 0.4, 0.6), a catalyst for toxic dye degradation is synthesized through chemical co-precipitation route. The formation of the spinel ferrite catalyst is initially confirmed by Fourier transform infrared spectra, which shows the frequency of metal-oxygen bond vibration at 539 and 427 cm−1 attributed to the tetrahedral and octahedral sites respectively. Higher intensity sharp peak of X-ray diffraction for (311) plane is the evidence for the phase purity and the formation of spinel ferrite. The crystallite size is found to decrease with the increase of Al3+ ion. The surface structure of the obtained particles is investigated using a scanning electron microscope. Analyses of the material's magnetic characteristics using a vibrating sample magnetometer (VSM) revealed that it is, in fact, a soft magnet, as evidenced by the loop of its hysteresis, which is narrow. The catalytic degradation of methylene blue dye under the mechanism of the photo-Fenton process is studied with the obtained spinel ferrites and the result is found to be as high as 96.5%. The process follows pseudo-second order kinetics and the Langmuir isotherm. 相似文献
2.
Ahmad Tasneem Nazar Sonaina Ahmad Kafeel Khan Zafar Iqbal Bashir Humayun Ashfaq Asma Munir Mudasra Munir Zunaira Hussain Khadim Alkahtani Jawaher Elshikh Mohamed Soliman Nadeem Muhammad Malik Ifra Saleem 《Environmental science and pollution research international》2021,28(23):29110-29116
Environmental Science and Pollution Research - The instant endeavor was undertaken to monitor copper (Cu) contents in water, soil, forage, and cow’s blood impacted by heavy automobiles in... 相似文献
3.
Environmental Fluid Mechanics - A series of experiments were conducted to quantify the dynamics of a filling box driven by a line plume that spans the full width of the enclosure. Three... 相似文献
4.
Abdul Jabbar Waheed Arshed Arshad Saleem Bhatti Syed Salman Ahmad Perveen Akhter Saeed -Ur -Rehman Muhammad Iftikhar Anjum 《Environmental monitoring and assessment》2010,169(1-4):429-438
Rechna interfluvial region is one of the main regions of Punjab, Pakistan. It is the area which is lying between River Ravi and River Chenab, alluvial-filled. Radioactivity levels in soil samples, collected from southern Rechna interfluvial region, Pakistan, have been estimated by using gamma-ray spectrometric technique. 226Ra, 232Th, the primordial radionuclide 40K, and the artificial radionuclide 137Cs have been measured in the soil of the study area. The mean radioactivity levels of 226Ra, 232Th, 40K, and 137Cs were found to be 50.6 ± 1.7, 62.3 ± 3.2, 662.2 ± 32.1, and 3.1 ± 0.3 Bq kg???1, respectively. The mean radium equivalent activity (Raeq), outdoor radiation hazard index (H out), indoor radiation hazard index (H in), and terrestrial absorbed dose rate for the area under study were determined as 190.8 ± 8.7 Bq kg???1, 0.52, 0.65, and 69.8 nGy h???1, respectively. The annual effective dose to the general public was found to be 0.43 mSv. This value lies well below the limit of 1 mSv for general public as recommended by the International Commission on Radiological Protection. The measured values are comparable with other global radioactivity measurements and are found to be safe for the public and the environment. 相似文献
5.
Tasneem Gul Kazi Sadaf Sadia Arain Hassan Imran Afridi Naeemullah Kapil Dev Brahman Nida Fatima Kolachi Moina Akhtar Mughal 《Environmental monitoring and assessment》2013,185(6):5199-5208
The extent to which smokeless tobacco endangers human health is an ongoing subject of debate. In this study, concentrations of toxic metals, cadmium (Cd), lead (Pb), and nickel (Ni), were measured in different snuff products (dry brown and black and moist green and brown), available and consumed in Pakistan. Concentrations of Cd, Pb, and Ni were determined in 23 samples of various brands of snuff by electrothermal atomic absorption spectrometry, after microwave-assisted acid digestion. The reliability of methodology was assured by analyzing certified reference material. The resulted data of toxic metals in different snuff products are comparable to the existing information with limited exceptions. It was estimated that 10 g intake of different types of snuff could contribute 14–68, 17–47, and 20–73 % of the provisional maximum tolerable daily intake for Cd, Ni, and Pb, respectively. 相似文献
6.
Sadaf Sadia Arain Tasneem Gul Kazi Jamshed Bashir Arain Hassan Imran Afridi Atif Gul Kazi Syeda Nasreen Kapil Dev Brahman 《Environmental science and pollution research international》2014,21(20):12017-12027
Oropharyngeal cancer is a significant public health issue in the world. The incidence of oropharyngeal cancer has been increased among people who have habit of chewing smokeless tobacco (SLT) in Pakistan. The aim of present study was to evaluate the concentration of nickel (Ni) in biological samples (whole blood, serum) of oral (n?=?95) and pharyngeal (n?=?84) male cancer patients. For comparison purposes, the biological samples of healthy age-matched referents (n?=?150), who consumed and did not consumed SLT products, were also analyzed for Ni levels. As the Ni level is very low in biological samples, a preconcentration procedure has been developed, prior to analysis of analyte by flame atomic absorption spectrometry (FAAS). The Ni in acid-digested biological samples was complexed with ammonium pyrrolidinedithio carbamate (APDC), and a resulted complex was extracted in a surfactant Triton X-114. Acidic ethanol was added to the surfactant-rich phase prior to its analysis by FAAS. The chemical variables, such as pH, amounts of reagents (APDC, Triton X-114), temperature, incubation time, and sample volume were optimized. The resulted data indicated that concentration of Ni was higher in blood and serum samples of cancer patients as compared to that of referents who have or have not consumed different SLT products (p?=?0.012–0.001). It was also observed that healthy referents who consumed SLT products have two to threefold higher levels of Ni in both biological samples as compared to those who were not chewing SLT products (p?0.01). Figure
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7.
Estimation of internal radiation dose to the adult Asian population from the dietary intakes of two long-lived radionuclides 总被引:1,自引:0,他引:1
Iyengar GV Kawamura H Dang HS Parr RM Wang JW Akhter P Cho SY Natera E Miah FK Nguyen MS 《Journal of environmental radioactivity》2004,77(3):221-232
Daily dietary intakes of two naturally occurring long-lived radionuclides, 232Th and 238U, were estimated for the adult population living in a number of Asian countries, using highly sensitive analytical methods such as instrumental and radiochemical neutron activation analysis (INAA and RNAA), and inductively coupled plasma mass spectrometry (ICP-MS). The Asian countries that participated in the study were Bangladesh (BGD), China (CPR), India (IND), Japan (JPN), Pakistan (PAK), Philippines (PHI), Republic of Korea (ROK) and Vietnam (VIE). Altogether, these countries represent more than 50% of the world population. The median daily intakes of 232Th ranged between 0.6 and 14.4 mBq, the lowest being for Philippines and the highest for Bangladesh, and daily intakes of 238U ranged between 6.7 and 62.5 mBq, lowest and the highest being for India and China, respectively. The Asian median intakes were obtained as 4.2 mBq for 232Th and 12.7 mBq for 238U. Although the Asian intakes were lower than intakes of 12.3 mBq (3.0 ug) 232Th and 23.6 mBq (1.9 ug) 238U proposed by the International Commission on Radiological Protection (ICRP) for the ICRP Reference Man, they were comparable to the global intake values of 4.6 mBq 232Th and 15.6 mBq 238U proposed by the United Nation Scientific Commission on Effects of Radiation (UNSCEAR). The annual committed effective doses to Asian population from the dietary intake of 232Th and 238U were calculated to be 0.34 and 0.20 microSv, respectively, which are three orders of magnitude lower than the global average annual radiation dose of 2400 microSv to man from the natural radiation sources as proposed by UNSCEAR. 相似文献
8.
Akhter P Orfi SD Kawamura H Ahmad N Khaleeq-Ur-Rahman M 《Journal of environmental radioactivity》2002,62(2):123-127
A pilot study on ingestion and organ content of trace elements of importance in radiological protection was to be carried out in Pakistan. Baseline analytical data on daily dietary intake of thorium was to be measured using Instrumental Neutron Activation Analysis (INAA) technique. To determine the accuracy and reliability of our technique, some samples were measured in Pakistan using INAA and in Japan using Inductively Coupled Plasma-Mass Spectrometry. For intercomparison of results overall mean Z-scores were calculated. The results showed validity of our technique. Mean value of 232Th concentration in Pakistani diet samples using INAA technique is 0.0062 +/- 0.0028 microg/g and with ICP-MS technique is 0.0069 +/- 0.0032 microg/g. 相似文献
9.
Shakoor Adeel Khan Asim Laeeq Akhter Parveen Aslam Muhammad Bilad Muhammad Roil Maafa Ibrahim M. Moustakas Konstantinos Nizami Abdul-Sattar Hussain Murid 《Environmental science and pollution research international》2021,28(10):12397-12405
Environmental Science and Pollution Research - Mixed matrix membranes (MMMs) were fabricated by the hydrothermal synthesis of ordered mesoporous KIT-6 type silica and incorporating in polyimide... 相似文献
10.
Naaz Haleema Yasin Durdana Afzal Bushra Sami Neha Khan Nida Jamil Fatma Tasneem 《Environmental science and pollution research international》2023,30(10):25069-25079
Environmental Science and Pollution Research - Paddy field farming remains the dominant form of growing rice in modern times as the rice is the staple food for over half the world’s... 相似文献